(+)-1,2-BIS[(2S,5S)-2,5-DIETHYLPHOSPHOLANO]BENZENE

Reaction

Product Name: (+)-1,2-BIS[(2S,5S)-2,5-DIETHYLPHOSPHOLANO]BENZENE
CAS No.: 136779-28-7
Chemical Name: (+)-1,2-BIS[(2S,5S)-2,5-DIETHYLPHOSPHOLANO]BENZENE
Synonyms: ano)benzene;(S,S)-ET-DUPHOS;(SS)-Et-DuPhosTM;(S,S)-ETHYL-DUPHOS;(+)-1,2-BIS[(2S,5S)-2,5-DIETHYLPHOSPHOLANO]BENZENE;1,2-Bis((2S,5S)-2,5-diethylphospholan-1-yl)benzene;(+)-1,2-Bis((2S,5S)-2,5-diethylphospholano)benzene;1,2-Bis[(2S,5S)-2,5-diethyl-1-phospholanyl]benzene;(+)-1,2-Bis[(2S,5S)-2,5-diethyl-1-phospholanyl]benzene, 97+%;1,2-Bis((2S,5S)-2,5-diethylphospholan-1-yl)benzene - [B94182]
CBNumber: CB6458276
Molecular Formula: C22H36P2
Formula Weight: 362.47
MOL File: 136779-28-7.mol

More

Less

(+)-1,2-BIS[(2S,5S)-2,5-DIETHYLPHOSPHOLANO]BENZENE Property

Boiling point:: 468.5±15.0 °C(Predicted)
alpha: +265° (c 1, hexane)
Density: 1.010 g/mL at 25 °C
refractive index: n20/D 1.581
Flash point:: >230 °F
storage temp.: under inert gas (nitrogen or Argon) at 2-8°C
Appearance: Colorless to light yellow Viscous Liquid
optical activity: 146.34°(C=1.00g/100mL, hexane, 20°C, 589nm)
Sensitive: Air Sensitive
BRN: 4814174

More

Less

Safety

Hazard Codes: Xi
Risk Statements: 36/37/38
Safety Statements: 26-36
WGK Germany: 3
F: 1-10

More

Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

More

Less

N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 668486
Product name: (+)-1,2-Bis[(2S,5S)-2,5-diethylphospholano]benzene
Purity: Namena purity
Packaging: 500mg
Price: $283
Updated: 2025/07/31

Sigma-Aldrich

Product number: 668486
Product name: (+)-1,2-Bis[(2S,5S)-2,5-diethylphospholano]benzene
Purity: Namena purity
Packaging: 100mg
Price: $108
Updated: 2024/03/01

Strem Chemicals

Product number: 15-0098
Product name: (+)-1,2-Bis((2S,5S)-2,5-diethylphospholano)benzene, 98+% (S,S)-Et-DUPHOS
Packaging: 100mg
Price: $82
Updated: 2024/03/01

Strem Chemicals

Product number: 15-0098
Product name: (+)-1,2-Bis((2S,5S)-2,5-diethylphospholano)benzene, 98+% (S,S)-Et-DUPHOS
Packaging: 500mg
Price: $283
Updated: 2024/03/01

Strem Chemicals

Product number: 15-0098
Product name: (+)-1,2-Bis((2S,5S)-2,5-diethylphospholano)benzene, 98+% (S,S)-Et-DUPHOS
Packaging: 2g
Price: $917
Updated: 2024/03/01

More

Less

(+)-1,2-BIS[(2S,5S)-2,5-DIETHYLPHOSPHOLANO]BENZENE Chemical Properties,Usage,Production

Reaction

Ligand used in rhodium catalyzed asymmetric hydrogenation of 2-methylenesuccinamic acid.

Uses

DuPhos and BPE Ligands: Highly Efficient Privileged Ligands

(+)-1,2-BIS[(2S,5S)-2,5-DIETHYLPHOSPHOLANO]BENZENE Preparation Products And Raw materials

Raw materials

Preparation Products

More

Less

(+)-1,2-BIS[(2S,5S)-2,5-DIETHYLPHOSPHOLANO]BENZENE Suppliers

China 45 Germany 2 India 1 Japan 1 Norway 1 Switzerland 1 The Netherlands 1 United Kingdom 2 United States 6 Global 60

J & K SCIENTIFIC LTD.

Tel: 18210857532; 18210857532
Fax: 86-10-82849933
Email: jkinfo@jkchemical.com
Country: China
ProdList: 96815
Advantage: 76

Meryer (Shanghai) Chemical Technology Co., Ltd.

Tel: 4006356688 18621169109
Fax: 86-21-61259102
Email: market03@meryer.com
Country: China
ProdList: 40228
Advantage: 62

Alfa Aesar

Tel: 400-6106006
Fax: 021-67582001/03/05
Email: saleschina@alfa-asia.com
Country: China
ProdList: 30123
Advantage: 84

Energy Chemical

Tel: 021-021-58432009 400-005-6266
Fax: 021-58436166
Email: sales8178@energy-chemical.com
Country: China
ProdList: 44801
Advantage: 61

Jiangsu Aikon Biopharmaceutical R&D co.,Ltd.

Tel: 025-66028182 18626450290
Email: yftan@aikonchem.com
Country: China
ProdList: 16679
Advantage: 50

Sigma-Aldrich

Tel: 021-61415566 800-8193336
Email: orderCN@merckgroup.com
Country: China
ProdList: 51395
Advantage: 80

Zhengzhou Kingorgchem Chemical Technology Co., Ltd.gy Co., Ltd.

Tel: 0371-65511006 18625597674
Email: sales@kingorgchem.com
Country: China
ProdList: 976
Advantage: 55

LaaJoo

Tel: 021-60702684 18516024827
Email: huang.jiayi@sinocompound.com
Country: China
ProdList: 2280
Advantage: 58

Shandong Ono Chemical Co., Ltd.

Tel: 0539-6362799 20）
Fax: 0539-6362799（To 20）
Country: China
ProdList: 9998
Advantage: 58

Shanghai Tube Pharmaceutical Co., Ltd.

Tel: 021-54338626 18017892860
Fax: 021-54338626
Email: sales@tubepharm.com
Country: China
ProdList: 2572
Advantage: 58

136779-28-7, (+)-1,2-BIS[(2S,5S)-2,5-DIETHYLPHOSPHOLANO]BENZENERelated Search:

(R)-5-fluoro-3-methylisobenzofuran-1(3H)-one (+)-1,2-BIS[(2S,5S)-2,5-DIMETHYLPHOSPHOLANO]BENZENE (S)-5-fluoro-3-methylisobenzofuran-1(3H)-one (-)-1,2-BIS[(2R,5R)-2,5-DIMETHYLPHOSPHOLANO]BENZENE (-)-1,2-BIS((2R,5R)-2,5-DIETHYLPHOSPHOLANO)BENZENE Benzene (+)-1,2-BIS((2S,5S)-2,5-DIETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM (I) TRIFLUOROMETHANESULFONATE (-)-1,2-BIS((2R,5R)-2,5-DIETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(L)TETRAFLUOROBORATE (-)-1,2-Bis((2R,5R)-2,5-diethylphospholano)benzene(cyclooctadiene)rhodium(I) trifluoromethanesulfonate (+)-1,2-BIS((2R,5R)-2,5-DI-I-PROPYLPHOSPHOLANO)BENZENE)1,5-CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE (-)-1,2-BIS((2R,5R)-2,5-DIETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I)TRIFLUOROMETHANESULFONATE (+)-1,2-BIS((2S,5S)-2,5-DIETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(L)TETRAFLUOROBORATE (+)-1,2-Bis[(2R,5R)-2,5-diisopropylphospholano]benzene (+)-1,2-BIS[(2S,5S)-2,5-DIETHYLPHOSPHOLANO]BENZENE

(S,S)-ETHYL-DUPHOS

(S,S)-ET-DUPHOS

1,2-Bis((2S,5S)-2,5-diethylphospholan-1-yl)benzene

(+)-1,2-Bis[(2S,5S)-2,5-diethylphospholano]benzene, Kanata purity

(+)-1,2-Bis((2S,5S)-2,5-diethylphospholano)benzene,98+%(S,S)-Et-DUPHOS

(S,S)-Ethyl-DUPHOS, (2S,2μS,5S,5μS)-2,2μ,5,5μ-Tetraethyl-1,1μ-(o-phenylene)diphospholane

(2S,2'S,5S,5'S)-2,2',5,5'-TETRAETHYL-1,1'-(1,2-PHENYLENE)DIPHOSPHOLANE

(2S,2'S,5S,5'S)-2,2',5,5'-TETRAETHYL-1,1'-(O-PHENYLENE)DIPHOSPHOLANE

(+)-1,2-BIS[(2S,5S)-2,5-DIETHYLPHOSPHOLANO]BENZENE

(+)-1,2-Bis[(2S,5S)-2,5-diethyl-1-phospholanyl]benzene, 97+%

(+)-1,2-Bis((2S,5S)-2,5-diethylphospholano)benzene (S,S)-Et-DUPHOS

ano)benzene

Phospholane, 1,1'-(1,2-phenylene)bis[2,5-diethyl-, (2S,2'S,5S,5'S)-

(+)-1,2-Bis((2S,5S)-2,5-diethylphospholano)benzene

(2S,5S)-1-[2-[(2S,5S)-2,5-diethylphospholan-1-yl]phenyl]-2,5-diethylphospholane

(SS)-Et-DuPhosTM

1,2-Bis[(2S,5S)-2,5-diethyl-1-phospholanyl]benzene

(+)-1,2-Bis[(2<i>S</i>,5<i>S</i>)-2,5-diethylphospholano]benzene

1,2-Bis((2S,5S)-2,5-diethylphospholan-1-yl)benzene - [B94182]

136779-28-7

C22H36P2

Chiral Catalysts, Ligands, and Reagents

Asymmetric Synthesis

Privileged Ligands

DuPhos/BPE

organophosphine ligand