(-)-1,2-BIS[(2R,5R)-2,5-DIMETHYLPHOSPHOLANO]BENZENE

Reactions

Product Name: (-)-1,2-BIS[(2R,5R)-2,5-DIMETHYLPHOSPHOLANO]BENZENE
CAS No.: 147253-67-6
Chemical Name: (-)-1,2-BIS[(2R,5R)-2,5-DIMETHYLPHOSPHOLANO]BENZENE
Synonyms: an-1-yL;(R,R)-ME-DUPHOS;(R,R)-METHYL-DUPHOS;()-1,2-Bis[(2R,5R)-2,5-dimethylphospholano]benzene;1,2-Bis[(2R,5R)-2,5-dimethyl-1-phospholanyl]benzene;(-)-1,2-BIS[(2R,5R)-2,5-DIMETHYLPHOSPHOLANO]BENZENE;1,2-bis((2R,5R)-2,5-dimethylphospholan-1-yl)benzene;(-)-1,2-bis-((2R,5R)-2,5-Dimethylphospholano)benzene;(-) -1,2-bis ((2R, 5R) -2,5-dimethylphosphorus) benzene;1,2-Bis[(2R,5R)-2,5-diMethyl-1-phospholanyl]benzene, 97+%
CBNumber: CB0456508
Molecular Formula: C18H28P2
Formula Weight: 306.36
MOL File: 147253-67-6.mol

More

Less

(-)-1,2-BIS[(2R,5R)-2,5-DIMETHYLPHOSPHOLANO]BENZENE Property

Melting point:: 66-76 °C
alpha: -476° (c 1, hexane)
Boiling point:: 415.0±15.0 °C(Predicted)
storage temp.: under inert gas (nitrogen or Argon) at 2-8°C
form: crystal
color: white
optical activity: [α]20/D -420±15°, c = 0.5 in methylene chloride
Water Solubility: Insoluble in water.
Sensitive: Air Sensitive
BRN: 4810602
CAS DataBase Reference: 147253-67-6

More

Less

Safety

Safety Statements: 22-24/25
WGK Germany: 3
F: 10-23
HS Code: 2934999090

More

Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

More

Less

N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 665258
Product name: (?)-1,2-Bis[(2R,5R)-2,5-dimethylphospholano]benzene
Purity: kanata purity
Packaging: 100mg
Price: $78.5
Updated: 2023/06/20

TCI Chemical

Product number: B2436
Product name: 1,2-Bis[(2R,5R)-2,5-dimethylphospholano]benzene
Packaging: 100MG
Price: $65
Updated: 2024/03/01

TCI Chemical

Product number: B2436
Product name: 1,2-Bis[(2R,5R)-2,5-dimethylphospholano]benzene
Packaging: 500MG
Price: $269
Updated: 2024/03/01

Alfa Aesar

Product number: H60592
Product name: 1,2-Bis[(2R,5R)-2,5-dimethyl-1-phospholanyl]benzene, 97+%
Packaging: 250mg
Price: $125.65
Updated: 2024/03/01

Alfa Aesar

Product number: H60592
Product name: 1,2-Bis[(2R,5R)-2,5-dimethyl-1-phospholanyl]benzene, 97+%
Packaging: 1g
Price: $424.65
Updated: 2024/03/01

More

Less

(-)-1,2-BIS[(2R,5R)-2,5-DIMETHYLPHOSPHOLANO]BENZENE Chemical Properties,Usage,Production

Reactions

The DUPHOS family of catalysts is highly efficient for the asymmetric hydrogenation of various substituted cetamidoacrylates and enol acetates yielding products of high enantiomeric excesses.
Efficient ligand for the asymmetric hydrogenation of imines, enamines, and enamides.
Asymmetric hydrogenation of vinyl alcohols.
Catalyst used for the asymmetric hydrogenation of enol phosphonates.
Asymmetric hydrogenation of allylic alcohols.
Ligand for the catalytic asymmetric [4+1] cycloaddition of vinylallenes with CO.
Ligand for the Rh-catalyzed asymmetric enyne cycloisomerization.
Catalytic enantioselective addition of dialkylzinc to N-Diphenylphosphinoylimines.

Uses

1,2-Bis[(2R,5R)-2,5-dimethyl-1-phospholanyl]benzene is an important raw material and intermediate used in organic synthesis, pharmaceuticals, agrochemicals and dyestuff. It is used as highly efficient privileged ligands.

(-)-1,2-BIS[(2R,5R)-2,5-DIMETHYLPHOSPHOLANO]BENZENE Preparation Products And Raw materials

Raw materials

Preparation Products

More

Less

(-)-1,2-BIS[(2R,5R)-2,5-DIMETHYLPHOSPHOLANO]BENZENE Suppliers

Americas 1 China 58 Europe 1 Germany 2 India 2 Israel 1 Japan 2 Norway 1 Switzerland 1 The Netherlands 1 United Kingdom 1 United States 5 Global 76

J & K SCIENTIFIC LTD.

Tel: 010-82848833 400-666-7788
Fax: 86-10-82849933
Email: jkinfo@jkchemical.com
Country: China
ProdList: 96815
Advantage: 76

Meryer (Shanghai) Chemical Technology Co., Ltd.

Tel: 021-61259108 18621169109
Fax: 86-21-61259102
Email: market03@meryer.com
Country: China
ProdList: 40228
Advantage: 62

Alfa Aesar

Tel: 400-6106006
Fax: 021-67582001/03/05
Email: saleschina@alfa-asia.com
Country: China
ProdList: 30123
Advantage: 84

Beijing HwrkChemical Technology Co., Ltd

Tel: 010-89508211 18501085097
Fax: 010-89508210
Email: sales.bj@hwrkchemical.com
Country: China
ProdList: 8415
Advantage: 55

Energy Chemical

Tel: 021-021-58432009 400-005-6266
Fax: 021-58436166
Email: sales8178@energy-chemical.com
Country: China
ProdList: 44689
Advantage: 61

Adamas Reagent, Ltd.

Tel: 400-6009262 16621234537
Fax: 021-64823266
Email: chenyj@titansci.com
Country: China
ProdList: 14103
Advantage: 59

Daicel Chiral Technologies (China)CO.,LTD

Tel: 021-50460086-9 15921403865
Fax: +86-21-50462321
Email: han_yajun@dctc.daicel.com
Country: China
ProdList: 7189
Advantage: 65

Hunan Hui Bai Shi Biotechnology Co., Ltd.

Tel: 0731-85526065 13308475853
Email: ivy@hnhbsj.com
Country: China
ProdList: 4552
Advantage: 62

TOKYO CHEMICAL INDUSTRY CO., LTD.

Tel: 03-36680489
Fax: 03-3668-0520
Email: Sales-JP@TCIchemicals.com
Country: Japan
ProdList: 28387
Advantage: 80

TCI Europe

Tel: 320-37350700
Fax: +32 (0)37350701
Email: sales@tcieurope.eu
Country: Europe
ProdList: 23671
Advantage: 75

More

Less

View Lastest Price from (-)-1,2-BIS[(2R,5R)-2,5-DIMETHYLPHOSPHOLANO]BENZENE manufacturers

Career Henan Chemical Co

Product: (-)-1,2-BIS[(2R,5R)-2,5-DIMETHYLPHOSPHOLANO]BENZENE 147253-67-6
Price: US $7.00/KG
Min. Order: 0.1KG
Purity: 98%
Supply Ability: 1KG; 10KG; 50KG; 100KG and more
Release date: 2024-10-11

Zhuozhou Wenxi import and Export Co., Ltd

Product: ()-1,2-Bis[(2R,5R)-2,5-dimethylphospholano]benzene 147253-67-6
Price: US $15.00-10.00/KG
Min. Order: 1KG
Purity: 99%+ HPLC
Supply Ability: Monthly supply of 1 ton
Release date: 2021-06-27

147253-67-6, (-)-1,2-BIS[(2R,5R)-2,5-DIMETHYLPHOSPHOLANO]BENZENERelated Search:

(+)-1,2-Bis((2S,5S)-2,5-dimethylphospholano)benzene,98+%(S,S)-Me-DUPHOS,(+)-1,2-BIS[(2S,5S)-2,5-DIMETHYLPHOSPHOLANO]BENZENE (-)-1,2-BIS((2R,5R)-2,5-DIETHYLPHOSPHOLANO)BENZENE (3R,6R)-3,6-OCTANEDIOL (-)-1,2-BIS((2R,5R)-2,5-DIPHENYLPHOSPHOLANO)ETHANE (R)-5-fluoro-3-methylisobenzofuran-1(3H)-one (+)-1,2-BIS[(2S,5S)-2,5-DIETHYLPHOSPHOLANO]BENZENE (S)-5-fluoro-3-methylisobenzofuran-1(3H)-one (-)-1,2-BIS((2R,5R)-2,5-DIETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(L)TETRAFLUOROBORATE (-)-1,2-Bis[(2R,5R)-dimethylphospholano]benzene(cyclooctadiene)rhodium(I) tetrafluoroborate (S,S)-I-PR-DUPHOS (-)-1,2-BIS[(2R,5R)-2,5-DIMETHYLPHOSPHOLANO]BENZENE (-)-1,2(2R,5R)-2,5-(DIMETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I)TRIFLUOROMETHANESULFONATE (+)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I)TETRAFLUOROBORATE (-)-1,2-BIS((2R,5R)-2,5-DIETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I)TRIFLUOROMETHANESULFONATE (-)-1,2(2R,5R)-2,5-(DIMETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I)TRIFLUOROMETHANESULFONATE 1,2-Bis[(2R,5R)-2,5-dimethylphospholano]benzene monooxide 1,2-Bis[(2S,5S)-2,5-dimethylphospholano]benzene monooxide (-)-1,2-BIS((2S,5S)-2,5-DI-I-PROPYLPHOSPHOLANO)BENZENE(1,5-CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE

(2R,2'R,5R,5'R)-2,2',5,5'-TETRAMETHYL-1,1'-(1,2-PHENYLENE)DIPHOSPHOLANE

(2R,2'R,5R,5'R)-2,2',5,5'-TETRAMETHYL-1,1'-(O-PHENYLENE)DIPHOSPHOLANE

(-)-1,2-BIS[(2R,5R)-2,5-DIMETHYLPHOSPHOLANO]BENZENE

(-)-1,2-BIS((2R,5R)-2,5-DIMETHYLPHOSPHOLANO)BENZENE, KANATA PURITY

(-)-1,2-Bis((2R,5R)-2,5-dimethylphospholano)benzene(r,r)-me-duphos

(-)-1,2-Bis((2R,5R)-2,5-dimethylphospholano)benzene,98+%(R,R)-Me-DUPHOS

(-)-1,2-Bis((2R,5R)-2,5-dimethylphospholano)benzene, (R,R)-Me-DUPHOS,98+%

()-1,2-Bis[(2R,5R)-2,5-dimethylphospholano]benzene,(2R,2’R,5R,5′R)-2,2′,5,5′-Tetramethyl-1,1′-(o-phenylene)diphospholane, (R,R)-Me-DUPHOS, (R,R)-Methyl-DUPHOS

1,2-Bis[(2R,5R)-2,5-diMethyl-1-phospholanyl]benzene, 97+%

(2R,5R,2'R,5'R)-1,1'-(1,2-Phenylene)bis(2,5-dimethylphospholane)

1,2-Bis[(2R,5R)-2,5-dimethyl-1-phospholanyl]benzene

(R,R)-ME-DUPHOS

(R,R)-METHYL-DUPHOS

()-1,2-Bis[(2R,5R)-2,5-diMethylphospholano]benzene,>=95.0%

1,2-bis((2R,5R)-2,5-dimethylphospholan-1-yl)benzene

[2R-[1(2'R*,5'R*),2a,5b]]-1,1'-(1,2-phenylene)bis[2,5-dimethylphospholane]

(-)-1,2-Bis((2R,5R)-2,5-dimethylphospholano)benzene, min.97% (R,R)-Me-DUPHOS

Phospholane, 1,1'-(1,2-phenylene)bis[2,5-dimethyl-, (2R,2'R,5R,5'R)-

an-1-yL

()-1,2-Bis[(2R,5R)-2,5-dimethylphospholano]benzene

(-)-1,2-bis-((2R,5R)-2,5-Dimethylphospholano)benzene

(-)-1,2-Bis((2R,5R)-2,5-dimethylphospholano)benzene (R,R)-Me-Duphos

(-) -1,2-bis ((2R, 5R) -2,5-dimethylphosphorus) benzene

147253-67-6

C18H28P2

Asymmetric Synthesis

Chiral Catalysts, Ligands, and Reagents

Privileged Ligands

DuPhos/BPE

organophosphine ligand