Allyltriphenylphosphonium bromide
- Product Name
- Allyltriphenylphosphonium bromide
- CAS No.
- 1560-54-9
- Chemical Name
- Allyltriphenylphosphonium bromide
- Synonyms
- TAL;triphenyl(prop-2-en-1-yl)phosphaniuM broMide;NSC 59815;NSC 110609;allyltriphenylphosphonium;allyltriphenyl-phosphoniubromide;Allytriphenylphosphonium bromide;allyl triphenylphosphine bromide;Triphenylallylphosphonium bromide;ALLYLTRIPHENYLPHOSPHONIUM BROMIDE
- CBNumber
- CB4381501
- Molecular Formula
- C21H20BrP
- Formula Weight
- 383.26
- MOL File
- 1560-54-9.mol
Allyltriphenylphosphonium bromide Property
- Melting point:
- 222-225 °C (lit.)
- storage temp.
- Sealed in dry,Room Temperature
- form
- Powder
- color
- White
- Water Solubility
- decomposes
- Sensitive
- Hygroscopic
- BRN
- 3579053
- InChI
- InChI=1S/C21H20P.BrH/c1-2-18-22(19-12-6-3-7-13-19,20-14-8-4-9-15-20)21-16-10-5-11-17-21;/h2-17H,1,18H2;1H/q+1;/p-1
- InChIKey
- FWYKRJUVEOBFGH-UHFFFAOYSA-M
- SMILES
- [P+](CC=C)(C1C=CC=CC=1)(C1=CC=CC=C1)C1C=CC=CC=1.[Br-]
- CAS DataBase Reference
- 1560-54-9(CAS DataBase Reference)
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P405Store locked up.
N-Bromosuccinimide Price
- Product number
- S280178
- Product name
- ALLYL-TRIPHENYL-PHOSPHONIUM, BROMIDE
- Purity
- AldrichCPR
- Packaging
- 25MG
- Price
- $29.8
- Updated
- 2024/03/01
- Product number
- A36603
- Product name
- Allyltriphenylphosphonium bromide
- Purity
- 99%
- Packaging
- 100g
- Price
- $63
- Updated
- 2024/03/01
- Product number
- A1007
- Product name
- Allyltriphenylphosphonium Bromide
- Purity
- >98.0%(T)
- Packaging
- 25g
- Price
- $126
- Updated
- 2024/03/01
- Product number
- A14490
- Product name
- Allyltriphenylphosphonium bromide, 99%
- Packaging
- 50g
- Price
- $47.65
- Updated
- 2024/03/01
- Product number
- A14490
- Product name
- Allyltriphenylphosphonium bromide, 99%
- Packaging
- 250g
- Price
- $160.65
- Updated
- 2024/03/01
Allyltriphenylphosphonium bromide Chemical Properties,Usage,Production
Chemical Properties
white crystalline powder
Uses
Allyltriphenylphosphonium bromide is used for the first time in the preparation of DES. It has been shown to be part of Phosphonium salts, having antiviral activity against influenza virus A. It can be used in witting olefination of aldehydes for preparation of conjugated dienes.
Preparation
Allyltriphenylphosphonium bromide was synthesized from the reaction of triphenylphosphine and allyl bromide in dry toluene.
Application
Reactant for:
Preparation of a diol and carbamate chemistry library for common functional groups
Regioselective synthesis of alkenes via semihydrogenation and semihydrogenation-oxidation of dienes
Alkene addition of frustrated Lewis pairs
Olefination of N-sulfonyl imines for stereoselective synthesis of vinyl arenes
Wittig olefination of aldehydes for preparation of conjugated dienes
Tandem Michael addition / ylide olefination reactions for the synthesis of highly functionalized cyclohexadienes
Reaction of allyltriphenylphosphonium bromide and Garner's aldehyde in basic media provided β- hydroxy-1,3-dienes.
Methyl 3-(buta-1,3-dienyl)benzoate
1-(Buta-1,3-dienyl)-4-(trifluoromethyl)benzene
1-(Buta-1,3-dienyl)-2-chlorobenzene
1-Bromo-4-(buta-1,3-dienyl)benzene
Buta-1,3-dienylbenzene
Allyltriphenylphosphonium bromide Preparation Products And Raw materials
Raw materials
Preparation Products
Allyltriphenylphosphonium bromide Suppliers
- Tel
- 03-36680489
- Fax
- 03-3668-0520
- Sales-JP@TCIchemicals.com
- Country
- Japan
- ProdList
- 28398
- Advantage
- 80
View Lastest Price from Allyltriphenylphosphonium bromide manufacturers
- Product
- Allyltriphenylphosphonium bromide 1560-54-9
- Price
- US $0.00-0.00/kg
- Min. Order
- 1kg
- Purity
- 98%
- Supply Ability
- 1Ton
- Release date
- 2022-10-10
- Product
- Allyltriphenylphosphonium bromide 1560-54-9
- Price
- US $1.00-0.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 20 tons
- Release date
- 2020-01-15
- Product
- Allyltriphenylphosphonium bromide 1560-54-9
- Price
- US $8.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- 10TON
- Release date
- 2018-12-18