3-FLUORO-4-NITROBENZYL BROMIDE

Product Name: 3-FLUORO-4-NITROBENZYL BROMIDE
CAS No.: 131858-37-2
Chemical Name: 3-FLUORO-4-NITROBENZYL BROMIDE
Synonyms: 4-(BroMoMethyl)-2-fluoro-1-nitrobenzene;3-FLUORO-4-NITROBENZYL BROMIDE;4-(Bromomethyl)-2-fluoronitrobenzene;Benzene, 4-(bromomethyl)-2-fluoro-1-nitro-;4-(Bromomethyl)-2-fluoronitrobenzene, alpha-Bromo-3-fluoro-4-nitrotoluene
CBNumber: CB4395597
Molecular Formula: C7H5BrFNO2
Formula Weight: 234.02
MOL File: 131858-37-2.mol

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3-FLUORO-4-NITROBENZYL BROMIDE Property

Melting point:: 46-48°C
Boiling point:: 311.6±27.0 °C(Predicted)
Density: 1.733±0.06 g/cm3(Predicted)
storage temp.: under inert gas (nitrogen or Argon) at 2-8°C
form: crystalline powder
color: Yellow
Sensitive: Lachrymatory
InChI: InChI=1S/C7H5BrFNO2/c8-4-5-1-2-7(10(11)12)6(9)3-5/h1-3H,4H2
InChIKey: ZOZJSWIXPIVMRU-UHFFFAOYSA-N
SMILES: C1([N+]([O-])=O)=CC=C(CBr)C=C1F
CAS DataBase Reference: 131858-37-2(CAS DataBase Reference)

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Safety

Hazard Codes: C
Risk Statements: 34-36/37/38
Safety Statements: 26-36/37/39
RIDADR: 1759
WGK Germany: WGK 3
Hazard Note: Corrosive/Lachrymatory
HazardClass: 8
PackingGroup: III
HS Code: 2904990090
Storage Class: 11 - Combustible Solids
Hazard Classifications: Acute Tox. 4 Oral
Eye Irrit. 2
Skin Irrit. 2
STOT SE 3

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P337+P313IF eye irritation persists: Get medical advice/attention.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: VBP00031
Product name: 3-Fluoro-4-nitrobenzyl bromide
Purity: Aldrich
Packaging: 1g
Price: $114
Updated: 2026/04/30

Matrix Scientific

Product number: 145078
Product name: 4-(Bromomethyl)-2-fluoro-1-nitrobenzene
Packaging: 5.00g
Price: $363
Updated: 2026/05/18

Matrix Scientific

Product number: 145078
Product name: 4-(Bromomethyl)-2-fluoro-1-nitrobenzene
Packaging: 10.00g
Price: $678
Updated: 2026/05/18

Crysdot

Product number: CD12153998
Product name: 4-(Bromomethyl)-2-fluoro-1-nitrobenzene
Purity: 97%
Packaging: 25g
Price: $361
Updated: 2026/05/20

TRC

Product number: F597618
Product name: 3-Fluoro-4-nitrobenzyl bromide
Packaging: 500mg
Price: $65
Updated: 2021/12/16

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3-FLUORO-4-NITROBENZYL BROMIDE Chemical Properties,Usage,Production

Chemical Reactivity

The reaction of 3-fluoro-4-nitrobenzyl bromide with lithium azaenolate of (S)-4-isopropyl-2,5-dimethoxy-2,5-dihydropyrazine gave only a poor yield (<10%) of alkylated product, presumably due to the high acidity of benzylic protons and more importantly, the presence of multi-electrophilic centers in 3-fluoro-4-nitrobenzyl bromide. ¹

References

[1]BERGGREN, D. TOWARDS THE SYNTHESIS OF DIKETOPIPERAZINE-CONTAINING MACROCYCLES VERGOU MARIA, CHEMIST SUPERVISORS: ASST. PROF. A. ZOGRAFOS.

3-FLUORO-4-NITROBENZYL BROMIDE Preparation Products And Raw materials

Raw materials

Preparation Products

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3-FLUORO-4-NITROBENZYL BROMIDE Suppliers

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131858-37-2, 3-FLUORO-4-NITROBENZYL BROMIDERelated Search:

Benzotrifluoride Benzyl bromide 2-FLUORO-4-NITROBENZYL BROMIDE 4-FLUORO-3-NITROBENZYL BROMIDE 4-FLUORO-2-NITROBENZYL BROMIDE 2-FLUORO-6-NITROBENZYL BROMIDE,2-Fluoro-6-nitrobenzyl bromide 98% 4-Nitrobenzyl bromide 2,5-DIFLUORO-4-NITROBENZYL BROMIDE 3-Fluorobenzyl bromide 3-Fluoro-4-nitrotoluene 3-FLUORO-4-NITROBENZYL BROMIDE

4-(Bromomethyl)-2-fluoronitrobenzene

4-(BroMoMethyl)-2-fluoro-1-nitrobenzene

4-(Bromomethyl)-2-fluoronitrobenzene, alpha-Bromo-3-fluoro-4-nitrotoluene

3-FLUORO-4-NITROBENZYL BROMIDE

Benzene, 4-(bromomethyl)-2-fluoro-1-nitro-

131858-37-2

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