Trimethyl(phenoxy)silane

Product Name: Trimethyl(phenoxy)silane
CAS No.: 1529-17-5
Chemical Name: Trimethyl(phenoxy)silane
Synonyms: DK553;DKSI224;Phenol, TMS ether;PHENOXYTRIMETHYLSILANE;Trimethylphenoxysilane;trimethylphenoxy-silan;TRIMETHYLSILYLPHENOXIDE;trimethylphenoxy-Silane;trimethyl-phenoxy-silane;(Trimethylsiloxy)benzene
CBNumber: CB4402745
Molecular Formula: C9H14OSi
Formula Weight: 166.29
MOL File: 1529-17-5.mol

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Trimethyl(phenoxy)silane Property

Melting point:: -55 °C
Boiling point:: 81 °C23 mm Hg(lit.)
Density: 0.92 g/mL at 25 °C(lit.)
refractive index: n20/D 1.478
Flash point:: 127 °F
storage temp.: Sealed in dry,Room Temperature
form: liquid
Specific Gravity: 0.92
color: Colorless to Light orange to Yellow
Hydrolytic Sensitivity: 7: reacts slowly with moisture/water
λmax: 274nm(Heptane)(lit.)
BRN: 1905943
InChIKey: OJAJJFGMKAZGRZ-UHFFFAOYSA-N
EPA Substance Registry System: Silane, trimethylphenoxy- (1529-17-5)

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Safety

Hazard Codes: Xi
Risk Statements: 10-36/37/38
Safety Statements: 26-36
RIDADR: UN 1993 3/PG 3
WGK Germany: 3
F: 10-21
TSCA: Yes
HazardClass: 3.2
PackingGroup: III
HS Code: 29319090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H226Flammable liquid and vapour

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 380415
Product name: Trimethyl(phenoxy)silane
Purity: 97%
Packaging: 10ml
Price: $73.5
Updated: 2023/06/20

TCI Chemical

Product number: T3222
Product name: Trimethyl(phenoxy)silane
Purity: >97.0%(GC)
Packaging: 5mL
Price: $49
Updated: 2024/03/01

TCI Chemical

Product number: T3222
Product name: Trimethyl(phenoxy)silane
Purity: >97.0%(GC)
Packaging: 25mL
Price: $140
Updated: 2024/03/01

Frontier Specialty Chemicals

Product number: JK494677
Product name: Phenoxytrimethylsilane
Purity: 97%
Packaging: 25g
Price: $143
Updated: 2021/12/16

AK Scientific

Product number: 9306AL
Product name: Trimethyl(phenoxy)silane
Packaging: 25g
Price: $168
Updated: 2021/12/16

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Trimethyl(phenoxy)silane Chemical Properties,Usage,Production

Chemical Properties

Clear colorless liquid

Uses

Trimethyl(phenoxy)silane can be used as a catalyst for the Friedel-Crafts reaction, which is an organic reaction that converts alkenes into alcohols or epoxides. It can also reacts with hydrochloric acid to give phenol and chloroform. Trimethyl(phenoxy)silane has been shown to have chemical properties similar to those of phenol, such as viscosity, chemical species and resonance spectroscopy properties. It can react with oxygen in the air to form peroxides, so it should be stored in a cool, dry place away from light.

General Description

Trimethyl(phenoxy)silane is a trimethylsilyl protected alcohol. Direct lateral zincation (DlZn) of trimethyl(phenoxy)silane has been reported. Dielectric studies of phenoxysilane-phenol binary systems has been reported.

Synthesis

General procedure for trimethylsilylation of alcohols with HMDS catalyzed by P2O5/Al2O3. P2O5/Al2O3 (0.1 g) was added to a stirred solution of the alcohol (10 mmol) and HMDS (7.5 mmol) and the mixture was stirred at room temperature for the time specified in Table 2. The reaction was followed by TLC (n-hexane-EtOAc, 9:1). After completion of the reaction, ethyl acetate was added to the reaction mixture and the catalyst was isolated by filtration. It was washed well with ethyl acetate (2 9 5 ml) and then dried at 100°C for 2 h before being used again. The filtered solution was evaporated and purified by passage through a short column of silica gel with n-hexane as eluent (2 x 20 ml). Evaporation of the solvent under reduced pressure gave the pure product Trimethyl(phenoxy)silane, Yield; 89%.

Trimethyl(phenoxy)silane Preparation Products And Raw materials

Raw materials

Preparation Products

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Trimethyl(phenoxy)silane Suppliers

Belgium 1 China 161 Czech 1 Germany 2 India 1 Japan 1 Singapore 1 Switzerland 1 The Netherlands 1 United Kingdom 2 United States 16 Global 188

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View Lastest Price from Trimethyl(phenoxy)silane manufacturers

Hebei Mojin Biotechnology Co., Ltd

Product: Phenoxytrimethylsilane 1529-17-5
Price: US $50.00/KG
Min. Order: 25KG
Purity: 99%
Supply Ability: 200ton
Release date: 2021-05-11

henan kanbei chemical co.,ltd

Product: Trimethylphenoxysilane 1529-17-5
Price: US $0.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 1000kg
Release date: 2022-09-19

Career Henan Chemical Co

Product: PHENOXYTRIMETHYLSILANE 1529-17-5
Price: US $2.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: customsie
Release date: 2018-08-20

1529-17-5, Trimethyl(phenoxy)silaneRelated Search:

TRIMETHYLSILYL METHACRYLATE METHOXYTRIMETHYLSILANE ISOPROPENYLOXYTRIMETHYLSILANE (3-BROMOPHENOXY)TRIMETHYLSILANE 1-BROMO-3-(TERT-BUTYLDIMETHYLSILOXY)BENZENE Trimethyl(phenoxy)silane (4-BROMOPHENOXY)TRIMETHYLSILANE 2-(TRIMETHYLSILOXY)BENZALDEHYDE P-TRIMETHYLSILOXYNITROBENZENE 4-(TRIMETHYLSILOXY)BENZALDEHYDE 3-(TERT-BUTYLDIMETHYLSILOXY)THIOPHENOL CHLOROMETHYL(2-CHLOROPHENOXY)DIMETHYLSILANE (4-BROMOPHENOXY)-TERT-BUTYLDIMETHYLSILANE 1,3-BIS(CHLOROMETHYLDIMETHYLSILOXY)BENZENE 3,5-BIS(TERT-BUTYLDIPHENYLSILYLOXY)BENZOIC ACID METHYL ESTER 3-(T-BUTYLDIMETHYLSILOXY)IODOBENZENE CHLOROMETHYL(4-CHLOROPHENOXY)DIMETHYLSILANE BIS(TRIMETHYLSILYL)BISPHENOL A

Phenoxy(trimethyl)silane, Phenyl trimethylsilyl ether

trimethylphenoxy-silan

Trimethylphenoxysilane

trimethyl-phenoxy-silane

trimethylphenoxy-Silane

Trimethylsilyl phenyl ether

PHENOXYTRIMETHYLSILANE, 97+%

(Trimethylsilyl)oxybenzene

PHENYL TRIMETHYLSILYL ETHER

PHENOXYTRIMETHYLSILANE

TRIMETHYLSILYLPHENOXIDE

(Trimethylsiloxy)benzene

O-(Trimethylsilyl)phenol

Phenol trimethylsilyl ether

Phenol, TMS ether

Silane, trimethylphenoxy-

Trimethyl(Phenoxy)Silane,>94%

Benzene, [(trimethylsilyl)oxy]-

DK553

DKSI224

1529-17-5

C6H5OSiCH33

Building Blocks

Protected Alcohols/Phenols

Oxygen Compounds

Organic Building Blocks

Building Blocks

Chemical Synthesis

Organic Building Blocks

Oxygen Compounds

Protected Alcohols/Phenols