ChemicalBook > CAS DataBase List > 2-AMINO-4-(4-CHLOROPHENYL)THIAZOLE

2-AMINO-4-(4-CHLOROPHENYL)THIAZOLE

Product Name
2-AMINO-4-(4-CHLOROPHENYL)THIAZOLE
CAS No.
2103-99-3
Chemical Name
2-AMINO-4-(4-CHLOROPHENYL)THIAZOLE
Synonyms
4-(4-CHLOROPHENYL)THIAZOL-2-AMINE;f1654;AURORA 13234;AKOS B000490;TOSLAB 14871;AKOS BBS-00000674;BUTTPARK 18\03-88;IFLAB-BB F1912-0041;TIMTEC-BB SBB000503;OTAVA-BB BB7010240509
CBNumber
CB4404608
Molecular Formula
C9H7ClN2S
Formula Weight
210.68
MOL File
2103-99-3.mol
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2-AMINO-4-(4-CHLOROPHENYL)THIAZOLE Property

Melting point:
169-171 °C(lit.)
Boiling point:
389.8±17.0 °C(Predicted)
Density 
1.389±0.06 g/cm3(Predicted)
storage temp. 
Keep in dark place,Inert atmosphere,Room temperature
pka
3.95±0.10(Predicted)
form 
Powder
color 
White to off-white
λmax
232nm(phosphate buffer sol.)(lit.)
BRN 
153889
LogP
3.411 (est)
CAS DataBase Reference
2103-99-3(CAS DataBase Reference)
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Safety

Hazard Codes 
Xi,Xn
Risk Statements 
36/37/38
Safety Statements 
26-36-36/37/39
RIDADR 
UN 2811 6.1/PG 3
WGK Germany 
3
RTECS 
XJ1026732
HazardClass 
IRRITANT
PackingGroup 
III
HS Code 
29341000
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H301Toxic if swalloed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
339369
Product name
2-Amino-4-(4-chlorophenyl)thiazole
Purity
98%
Packaging
1g
Price
$25.5
Updated
2023/01/07
TCI Chemical
Product number
A2841
Product name
2-Amino-4-(4-chlorophenyl)thiazole
Purity
>98.0%(GC)(T)
Packaging
1g
Price
$61
Updated
2025/07/31
TCI Chemical
Product number
A2841
Product name
2-Amino-4-(4-chlorophenyl)thiazole
Purity
>98.0%(GC)(T)
Packaging
5g
Price
$216
Updated
2025/07/31
TRC
Product number
A603205
Product name
2-Amino-4-(4-chlorophenyl)thiazole
Packaging
5g
Price
$365
Updated
2021/12/16
Oakwood
Product number
210746
Product name
4-(4-Chlorophenyl)thiazol-2-amine
Purity
95%
Packaging
100mg
Price
$10
Updated
2021/12/16
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2-AMINO-4-(4-CHLOROPHENYL)THIAZOLE Chemical Properties,Usage,Production

Chemical Properties

white to light yellow crystal powde

Uses

2-Amino-4-(4-chlorophenyl)thiazole was used in the preparation of 2-chloroacetamido-4-(4-chlorophenyl)thiazole.

Synthesis

17356-08-0

536-38-9

2103-99-3

GENERAL METHOD: A mixture of thiourea (1.2 mmol) and α-bromo-4-chloroacetophenone (1 mmol) in ethanol (2 mL) was stirred and reacted at 70 °C for 1 hour. After completion of the reaction, the mixture was cooled to room temperature, poured into ice water, filtered to collect the precipitate precipitated, and dried to obtain the target product 2-amino-4-(4-chlorophenyl)thiazole. The product yields and physical properties were as follows: [6a (99% yield), white solid, melting point 150-152 °C (literature value 26: 149-150 °C); 6b (100% yield), white solid, melting point 162-165 °C (literature value 26: 163-164 °C); 6c (0.236 g, 93% yield), white solid, melting point 179-181 °C (literature value 26: 180-181 °C); 6d (98% yield), white solid, melting point 203.6-204.2 °C (literature value 28/22: 204.0-204.5 °C); 6e (94% yield), bright yellow solid, melting point 287-288 °C (literature values 26,27: 285-286 °C); 6f (100% yield), white solid, melting point 172-174°C (literature values 29-31: 172°C).

References

[1] Arkivoc, 2018, vol. 2018, # 7, p. 110 - 118
[2] Chinese Chemical Letters, 2014, vol. 25, # 1, p. 172 - 175
[3] Research on Chemical Intermediates, 2015, vol. 41, # 11, p. 8099 - 8109
[4] Molecules, 2017, vol. 22, # 5,
[5] Synthetic Communications, 2009, vol. 39, # 16, p. 2895 - 2906

2-AMINO-4-(4-CHLOROPHENYL)THIAZOLE Preparation Products And Raw materials

Raw materials

Preparation Products

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2-AMINO-4-(4-CHLOROPHENYL)THIAZOLE Suppliers

J & K SCIENTIFIC LTD.
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18210857532; 18210857532
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86-10-82849933
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jkinfo@jkchemical.com
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China
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Meryer (Shanghai) Chemical Technology Co., Ltd.
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4006356688 18621169109
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86-21-61259102
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China
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Alfa Aesar
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400-6106006
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021-67582001/03/05
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saleschina@alfa-asia.com
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Energy Chemical
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sales8178@energy-chemical.com
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China
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Capot Chemical Co., Ltd
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+86 (0) 571 85 58 67 18
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0086-571-85864795
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China
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Beijing Ouhe Technology Co., Ltd
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+86-10-82967029
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2355560935@qq.com
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China
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Adamas Reagent, Ltd.
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Accela ChemBio Co.,Ltd.
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021-50795510 4000665055
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021-50795055
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sales@accelachem.com
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China
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Shanghai Hanhong Scientific Co.,Ltd.
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021-54306202 13764082696
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info@hanhongsci.com
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Syntechem Co.,Ltd
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Fax
E-Mail Inquiry
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View Lastest Price from 2-AMINO-4-(4-CHLOROPHENYL)THIAZOLE manufacturers

Career Henan Chemical Co
Product
2-AMINO-4-(4-CHLOROPHENYL)THIAZOLE 2103-99-3
Price
US $9.80/KG
Min. Order
1g
Purity
≥99%
Supply Ability
100kg
Release date
2020-01-10

2103-99-3, 2-AMINO-4-(4-CHLOROPHENYL)THIAZOLERelated Search:


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