2-AMINO-4-(4-CHLOROPHENYL)THIAZOLE

Product Name: 2-AMINO-4-(4-CHLOROPHENYL)THIAZOLE
CAS No.: 2103-99-3
Chemical Name: 2-AMINO-4-(4-CHLOROPHENYL)THIAZOLE
Synonyms: 4-(4-CHLOROPHENYL)THIAZOL-2-AMINE;f1654;AURORA 13234;AKOS B000490;TOSLAB 14871;AKOS BBS-00000674;BUTTPARK 18\03-88;IFLAB-BB F1912-0041;TIMTEC-BB SBB000503;OTAVA-BB BB7010240509
CBNumber: CB4404608
Molecular Formula: C9H7ClN2S
Formula Weight: 210.68
MOL File: 2103-99-3.mol

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2-AMINO-4-(4-CHLOROPHENYL)THIAZOLE Property

Melting point:: 169-171 °C(lit.)
Boiling point:: 389.8±17.0 °C(Predicted)
Density: 1.389±0.06 g/cm3(Predicted)
storage temp.: Keep in dark place,Inert atmosphere,Room temperature
pka: 3.95±0.10(Predicted)
form: Powder
color: White to off-white
λmax: 232nm(phosphate buffer sol.)(lit.)
BRN: 153889
InChI: 1S/C9H7ClN2S/c10-7-3-1-6(2-4-7)8-5-13-9(11)12-8/h1-5H,(H2,11,12)
InChIKey: DWGWNNCHJPKZNC-UHFFFAOYSA-N
SMILES: Nc1nc(cs1)-c2ccc(Cl)cc2
LogP: 3.411 (est)
CAS DataBase Reference: 2103-99-3(CAS DataBase Reference)

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Safety

Hazard Codes: Xi,Xn
Risk Statements: 36/37/38
Safety Statements: 26-36-36/37/39
RIDADR: UN 2811 6.1/PG 3
WGK Germany: 3
RTECS: XJ1026732
HazardClass: IRRITANT
PackingGroup: III
HS Code: 29341000
Storage Class: 6.1C - Combustible acute toxic Cat.3
toxic compounds or compounds which causing chronic effects
Hazard Classifications: Acute Tox. 3 Oral
Eye Irrit. 2
Skin Irrit. 2
STOT SE 3

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H301Toxic if swalloed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 339369
Product name: 2-Amino-4-(4-chlorophenyl)thiazole
Purity: 98%
Packaging: 1g
Price: $25.5
Updated: 2023/01/07

TCI Chemical

Product number: A2841
Product name: 2-Amino-4-(4-chlorophenyl)thiazole
Purity: >98.0%(GC)(T)
Packaging: 1g
Price: $61
Updated: 2025/07/31

TCI Chemical

Product number: A2841
Product name: 2-Amino-4-(4-chlorophenyl)thiazole
Purity: >98.0%(GC)(T)
Packaging: 5g
Price: $216
Updated: 2025/07/31

TRC

Product number: A603205
Product name: 2-Amino-4-(4-chlorophenyl)thiazole
Packaging: 5g
Price: $365
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FA36275
Product name: 2-Amino-4-(4-chlorophenyl)thiazole
Packaging: 2g
Price: $434
Updated: 2021/12/16

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2-AMINO-4-(4-CHLOROPHENYL)THIAZOLE Chemical Properties,Usage,Production

Chemical Properties

white to light yellow crystal powde

Uses

2-Amino-4-(4-chlorophenyl)thiazole was used in the preparation of 2-chloroacetamido-4-(4-chlorophenyl)thiazole.

Synthesis

17356-08-0

536-38-9

2103-99-3

GENERAL METHOD: A mixture of thiourea (1.2 mmol) and α-bromo-4-chloroacetophenone (1 mmol) in ethanol (2 mL) was stirred and reacted at 70 °C for 1 hour. After completion of the reaction, the mixture was cooled to room temperature, poured into ice water, filtered to collect the precipitate precipitated, and dried to obtain the target product 2-amino-4-(4-chlorophenyl)thiazole. The product yields and physical properties were as follows: [6a (99% yield), white solid, melting point 150-152 °C (literature value 26: 149-150 °C); 6b (100% yield), white solid, melting point 162-165 °C (literature value 26: 163-164 °C); 6c (0.236 g, 93% yield), white solid, melting point 179-181 °C (literature value 26: 180-181 °C); 6d (98% yield), white solid, melting point 203.6-204.2 °C (literature value 28/22: 204.0-204.5 °C); 6e (94% yield), bright yellow solid, melting point 287-288 °C (literature values 26,27: 285-286 °C); 6f (100% yield), white solid, melting point 172-174°C (literature values 29-31: 172°C).

References

[1] Arkivoc, 2018, vol. 2018, # 7, p. 110 - 118
[2] Chinese Chemical Letters, 2014, vol. 25, # 1, p. 172 - 175
[3] Research on Chemical Intermediates, 2015, vol. 41, # 11, p. 8099 - 8109
[4] Molecules, 2017, vol. 22, # 5,
[5] Synthetic Communications, 2009, vol. 39, # 16, p. 2895 - 2906

2-AMINO-4-(4-CHLOROPHENYL)THIAZOLE Preparation Products And Raw materials

Raw materials

Preparation Products

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2-AMINO-4-(4-CHLOROPHENYL)THIAZOLE Suppliers

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View Lastest Price from 2-AMINO-4-(4-CHLOROPHENYL)THIAZOLE manufacturers

Career Henan Chemical Co

Product: 2-AMINO-4-(4-CHLOROPHENYL)THIAZOLE 2103-99-3
Price: US $9.80/KG
Min. Order: 1g
Purity: ≥99%
Supply Ability: 100kg
Release date: 2020-01-10

2103-99-3, 2-AMINO-4-(4-CHLOROPHENYL)THIAZOLERelated Search:

2-AMINO-4-(4-CHLOROPHENYL)THIAZOLE 2-Amino-5-(4-chlorophenyl)thiazole ETHYL 2-AMINO-4-(4-CHLOROPHENYL)THIAZOLE-5-CARBOXYLATE Ethyl 2-amino-5-(4-chlorophenyl)thiazole-4-carboxylate Ethyl 2-amino-5-(3-chlorophenyl)thiazole-4-carboxylate Methyl 2-amino-4-(3-chlorophenyl)thiazole-5-carboxylate 2-CHLORO-N-[4-(4-CHLOROPHENYL)-1,3-THIAZOL-2-YL]ACETAMIDE N-[4-(4-CHLOROPHENYL)-1,3-THIAZOL-2-YL]-2-PIPERIDINOACETAMIDE Methyl 2-amino-4-(4-chlorophenyl)thiazole-5-carboxylate Methyl 2-amino-4-(2-chlorophenyl)thiazole-5-carboxylate 4-(4-CHLORO-PHENYL)-THIAZOLE 4-(4-CHLOROPHENYL)-3-METHYL-2-(4-([(5-METHYLISOXAZOL-3-YL)AMINO]SULFONYL)ANILINO)-1,3-THIAZOL-3-IUM BROMIDE 1-[4-(4-CHLOROPHENYL)-1,3-THIAZOL-2-YL]-3-PHENYL-1H-PYRAZOL-5-AMINE 2-AMINO-4-(4'-CHLORO-3'-METHYL)PHENYLTHIAZOLE 1-(4-(4-CHLOROPHENYL))-2-THIAZOLYL-1'-TERT-BUTYL-3,3'-DIMETHYL-5-HYDROXY[4,5']-BIPYRAZOL 2-[[Amino(amino)methylene]amino]-4-(3-chlorophenyl)thiazole 4-(4-CHLOROPHENYL)-2-(2,4-DIFLUOROANILINO)-3-PROPYL-1,3-THIAZOL-3-IUM BROMIDE 4-(4-CHLOROPHENYL)-2-(2,4-DIFLUOROANILINO)-3-METHYL-1,3-THIAZOL-3-IUM BROMIDE

2-AMINO 4(P-CHLORO)PHENYL THIAZOLE

2-AMINO-4-(4-CHLOROPHENYL)THIAZOLE

AKOS B000490

AKOS BBS-00000674

4-(4-CHLORO-PHENYL)-THIAZOL-2-YLAMINE

4-(4-CHLOROPHENYL)-1,3-THIAZOL-2-AMINE

AURORA 13234

BUTTPARK 18\03-88

IFLAB-BB F1912-0041

4-(4-chlorophenyl)-2-thiazolamin

4-(4-chlorophenyl)-2-thiazolamine

f1654

p-chlorophenyl-4amino-2thiazole

TOSLAB 14871

TIMTEC-BB SBB000503

OTAVA-BB BB7010240509

4-(4-CHLOROPHENYL)THIAZOL-2-AMINE

4-(4-chlorophenyl)-1,3-thiazol-2-ylamine

4-(4-chlorophenyl)-1,3-thiazol-2-amine(SALTDATA: FREE)

2-Thiazolamine, 4-(4-chlorophenyl)-

p-Chloro phenyl-4 amino-2 thiazole [French]

Thiazol-2-amine, 4-(4-chlorophenyl)-

Thiazole, 2-amino-4-(p-chlorophenyl)-

2-Amino-4-(4-chlorophenyl)thiazole 98%

JR-8887, 2-Amino-4-(4-chlorophenyl)thiazole, 97%

Histone acetyltransferase p300 Inhibitor 4c

2103-99-3

C9H7ClN2S

C9H7ClN2SBrH

Halogenated Heterocycles

Heterocyclic Building Blocks

Thiazoles

Building Blocks

Halogenated Heterocycles

Heterocyclic Building Blocks

Thiazoles

ThiazolesHeterocyclic Building Blocks

Building Blocks

C8 to C9

Chemical Synthesis

Halogenated Heterocycles

Heterocyclic Building Blocks