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N-ETHYLBENZISOXAZOLIUM TETRAFLUOROBORATE

Product Name
N-ETHYLBENZISOXAZOLIUM TETRAFLUOROBORATE
CAS No.
4611-62-5
Chemical Name
N-ETHYLBENZISOXAZOLIUM TETRAFLUOROBORATE
Synonyms
2-ethyl-2H-1λ,2-benzoxazol-1-ylium;N-ETHYLBENZISOXAZOLIUM FLUOROBORATE;N-ETHYLBENZISOXAZOLIUM TETRAFLUOROBORATE;2-ETHYL-1 2-BENZISOXAZOLIUM TETRAFLUORO&;2-ethyl-1,2-benzisoxazole tetrafluoroborate;2-ETHYL-1,2-BENZISOXAZOLIUM TETRAFLUOROBORATE;N-Ethylbenzisoxazolium tetrafluoroborate, 98+%
CBNumber
CB4413871
Molecular Formula
C9H10BF4NO
Formula Weight
234.99
MOL File
4611-62-5.mol
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N-ETHYLBENZISOXAZOLIUM TETRAFLUOROBORATE Property

Melting point:
108-110 °C(lit.)
storage temp. 
Store at 0-5°C
solubility 
sol acetonitrile; slightly sol dichloromethane; sol aqueous acid (unstable above pH 4).
form 
crystalline solid
Sensitive 
Hygroscopic
CAS DataBase Reference
4611-62-5(CAS DataBase Reference)
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Safety

Risk Statements 
36/37/38
Safety Statements 
22-24/25
WGK Germany 
3
3-8-10-21
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
S617024
Product name
N-ETHYLBENZISOXAZOLIUM FLUOROBORATE
Purity
Aldrich
Packaging
250mg
Price
$29.8
Updated
2024/03/01
Alfa Aesar
Product number
B23794
Product name
N-Ethylbenzisoxazolium tetrafluoroborate, 98+%
Packaging
1g
Price
$20
Updated
2021/12/16
Alfa Aesar
Product number
B23794
Product name
N-Ethylbenzisoxazolium tetrafluoroborate, 98+%
Packaging
5g
Price
$71.9
Updated
2021/12/16
Alfa Aesar
Product number
B23794
Product name
N-Ethylbenzisoxazolium tetrafluoroborate, 98+%
Packaging
25g
Price
$279
Updated
2021/12/16
AK Scientific
Product number
7553AH
Product name
N-Ethylbenzisoxazoliumtetrafluoroborate
Packaging
1g
Price
$105
Updated
2021/12/16
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N-ETHYLBENZISOXAZOLIUM TETRAFLUOROBORATE Chemical Properties,Usage,Production

Description

N-Ethylbenzisoxazolium Tetrafluoroborate is a peptide-coupling reagent; reacts with a wide range of nucleophiles to give o-hydroxy-N-ethylbenzamido derivatives.

Synthesis

N-Ethylbenzisoxazolium Tetrafluoroborate is prepared by ethylation of benzisoxazole with purified Triethyloxonium Tetrafluoroborate.

storage

The salt is reported not to be hygroscopic, although it etches glass on long exposure to moist air; should be protected from light; reported to be an irritant.

Purification Methods

Recrystallise it from MeCN/EtOAc to give magnificent crystals. It is not hygroscopic but on long exposure to moisture it etches glass. It is light-sensitive and should be stored in brown glass bottles. UV (H2O), max 258nm ( 13 100) and 297nm ( 2 900), IR (CH2Cl2): max 1613 (C=N) and 1111-1000 (BF 4 ) [UV, IR, NMR: Kemp & Woodward Tetrahedron 21 3019 1965].

N-ETHYLBENZISOXAZOLIUM TETRAFLUOROBORATE Preparation Products And Raw materials

Raw materials

Preparation Products

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N-ETHYLBENZISOXAZOLIUM TETRAFLUOROBORATE Suppliers

Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
021-61259108 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40228
Advantage
62
Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30123
Advantage
84
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44689
Advantage
61
Guangzhou Jhd Chemical Reagent Co., Ltd.
Tel
020-84383047
Fax
020-84380294
Email
sales@jhd.com.cn
Country
China
ProdList
9186
Advantage
65
Career Henan Chemica Co
Tel
+86-0371-86658258 +8613203830695
Fax
0371-86658258
Email
laboratory@coreychem.com
Country
China
ProdList
30236
Advantage
58
XIAMEN AMITY INDUSTRY AND TRADE CO., LTD.
Tel
+8618950047208
Email
ellena@amitychem.com
Country
China
ProdList
43416
Advantage
58
Beijing dtftchem Technology Co., Ltd.
Tel
13651141086
Fax
86 (10) 60270825
Email
dtftchem@sina.com
Country
China
ProdList
3380
Advantage
62

4611-62-5, N-ETHYLBENZISOXAZOLIUM TETRAFLUOROBORATERelated Search:


  • 2-ETHYL-1,2-BENZISOXAZOLIUM TETRAFLUOROBORATE
  • N-ETHYLBENZISOXAZOLIUM TETRAFLUOROBORATE
  • 2-ethyl-1,2-benzisoxazole tetrafluoroborate
  • 2-ETHYL-1 2-BENZISOXAZOLIUM TETRAFLUORO&
  • N-Ethylbenzisoxazolium tetrafluoroborate, 98+%
  • N-ETHYLBENZISOXAZOLIUM FLUOROBORATE
  • 2-ethyl-2H-1λ,2-benzoxazol-1-ylium
  • 4611-62-5
  • C9H10BF4NO
  • C9H14BNO
  • C9H10NOBF4