1-Pyrenylboronic acid

Product Name: 1-Pyrenylboronic acid
CAS No.: 164461-18-1
Chemical Name: 1-Pyrenylboronic acid
Synonyms: 1-Boronopyrene;1-PYRENEBORONIC ACID;CAS:164461-18-1;1-Pyrenyboronic acid;1-Pyrenylboronic aci;PYRENE-1-BORONIC ACID;1-PYRENYLBORONIC ACID;Pyren-1-ylboronic acid;B-1-Pyrenylboronic acid;Pyrene-1-boronic acid 97%
CBNumber: CB4429775
Molecular Formula: C16H11BO2
Formula Weight: 246.07
MOL File: 164461-18-1.mol

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1-Pyrenylboronic acid Property

Melting point:: 247-251 °C(lit.)
Boiling point:: 509.4±33.0 °C(Predicted)
Density: 1.35±0.1 g/cm3(Predicted)
storage temp.: Keep in dark place,Sealed in dry,Room Temperature
pka: 8.53±0.30(Predicted)
form: Powder
color: Pale yellow
Water Solubility: Slightly soluble in water.
InChI: InChI=1S/C16H11BO2/c18-17(19)14-9-7-12-5-4-10-2-1-3-11-6-8-13(14)16(12)15(10)11/h1-9,18-19H
InChIKey: MWEKPLLMFXIZOC-UHFFFAOYSA-N
SMILES: B(C1=C2C3=C4C(C=C2)=CC=CC4=CC=C3C=C1)(O)O
CAS DataBase Reference: 164461-18-1(CAS DataBase Reference)

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Safety

Safety Statements: 24/25
WGK Germany: 3
HS Code: 29319090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 542873
Product name: Pyrene-1-boronic acid
Purity: ≥95.0%
Packaging: 1g
Price: $76.4
Updated: 2025/07/31

Sigma-Aldrich

Product number: 542873
Product name: Pyrene-1-boronic acid
Purity: ≥95.0%
Packaging: 5g
Price: $100.42
Updated: 2025/07/31

TCI Chemical

Product number: P1625
Product name: 1-Pyreneboronic Acid (contains varying amounts of Anhydride)
Packaging: 1g
Price: $38
Updated: 2025/07/31

TCI Chemical

Product number: P1625
Product name: 1-Pyreneboronic Acid (contains varying amounts of Anhydride)
Packaging: 5g
Price: $123
Updated: 2025/07/31

TCI Chemical

Product number: P1625
Product name: 1-Pyreneboronic Acid (contains varying amounts of Anhydride)
Packaging: 25g
Price: $398
Updated: 2025/07/31

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1-Pyrenylboronic acid Chemical Properties,Usage,Production

Chemical Properties

White to light brown solid

Uses

It is an important raw material and intermediate used in organic synthesis agrochemical, pharmaceutical and dyestuff field. Also used as a intermediate for organic light-emitting diode(OLED).

Uses

suzuki reaction

Synthesis

121-43-7

1714-29-0

164461-18-1

The general procedure for the synthesis of 1-pyrenylboronic acid from trimethyl borate and 1-bromopyrene was as follows: 1-bromopyrene (30 g, 107 mmol) was added to a round-bottom flask and dissolved in 240 mL of tetrahydrofuran (THF). Under cooling conditions, n-BuLi (1.6 M, 80 mL) in hexane was slowly added dropwise, keeping the reaction temperature at -78 °C. After the dropwise addition was completed, the reaction mixture continued to be stirred at -78 °C for about 1 hour. Subsequently, trimethyl borate (15.5 g, 149 mmol) was added and stirring was continued at -78 °C for 1 hour. After that, the reaction mixture was warmed up to room temperature and stirred for about 2 hours. After completion of the reaction, the reaction solution was adjusted to acidic with 2N HCl. Extraction was carried out with ethyl acetate (EA) and hexane, and the organic phases were combined and concentrated under reduced pressure to remove the solvent to give 19.5 g of 1-pyrenylboronic acid in 74% yield.

References

[1] Patent: KR101515814, 2015, B1. Location in patent: Paragraph 0343; 0344
[2] Patent: KR101503771, 2015, B1. Location in patent: Paragraph 0215; 0216
[3] Patent: US2014/131664, 2014, A1. Location in patent: Paragraph 0025-0026
[4] Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1998, # 7, p. 1263 - 1268
[5] ChemPlusChem, 2013, vol. 78, # 10, p. 1288 - 1295

1-Pyrenylboronic acid Preparation Products And Raw materials

Raw materials

Preparation Products

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1-Pyrenylboronic acid Suppliers

Americas 1 China 264 Germany 4 India 5 Japan 2 Switzerland 1 United Kingdom 1 United States 16 Global 294

Springchem New Material Technology Co.,Ltd

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Energy Chemical

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View Lastest Price from 1-Pyrenylboronic acid manufacturers

LY Global chemicals co.,ltd .

Product: 1-Pyrenylboronic acid 164461-18-1
Price: US $0.00-0.00/kg
Min. Order: 1kg
Purity: 98%Min
Supply Ability: 1000kg
Release date: 2023-03-12

Xinxiang Hongqi District Houyuan Trading Co.,Ltd

Product: 1-Pyrenylboronic acid 164461-18-1
Price: US $30.00-28.00/Kg
Min. Order: 1Kg
Purity: 99.0% up
Supply Ability: 20 tons per month
Release date: 2022-09-22

Zhuozhou Wenxi import and Export Co., Ltd

Product: 1-Pyrenylboronic acid 164461-18-1
Price: US $15.00-10.00/KG
Min. Order: 1KG
Purity: 99%+ HPLC
Supply Ability: Monthly supply of 1 ton
Release date: 2021-07-10

164461-18-1, 1-Pyrenylboronic acidRelated Search:

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1-Pyreneboronic acid, 96%, for synthesis

CAS:164461-18-1

164461-18-1

164464-18-1

C16H11BO2

Boronic Acids

B (Classes of Boron Compounds)

Pyrenes

Organometallic Reagents

Boronic Acids and Derivatives

Aryl

OLED materials,pharm chemical,electronic

Aryl Boronic Acids

Boronic Acids and Derivatives

Chemical Synthesis

Organometallic Reagents

Unsubstituted Aryl Boronic Acids

fine chemicals, specialty chemicals, intermediates, electronic chemical, organic synthesis

fine chemicals, specialty chemicals, intermediates, electronic chemical, organic synthesis, functional materials

Boron Compounds

blocks

BoronicAcids

Electronic Chemicals

B (Classes of Boron Compounds)

Boronic Acids

Pyrenes

OLED