ChemicalBook > CAS DataBase List > 4-(BENZYLOXY)PYRIDINE

4-(BENZYLOXY)PYRIDINE

Product Name: 4-(BENZYLOXY)PYRIDINE
CAS No.: 49826-70-2
Chemical Name: 4-(BENZYLOXY)PYRIDINE
Synonyms: 4-(BENZYLOXY)PYRIDINE;4-BENZYLOXYPYRIDINE(I);4-phenylmethoxypyridine;Pyridine,4-(phenylmethoxy)-;4-[(Phenylmethyl)oxy]pyridine;ETHYL3-(CYANOMETHYL)-2-OXO-2,3-DIHYDRO-1H-BENZO[D]IMIDAZOLE-3-CARBOXYLATE
CBNumber: CB4445829
Molecular Formula: C12H11NO
Formula Weight: 185.22
MOL File: 49826-70-2.mol

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4-(BENZYLOXY)PYRIDINE Property

Melting point:: 57-58℃
Boiling point:: 310℃
Density: 1.106
Flash point:: 114℃
storage temp.: Inert atmosphere,Room Temperature
pka: 6.58±0.10(Predicted)
Appearance: Off-white to light yellow Solid

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Safety

HS Code: 2933399990

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Apolloscientific

Product number: OR942402
Product name: 4-(Benzyloxy)pyridine
Purity: 95%
Packaging: 250mg
Price: $203
Updated: 2021/12/16

Apolloscientific

Product number: OR942402
Product name: 4-(Benzyloxy)pyridine
Purity: 95%
Packaging: 1g
Price: $486
Updated: 2021/12/16

American Custom Chemicals Corporation

Product number: CHM0378179
Product name: 4-(BENZYLOXY)PYRIDINE
Purity: 95.00%
Packaging: 5MG
Price: $503.16
Updated: 2021/12/16

AK Scientific

Product number: 2549AL
Product name: 4-(Benzyloxy)pyridine
Packaging: 5g
Price: $840
Updated: 2021/12/16

AK Scientific

Product number: 2549AL
Product name: 4-(Benzyloxy)pyridine
Packaging: 10g
Price: $1245
Updated: 2021/12/16

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4-(BENZYLOXY)PYRIDINE Chemical Properties,Usage,Production

Synthesis

7379-35-3

100-51-6

49826-70-2

Sodium hydride (60% mineral oil dispersion, 0.72 g, 18.0 mmol) was added to a dry reaction flask, followed by the addition of N,N-dimethylformamide (30 mL) to form a suspension, and the mixture was cooled to 5 °C. Under stirring, benzyl alcohol (1.04 mL, 10.0 mmol) was slowly added dropwise. After dropwise addition, stirring was continued for 15 minutes. Subsequently, 4-chloropyridine hydrochloride (1.00 g, 6.67 mmol) was added in batches, with each addition approximately 5 minutes apart. After the addition was completed, the reaction mixture was stirred at 5°C for 10 minutes, then gradually warmed to 60°C and stirred at this temperature for 1.5 hours. After completion of the reaction, the mixture was cooled to room temperature (23°C), the reaction was quenched by the addition of water and extracted with ethyl acetate. The organic phases were combined, dried with anhydrous magnesium sulfate, filtered and concentrated under reduced pressure. The crude product was purified by silica gel column chromatography with gradient elution of hexane solution with 5% to 50% ethyl acetate as eluent to give the target product 4-benzyloxypyridine (1.10 g, 89% yield).

References

[1] Journal of Organic Chemistry, 2017, vol. 82, # 24, p. 13756 - 13767
[2] Patent: US2011/275627, 2011, A1. Location in patent: Page/Page column 60
[3] Patent: EP2331541, 2011, A1. Location in patent: Paragraph 0070; 0071
[4] Patent: EP2331541, 2015, B1. Location in patent: Paragraph 0070; 0071

4-(BENZYLOXY)PYRIDINE Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from 4-(BENZYLOXY)PYRIDINE manufacturers

Shaanxi Dideu New Materials Co. Ltd

Product: 4-(BENZYLOXY)PYRIDINE 49826-70-2
Price: US $0.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 10000KGS
Release date: 2025-07-26

Career Henan Chemical Co

Product: 4-phenylmethoxypyridine 49826-70-2
Price: US $9.80/KG
Min. Order: 1KG
Purity: ≥98%
Supply Ability: 20 tons
Release date: 2020-01-09

49826-70-2, 4-(BENZYLOXY)PYRIDINERelated Search:

2-PHENYL-2-(PYRIDIN-4-YLOXY)-ETHYLAMINE 4-(Benzyloxy)pyridine N-oxide 3,5-DICHLORO-2,6-DIFLUORO-4-BENZYLOXYPYRIDINE 4-BENZYLOXY-QUINOLIN-2-OL 4-(BENZYLOXY)-2-(CHLOROMETHYL)PYRIDINE Diethyl 4-(phenylmethoxy)-2,6-pyridinedicarboxylate 4-BENZYLOXY-2(1 H)-PYRIDONE Bis(phenylmethyl) 4-(phenylmethoxy)-2,6-pyridinedicarboxylate 4-(BENZYLOXY)PYRIDINE 4-BENZYLOXY-QUINOLINE

4-(BENZYLOXY)PYRIDINE

4-BENZYLOXYPYRIDINE(I)

4-[(Phenylmethyl)oxy]pyridine

Pyridine,4-(phenylmethoxy)-

4-phenylmethoxypyridine

ETHYL3-(CYANOMETHYL)-2-OXO-2,3-DIHYDRO-1H-BENZO[D]IMIDAZOLE-3-CARBOXYLATE

49826-70-2