ChemicalBook > CAS DataBase List > 1-Bromohexane
1-Bromohexane
Chemical nature Synthesis and reactions- Product Name
- 1-Bromohexane
- CAS No.
- 111-25-1
- Chemical Name
- 1-Bromohexane
- Synonyms
- N-HEXYL BROMIDE;Bromohexane;Hexylbromid;1-Bromhexan;HEXYL BROMIDE;1-BROMOHEXANE;1-bromo-hexan;N-BROMOHEXANE;JACS-111-25-1;1-hexylbromide
- CBNumber
- CB4447030
- Molecular Formula
- C6H13Br
- Formula Weight
- 165.07
- MOL File
- 111-25-1.mol
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1-Bromohexane Property
- Melting point:
- −85 °C(lit.)
- Boiling point:
- 154-158 °C(lit.)
- Density
- 1.176 g/mL at 25 °C(lit.)
- vapor density
- 5.7 (vs air)
- vapor pressure
- <10 mm Hg ( 20 °C)
- refractive index
- n20/D 1.448(lit.)
- Flash point:
- 135 °F
- storage temp.
- Store below +30°C.
- solubility
- <1g/l
- form
- Liquid
- color
- Clear
- Water Solubility
- Immiscible with water.
- BRN
- 1731290
- Dielectric constant
- 5.8（24℃）
- Stability:
- Stable. Incompatible with strong oxidizing agents, strong bases. Combustible.
- InChIKey
- MNDIARAMWBIKFW-UHFFFAOYSA-N
- CAS DataBase Reference
- 111-25-1(CAS DataBase Reference)
- NIST Chemistry Reference
- Hexane, 1-bromo-(111-25-1)
- EPA Substance Registry System
- Hexane, 1-bromo- (111-25-1)
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Safety
- Hazard Codes
- Xi
- Risk Statements
- 36/37/38-10
- Safety Statements
- 26-36-16
- RIDADR
- UN 1993 3/PG 3
- WGK Germany
- 2
- RTECS
- MO0925000
- TSCA
- Yes
- HazardClass
- 3
- PackingGroup
- III
- HS Code
- 29033036
- Toxicity
- LD50 orally in Rabbit: > 2000 mg/kg
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Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H226Flammable liquid and vapour
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P233Keep container tightly closed.
P240Ground/bond container and receiving equipment.
P241Use explosion-proof electrical/ventilating/lighting/…/equipment.
P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
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N-Bromosuccinimide Price
Sigma-Aldrich
- Product number
- B68240
- Product name
- 1-Bromohexane
- Purity
- 98%
- Packaging
- 100g
- Price
- $23.5
- Updated
- 2024/03/01
Sigma-Aldrich
- Product number
- B68240
- Product name
- 1-Bromohexane
- Purity
- 98%
- Packaging
- 1kg
- Price
- $171
- Updated
- 2024/03/01
Sigma-Aldrich
- Product number
- 8.01603
- Product name
- 1-Bromohexane
- Purity
- for synthesis
- Packaging
- 100mL
- Price
- $40
- Updated
- 2024/03/01
Sigma-Aldrich
- Product number
- 8.01603
- Product name
- 1-Bromohexane
- Purity
- for synthesis
- Packaging
- 500mL
- Price
- $67.3
- Updated
- 2024/03/01
TCI Chemical
- Product number
- B0600
- Product name
- 1-Bromohexane
- Purity
- >98.0%(GC)
- Packaging
- 25g
- Price
- $25
- Updated
- 2024/03/01
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1-Bromohexane Chemical Properties,Usage,Production
Chemical nature
1-Bromohexane is organobromine compound with formula Br(CH2)5CH3. It is a colorless liquid.
Synthesis and reactions
Most 1-bromoalkanes are prepared by free-radical addition of hydrogen bromide to the 1-alkene. These conditions lead to anti-Markovnikov addition, giving the 1-bromo derivative.
1-Bromohexane undergoes reactions expected of simple alkyl bromides. It can form Grignard reagents. It reacts with potassium fluoride to give the corresponding fluorocarbons.
Chemical Properties
1-Bromohexane is a colourless liquid organohalide. It is a solvent that is frequently used in grignard reactions. It is also used as Intermediate, for introduction of hexyl group.
Uses
1-Bromohexane is utilized in the preparation of pharmaceuticals and organic chemicals. It is involved in Grignard reactions as an alkylating agent and in the synthesis of bromo-cyclic compounds.
Application
1-Bromohexane is a very useful synthetic intermediate，it can be used to react with Mg to prepare Grignard reagents which play an important role in formation of carbon-carbon bond.
Synthesis Reference(s)
Chemistry Letters, 7, p. 833, 1978
Synthetic Communications, 6, p. 21, 1976 DOI: 10.1080/00397917608062128
Tetrahedron, 40, p. 641, 1984 DOI: 10.1016/S0040-4020(01)91092-0
Purification Methods
Shake the bromide with H2SO4, wash with water, dry (K2CO3) and fractionally distil. [Beilstein 1 IV 352.]
1-Bromohexane Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from 1-Bromohexane manufacturers
Henan Fengda Chemical Co., Ltd
- Product
- 1-Bromohexane 111-25-1
- Price
- US $100.00-1.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- g-kg-tons, free sample is available
- Release date
- 2023-12-25
Hebei Yanxi Chemical Co., Ltd.
- Product
- 1-Bromohexane 111-25-1
- Price
- US $0.00/kg
- Min. Order
- 1kg
- Purity
- 0.99
- Supply Ability
- 20tons
- Release date
- 2023-10-13
Firsky International Trade (Wuhan) Co., Ltd
- Product
- 1-Bromohexane 111-25-1
- Price
- US $30.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 20T
- Release date
- 2023-10-07
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