Chemical nature Synthesis and reactions
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1-Bromohexane

Chemical nature Synthesis and reactions
Product Name
1-Bromohexane
CAS No.
111-25-1
Chemical Name
1-Bromohexane
Synonyms
Bromohexane;Hexylbromid;1-Bromhexan;HEXYL BROMIDE;1-BROMOHEXANE;1-bromo-hexan;N-BROMOHEXANE;JACS-111-25-1;1-hexylbromide;N-Hexyl romide
CBNumber
CB4447030
Molecular Formula
C6H13Br
Formula Weight
165.07
MOL File
111-25-1.mol
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1-Bromohexane Property

Melting point:
−85 °C(lit.)
Boiling point:
154-158 °C(lit.)
Density 
1.176 g/mL at 25 °C(lit.)
vapor density 
5.7 (vs air)
vapor pressure 
<10 mm Hg ( 20 °C)
refractive index 
n20/D 1.448(lit.)
Flash point:
135 °F
storage temp. 
Store below +30°C.
solubility 
<1g/l
form 
Liquid
color 
Clear
Water Solubility 
Immiscible with water.
BRN 
1731290
Stability:
Stable. Incompatible with strong oxidizing agents, strong bases. Combustible.
InChIKey
MNDIARAMWBIKFW-UHFFFAOYSA-N
CAS DataBase Reference
111-25-1(CAS DataBase Reference)
NIST Chemistry Reference
Hexane, 1-bromo-(111-25-1)
EPA Substance Registry System
Hexane, 1-bromo- (111-25-1)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38-10
Safety Statements 
26-36-16
RIDADR 
UN 1993 3/PG 3
WGK Germany 
2
RTECS 
MO0925000
TSCA 
Yes
HazardClass 
3
PackingGroup 
III
HS Code 
29033036
Toxicity
LD50 orally in Rabbit: > 2000 mg/kg
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H226Flammable liquid and vapour

H303May be harmfulif swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

H401Toxic to aquatic life

H411Toxic to aquatic life with long lasting effects

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P233Keep container tightly closed.

P240Ground/bond container and receiving equipment.

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P337+P313IF eye irritation persists: Get medical advice/attention.

P403+P235Store in a well-ventilated place. Keep cool.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
B68240
Product name
1-Bromohexane
Purity
98%
Packaging
100g
Price
$21.4
Updated
2021/03/22
Sigma-Aldrich
Product number
8.01603
Product name
1-Bromohexane
Purity
for synthesis
Packaging
100 mL
Price
$29.51
Updated
2021/03/22
Sigma-Aldrich
Product number
8.01603
Product name
1-Bromohexane
Purity
for synthesis
Packaging
500 mL
Price
$49.58
Updated
2021/03/22
Sigma-Aldrich
Product number
B68240
Product name
1-Bromohexane
Purity
98%
Packaging
1kg
Price
$141
Updated
2021/03/22
TCI Chemical
Product number
B0600
Product name
1-Bromohexane
Purity
>98.0%(GC)
Packaging
25g
Price
$14
Updated
2021/03/22
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1-Bromohexane Chemical Properties,Usage,Production

Chemical nature

1-Bromohexane is organobromine compound with formula Br(CH2)5CH3. It is a colorless liquid.

Synthesis and reactions

Most 1-bromoalkanes are prepared by free-radical addition of hydrogen bromide to the 1-alkene. These conditions lead to anti-Markovnikov addition, giving the 1-bromo derivative.
1-Bromohexane undergoes reactions expected of simple alkyl bromides. It can form Grignard reagents. It reacts with potassium fluoride to give the corresponding fluorocarbons.

Chemical Properties

colourless liquid

Uses

Intermediate, for introduction of hexyl group.

Synthesis Reference(s)

Chemistry Letters, 7, p. 833, 1978
Synthetic Communications, 6, p. 21, 1976 DOI: 10.1080/00397917608062128
Tetrahedron, 40, p. 641, 1984 DOI: 10.1016/S0040-4020(01)91092-0

Purification Methods

Shake the bromide with H2SO4, wash with water, dry (K2CO3) and fractionally distil. [Beilstein 1 IV 352.]

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View Lastest Price from 1-Bromohexane manufacturers

HEBEI YINGONG NEW MATERIAL TECHNOLOGY CO.,LTD
Product
Hexylbromid 111-25-1
Price
US $160.00/ASSAYS
Min. Order
10g/ml
Purity
99.9%
Supply Ability
10 mt
Release date
2021-11-08
Zhuozhou Wenxi import and Export Co., Ltd
Product
1-Bromohexane 98% 111-25-1
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-06-26
HONG KONG IPURE BIOLOGY CO.,LIMITED
Product
1-Bromohexane 111-25-1
Price
US $1.00/BOU/Drum
Min. Order
1KG
Purity
98%
Supply Ability
1kg
Release date
2020-11-23

111-25-1, 1-BromohexaneRelated Search:


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