Identification Description Usage Natural occurrence
ChemicalBook > CAS DataBase List > 5-Methyl-2-acetylfuran

5-Methyl-2-acetylfuran

Identification Description Usage Natural occurrence
Product Name
5-Methyl-2-acetylfuran
CAS No.
1193-79-9
Chemical Name
5-Methyl-2-acetylfuran
Synonyms
FEMA 3609;2-Acetyl, 5-mefuran;5-Methyl-2-acetalfuran;2-acetyl-5-methyl-fura;2-ACETYL-5-METHYLFURAN;2-METHYL-5-ACETYLFURAN;5-Acetyl-2-methylfuran;5-Methyl-Z-acetylfuran;5-Methy-2-Acetyl lfuran;2-ACETYL-5-METHYLFURANE
CBNumber
CB4460042
Molecular Formula
C7H8O2
Formula Weight
124.14
MOL File
1193-79-9.mol
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5-Methyl-2-acetylfuran Property

Melting point:
2 °C
Boiling point:
100-101 °C/25 mmHg (lit.)
Density 
1.066 g/mL at 25 °C (lit.)
vapor density 
>1 (vs air)
refractive index 
n20/D 1.512(lit.)
FEMA 
3609 | 2-ACETYL-5-METHYLFURAN
Flash point:
176 °F
storage temp. 
Inert atmosphere,Room Temperature
solubility 
Chloroform (Soluble), Methanol (Slightly)
form 
clear liquid
Specific Gravity
1.066
color 
Light yellow to Brown
Odor
at 0.10 % in dipropylene glycol. strong musty nutty hay coconut coumarin milky
Odor Type
nutty
biological source
synthetic
Water Solubility 
Slightly soluble in water. Soluble in alcohol.
JECFA Number
1504
BRN 
110853
LogP
0.98
CAS DataBase Reference
1193-79-9(CAS DataBase Reference)
NIST Chemistry Reference
2-Acetyl-5-methylfuran(1193-79-9)
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Safety

Hazard Codes 
Xn,Xi
Risk Statements 
22
Safety Statements 
36
RIDADR 
2810
WGK Germany 
3
RTECS 
LT8528000
Hazard Note 
Harmful
HazardClass 
6.1(b)
PackingGroup 
III
HS Code 
29321900
Toxicity
mouse,LD50,oral,438mg/kg (438mg/kg),Drug and Chemical Toxicology. Vol. 3, Pg. 249, 1980.
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H227Combustible liquid

H301Toxic if swalloed

H302Harmful if swallowed

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P370+P378In case of fire: Use … for extinction.

P403+P235Store in a well-ventilated place. Keep cool.

P405Store locked up.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
W360902
Product name
2-Acetyl-5-methylfuran
Purity
≥98%, FG
Packaging
25g
Price
$68.7
Updated
2025/07/31
Sigma-Aldrich
Product number
W360902
Product name
2-Acetyl-5-methylfuran
Purity
≥98%, FG
Packaging
100g
Price
$85.59
Updated
2025/07/31
Sigma-Aldrich
Product number
W360902
Product name
2-Acetyl-5-methylfuran
Purity
≥98%, FG
Packaging
1kg
Price
$382
Updated
2025/07/31
Sigma-Aldrich
Product number
299553
Product name
2-Acetyl-5-methylfuran
Purity
98%
Packaging
25g
Price
$71.2
Updated
2025/07/31
Sigma-Aldrich
Product number
299553
Product name
2-Acetyl-5-methylfuran
Purity
98%
Packaging
5g
Price
$35.8
Updated
2023/06/20
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5-Methyl-2-acetylfuran Chemical Properties,Usage,Production

Identification

CAS.No.: 
1193-79-9 
FL.No.: 
13.083
FEMA.No.: 
3609
NAS.No.: 
3609
CoE.No.: 
11038
EINECS.No.: 
214-779-1 
JECFA.No.: 
1504
 
 

Description

A light yellow liquid with strong, nutty aroma.

Usage

Reported uses (ppm): (FEMA, 1994)

Food Category 
Usual 
Max. 
Gravies 
1
1.5
Nut.products 
0.5
1.5
Snack.foods 
1
2
Soups 
0.5
1.5

Natural occurrence

Reported found in coffee, roasted filberts, tomato juice, raisin, roasted onion, French fried potato, crispbread, smoked fatty fish, boiled/cooked beef, fried cured pork, beer, cognac, rum, malt whiskey, cocoa, black tea, wild rice (Zizania aquatuca), and squid.

Chemical Properties

Colorless to light yellow liqui

Chemical Properties

A light yellow liquid with strong, nutty aroma.

Occurrence

Reported found in coffee, roasted filberts, tomato juice, raisin, roasted onion, French fried potato, crispbread, smoked fatty fish, boiled/cooked beef, fried cured pork, beer, cognac, rum, malt whiskey, cocoa, black tea, wild rice (Zizania aquatuca), and squid.

Uses

Glucose was transformed to various furan compounds and carboxylic acids derivatives by heat treatment of autoclave such as levulinic acid, 2-acetylfuran and 2-acetyl-5-methylfuran. using 2-acetyl-5-methylfuran or 1,5-dimethyl-2-pyrrolecarbonitrile as reactants, that the formation of the 4-arylation products. Reaction of 2-acetyl-5-methylfuran 6a with 2-aminoethanol pioduced in 79% yield the aminal.

Definition

ChEBI: A furan carrying acetyl and methyl substituents at the 2- and 5-positions respectively.

Taste threshold values

Taste characteristics at 50 ppm: nutty, cocoa-like with toasted, bready nuance

General Description

s-cis-trans isomerism of 2-acetyl-5-methylfuran was investigated by IR and NMR spectroscopy.

Synthesis

534-22-5

108-24-7

1193-79-9

General procedure for the synthesis of 5-methyl-2-acetylfuran from 2-methylfuran and ethanoic anhydride: continuous acylation of 2-methylfuran (2-MF) by acetic anhydride (AA) on parent Hb, AC-Hb, TA-Hb, Si-Hb zeolites in a fixed-bed reactor (Fig. 1) at atmospheric pressure. The reactor consisted of a glass tube (inner diameter 10 mm) and an electric heater. Before carrying out the acylation reaction, an equal amount of zeolite was activated for 2 h in a drying oven at 200 °C. The activated zeolites need to be transferred to the reactor immediately to avoid exposure to the atmosphere. In standard experiments, the acylation temperature was first controlled at 60 °C by a water bath. Subsequently, 5.9 g of zeolite catalyst was immobilized in the center of the fixed-bed reactor. A mixture of 2-MF and AA (molar ratio of 1:2.5 or 1:4) was delivered to the catalytic column via a metering pump at a set flow rate (0.07 mL/min). Liquid acylation products were periodically collected from the reactor outlet and quantitatively analyzed using a gas chromatograph (GC, Agilent 7890A) equipped with a flame ionization detector (FID) and a DB-FFAP capillary column (30 m length, 0.25 μm film thickness, and 0.25 mm diameter). The target product 2-acetyl-5-methylfuran (2-AC-5-MF) was obtained by acylation reaction and identified using a mass spectrometer (MS, Agilent 5975C) equipped with a mass selective detector.

References

[1] Research on Chemical Intermediates, 2017, vol. 43, # 3, p. 1557 - 1574
[2] ChemSusChem, 2017, vol. 10, # 1, p. 91 - 98
[3] Molecules, 2007, vol. 12, # 3, p. 634 - 640
[4] Liebigs Annalen der Chemie, 1985, # 10, p. 1935 - 1950
[5] Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1989, p. 1981 - 1986

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View Lastest Price from 5-Methyl-2-acetylfuran manufacturers

Shaanxi Dideu New Materials Co. Ltd
Product
5-Methyl-2-acetylfuran 1193-79-9
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
98.0%
Supply Ability
10000KGS
Release date
2025-06-26
Hebei Chuanghai Biotechnology Co., Ltd
Product
5-Methyl-2-acetylfuran 1193-79-9
Price
US $30.00-10.00/KG
Min. Order
50KG
Purity
99%
Supply Ability
500000kg
Release date
2024-11-05
Henan Aochuang Chemical Co.,Ltd.
Product
5-Methyl-2-acetylfuran 1193-79-9
Price
US $0.00-0.00/kg
Min. Order
1kg
Purity
98%
Supply Ability
1Ton
Release date
2022-09-20

1193-79-9, 5-Methyl-2-acetylfuranRelated Search:


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