Uses
ChemicalBook > CAS DataBase List > TETRAPROPYLAMMONIUM PERRUTHENATE

TETRAPROPYLAMMONIUM PERRUTHENATE

Uses
Product Name
TETRAPROPYLAMMONIUM PERRUTHENATE
CAS No.
114615-82-6
Chemical Name
TETRAPROPYLAMMONIUM PERRUTHENATE
Synonyms
TPAP;TETRA-N-PROPYLAMMONIUM PERRUTHENATE;Tetrapropylammonium tetraoxoruthenate;TerapropylaMMoniuMperruthenate;etrapropylammoniumperruthenate;TETRAPROPYLAMMONIUM PERRUTHENATE;TetrapropylaMMoniuM perruthenate 97%;tetrapropylammonium perruthenate(VII);Tetrapropylammonium Perruthenate (TPAP);TETRA-N-PROPYLAMMONIUM PERRUTHENATE (VII)
CBNumber
CB4468073
Molecular Formula
C12H28NO4Ru
Formula Weight
351.43
MOL File
114615-82-6.mol
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TETRAPROPYLAMMONIUM PERRUTHENATE Property

Melting point:
~160 °C (dec.) (lit.)
storage temp. 
Inert atmosphere,2-8°C
solubility 
Methanol (Slightly)
form 
crystal
color 
green
Water Solubility 
Insoluble in water.
Sensitive 
Hygroscopic
Stability:
store cold
InChIKey
NQSIKKSFBQCBSI-UHFFFAOYSA-N
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Safety

Hazard Codes 
O,Xi
Risk Statements 
5-8-36/37/38
Safety Statements 
17-26-36
RIDADR 
UN 1479 5.1/PG 2
WGK Germany 
3
F 
3-10
HazardClass 
5.1
PackingGroup 
III
HS Code 
28439000
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H272May intensify fire; oxidizer

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P220Keep/Store away from clothing/…/combustible materials.

P221Take any precaution to avoid mixing with combustibles/…

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
330744
Product name
Tetrapropylammonium perruthenate
Purity
97%
Packaging
250mg
Price
$72.6
Updated
2024/03/01
Sigma-Aldrich
Product number
330744
Product name
Tetrapropylammonium perruthenate
Purity
97%
Packaging
1g
Price
$252
Updated
2024/03/01
TCI Chemical
Product number
T1559
Product name
Tetrapropylammonium Perruthenate
Packaging
1g
Price
$93
Updated
2024/03/01
TCI Chemical
Product number
T1559
Product name
Tetrapropylammonium Perruthenate
Packaging
5g
Price
$270
Updated
2024/03/01
Alfa Aesar
Product number
B24511
Product name
Tetra-n-propylammonium perruthenate(VII)
Purity
98%
Packaging
0.5g
Price
$82
Updated
2024/03/01
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TETRAPROPYLAMMONIUM PERRUTHENATE Chemical Properties,Usage,Production

Uses

A mild oxidant for the selective transformation of primary alcohols to aldehydes and secondary alcohols to ketones.

Chemical Properties

dark green solid

Uses

Tetrapropylammonium Perruthenate is used in sustainable oxidation reactions and has potential for chemical recycling.

Definition

ChEBI: A quaternary ammonium salt having tetrapropylammonium as the cation and perruthenate as the anion.

General Description

Tetrapropylammonium perruthenate is a mild oxidizing agent used for the oxidation of alcohols to corresponding carbonyl compounds. It is a non-volatile, air-stable, and readily soluble reagent, which can be used either stoichiometrically or catalytically with a suitable co-oxidant.

Purification Methods

It is a strong oxidant and may explode on heating. It can be washed with aqueous n-propanol, then H2O and dried over KOH in a vacuum. It is stable at room temperature but best stored in a refrigerator. It is soluble in CH2Cl2 and MeCN. [Dengel et al. Transition Met Chem 10 98 1985, Griffith et al. J Chem Soc, Chem Commun 1625 1987.] § Polymer supported reagent is available commercially.

TETRAPROPYLAMMONIUM PERRUTHENATE Preparation Products And Raw materials

Raw materials

Preparation Products

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TETRAPROPYLAMMONIUM PERRUTHENATE Suppliers

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View Lastest Price from TETRAPROPYLAMMONIUM PERRUTHENATE manufacturers

Career Henan Chemical Co
Product
TETRAPROPYLAMMONIUM PERRUTHENATE 114615-82-6
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
1000KGS
Release date
2019-12-23

114615-82-6, TETRAPROPYLAMMONIUM PERRUTHENATERelated Search:

Tetrapropylammonium hydroxide Tetrapropylammonium bromide Oxalyl chloride 1 4-BIS(DIPHENYLAMINO)BENZENE Zinc peroxide Tetrakis-(u-acetato-O,O'')-diruthenium Dodecyltrimethylammonium Bromide Ruthenium Ruthenium dioxide TETRAPROPYLAMMONIUM PERRUTHENATE

  • TETRAPROPYLAMMONIUM PERRUTHENATE
  • TETRA-N-PROPYLAMMONIUM PERRUTHENATE
  • TETRA-N-PROPYLAMMONIUM PERRUTHENATE (VII)
  • TPAP
  • Tetrapropylammonium tetraoxoruthenate
  • TerapropylaMMoniuMperruthenate
  • TetrapropylaMMoniuM perruthenate,97% TPAP, (n-C3H7)4NRuO4
  • 1-Propanaminium, N,N,N-tripropyl-, (T-4)-tetraoxoru
  • TetrapropylaMMoniuM perruthenate,TPAP,(n-C3H7)NRuO4
  • TetrapropylaMMoniuM perruthenate 97%
  • Tetrapropylammonium perruthenate, min. 97%
  • Tetrapropylammoniumperruthenate,min.97%TPAP
  • 1-Propanaminium, N,N,N-tripropyl-, (T-4)-tetraoxoruthenate(1-)
  • Tetrapropylammonium Perruthenate (TPAP)
  • Tetra-n-propylammonium perruthenate(VII), 98+%
  • Tetra n-propylammonium perruthenate Oxidation
  • tetrapropylammonium perruthenate(VII)
  • 1-Propanaminium, N,N,N-tripropyl-, (T-4)-tetraoxoruthenate(1-) (1:1)
  • etrapropylammoniumperruthenate
  • 114615-82-6
  • C12H28NRuO4
  • C3H74NRuO4
  • CH3CH224NRuO4
  • CH3CH2CH24NRuO4
  • C12H28NO4Ru
  • Quaternary Ammonium Compounds
  • Classes of Metal Compounds
  • Oxidation
  • Transition Metal Compounds
  • Transition Metal Complexes (Environmentally-friendly Oxidation)
  • Catalysts for Organic Synthesis
  • Metal Complexes
  • Ammonium Polyhalides, etc. (Quaternary)
  • Homogeneous Catalysts
  • Ru (Ruthenium) Compounds
  • Environmentally-friendly Oxidation
  • Others
  • Synthetic Reagents
  • Boron, Nitrile, Thio,& TM-Cpds
  • Ammonium Polyhalides, etc. (Quaternary)
  • Catalysts for Organic Synthesis
  • Classes of Metal Compounds
  • Environmentally-friendly Oxidation
  • Homogeneous Catalysts
  • Metal Complexes
  • Oxidation
  • Quaternary Ammonium Compounds
  • Ru (Ruthenium) Compounds
  • Synthetic Organic Chemistry
  • Transition Metal Complexes (Environmentally-friendly Oxidation)
  • Transition Metal Compounds
  • Ru
  • Alkylammonium salt