TETRAPROPYLAMMONIUM PERRUTHENATE
Uses- Product Name
- TETRAPROPYLAMMONIUM PERRUTHENATE
- CAS No.
- 114615-82-6
- Chemical Name
- TETRAPROPYLAMMONIUM PERRUTHENATE
- Synonyms
- TPAP;TETRA-N-PROPYLAMMONIUM PERRUTHENATE;Tetrapropylammonium tetraoxoruthenate;TerapropylaMMoniuMperruthenate;etrapropylammoniumperruthenate;TETRAPROPYLAMMONIUM PERRUTHENATE;TetrapropylaMMoniuM perruthenate 97%;tetrapropylammonium perruthenate(VII);Tetrapropylammonium Perruthenate (TPAP);TETRA-N-PROPYLAMMONIUM PERRUTHENATE (VII)
- CBNumber
- CB4468073
- Molecular Formula
- C12H28NO4Ru
- Formula Weight
- 351.43
- MOL File
- 114615-82-6.mol
TETRAPROPYLAMMONIUM PERRUTHENATE Property
- Melting point:
- ~160 °C (dec.) (lit.)
- storage temp.
- Inert atmosphere,2-8°C
- solubility
- Methanol (Slightly)
- form
- crystal
- color
- green
- Water Solubility
- Insoluble in water.
- Sensitive
- Hygroscopic
- Stability:
- store cold
- InChIKey
- NQSIKKSFBQCBSI-UHFFFAOYSA-N
Safety
- Hazard Codes
- O,Xi
- Risk Statements
- 5-8-36/37/38
- Safety Statements
- 17-26-36
- RIDADR
- UN 1479 5.1/PG 2
- WGK Germany
- 3
- F
- 3-10
- HazardClass
- 5.1
- PackingGroup
- III
- HS Code
- 28439000
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H272May intensify fire; oxidizer
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P220Keep/Store away from clothing/…/combustible materials.
P221Take any precaution to avoid mixing with combustibles/…
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P405Store locked up.
P501Dispose of contents/container to..…
N-Bromosuccinimide Price
- Product number
- 330744
- Product name
- Tetrapropylammonium perruthenate
- Purity
- 97%
- Packaging
- 250mg
- Price
- $72.6
- Updated
- 2024/03/01
- Product number
- 330744
- Product name
- Tetrapropylammonium perruthenate
- Purity
- 97%
- Packaging
- 1g
- Price
- $252
- Updated
- 2024/03/01
- Product number
- T1559
- Product name
- Tetrapropylammonium Perruthenate
- Packaging
- 1g
- Price
- $93
- Updated
- 2024/03/01
- Product number
- T1559
- Product name
- Tetrapropylammonium Perruthenate
- Packaging
- 5g
- Price
- $270
- Updated
- 2024/03/01
- Product number
- B24511
- Product name
- Tetra-n-propylammonium perruthenate(VII)
- Purity
- 98%
- Packaging
- 0.5g
- Price
- $82
- Updated
- 2024/03/01
TETRAPROPYLAMMONIUM PERRUTHENATE Chemical Properties,Usage,Production
Uses
A mild oxidant for the selective transformation of primary alcohols to aldehydes and secondary alcohols to ketones.
Chemical Properties
dark green solid
Uses
Tetrapropylammonium Perruthenate is used in sustainable oxidation reactions and has potential for chemical recycling.
Definition
ChEBI: A quaternary ammonium salt having tetrapropylammonium as the cation and perruthenate as the anion.
General Description
Tetrapropylammonium perruthenate is a mild oxidizing agent used for the oxidation of alcohols to corresponding carbonyl compounds. It is a non-volatile, air-stable, and readily soluble reagent, which can be used either stoichiometrically or catalytically with a suitable co-oxidant.
Purification Methods
It is a strong oxidant and may explode on heating. It can be washed with aqueous n-propanol, then H2O and dried over KOH in a vacuum. It is stable at room temperature but best stored in a refrigerator. It is soluble in CH2Cl2 and MeCN. [Dengel et al. Transition Met Chem 10 98 1985, Griffith et al. J Chem Soc, Chem Commun 1625 1987.] § Polymer supported reagent is available commercially.
TETRAPROPYLAMMONIUM PERRUTHENATE Preparation Products And Raw materials
Raw materials
Preparation Products
TETRAPROPYLAMMONIUM PERRUTHENATE Suppliers
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- Germany
- ProdList
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- Advantage
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View Lastest Price from TETRAPROPYLAMMONIUM PERRUTHENATE manufacturers
- Product
- TETRAPROPYLAMMONIUM PERRUTHENATE 114615-82-6
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 1000KGS
- Release date
- 2019-12-23