ChemicalBook > CAS DataBase List > 3,5-DIHYDROXYANISOLE HYDRATE

3,5-DIHYDROXYANISOLE HYDRATE

Product Name
3,5-DIHYDROXYANISOLE HYDRATE
CAS No.
2174-64-3
Chemical Name
3,5-DIHYDROXYANISOLE HYDRATE
Synonyms
Flamenol;Flamenol,≥95%;5-Methoxyresorcin;3-Methoxyresorcinol;5-METHOXYRESORCINOL;3,5-DIHYDROXYANISOLE;5-Methoxyresorcinol>5-METHOXYRESORCINOL 97%;5-Methoxy-1,3-benzenediol;1-Methoxy-3,5-benzenediol
CBNumber
CB4673817
Molecular Formula
C7H8O3
Formula Weight
140.14
MOL File
2174-64-3.mol
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3,5-DIHYDROXYANISOLE HYDRATE Property

Melting point:
78-80 °C(lit.)
Boiling point:
188-189 °C12 mm Hg(lit.)
Density 
1.270
refractive index 
1.4638 (estimate)
Flash point:
123℃
storage temp. 
Refrigerator
solubility 
Chloroform (Slightly), Methanol (Slightly)
pka
9.07±0.10(Predicted)
form 
Solid
color 
Yellow
Water Solubility 
Soluble in water.
BRN 
1423578
LogP
0.910 (est)
CAS DataBase Reference
2174-64-3(CAS DataBase Reference)
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Safety

Hazard Codes 
Xn
Risk Statements 
22-36/37/38
Safety Statements 
26
WGK Germany 
3
HS Code 
2909500090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
232491
Product name
5-Methoxyresorcinol
Purity
98%
Packaging
5g
Price
$308
Updated
2024/03/01
TCI Chemical
Product number
M1413
Product name
5-Methoxyresorcinol
Purity
>95.0%(GC)
Packaging
1g
Price
$189
Updated
2024/03/01
Alfa Aesar
Product number
H61996
Product name
5-Methoxyresorcinol, 95%
Packaging
1g
Price
$63.65
Updated
2024/03/01
Alfa Aesar
Product number
H61996
Product name
5-Methoxyresorcinol, 95%
Packaging
5g
Price
$238.65
Updated
2024/03/01
Alfa Aesar
Product number
H61996
Product name
5-Methoxyresorcinol, 95%
Packaging
250mg
Price
$35.2
Updated
2023/06/20
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3,5-DIHYDROXYANISOLE HYDRATE Chemical Properties,Usage,Production

Uses

5-Methoxyresorcinol was used in synthesis of isorobustin, substituted linear and angular benzofurocoumarins.

Definition

ChEBI: Flamenol is a member of the class of resorcinols that is phloroglucinol in which one of the phenolic hydrogens has been replaced by a methyl group. It has a role as a Brassica napus metabolite. It is a member of resorcinols and a monomethoxybenzene. It is functionally related to a phloroglucinol.

General Description

Kinetics of the aroxyl radical-scavenging action of 5-methoxyresorcinol has been investigated. The kinetics of reaction of 5,7-diisopropyl-tocopheroxyl radical (Toc) with 5-methoxyresorcinol has been measured by stopped-flow spectrophotometer.

Synthesis

Anhydrous phloroglucinol (25g,0.198 mole) is dissolved in absolutemethyl alcohol (100 ml) and the solution cooled to 18°.Dry hydrogenchloride gas is passed through the solution for 25 min at such a rate thatthe solution does not get saturated (approx. 200 bubbles/min).Themixture is then refluxed for 15 min,cooled immediately to 18° and dryhydrogen chloride gas passed again for25 min. The reaction mixture isallowed to stand for 12 hr and the solvent is removed by distillation invacuo.Great care is taken to remove as much of the solvent as possiblewithout applying any heat (preferably in rotatory evaporator).The residueis poured into water (500 ml) and extracted with ether (4 × 75 ml). The ether solution is dried (anhydrous sodium sulphate) and then distilled.The residual oily product is distilled in vacuo. A small quantity ofo-dimethyl phloroglucinol (5g,16.4 %) distils over first at 185-190°/25 mm and then o-monomethyl phloroglucinol (15g,54.2%) distils over at210° as a viscous oil. The viscous oil solidifies on standing for 2-3 days.M.p.78°.The yields are not consistent and vary according to the extent ofsaturation.

3,5-DIHYDROXYANISOLE HYDRATE Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from 3,5-DIHYDROXYANISOLE HYDRATE manufacturers

Career Henan Chemical Co
Product
3,5-DIHYDROXYANISOLE HYDRATE 2174-64-3
Price
US $6.68/KG
Min. Order
1KG
Purity
97%-99%
Supply Ability
1kg-1000kg
Release date
2020-01-08

2174-64-3, 3,5-DIHYDROXYANISOLE HYDRATERelated Search:


  • PHLOROGLUCINOL MONOMETHYL ETHER
  • PHLOROGLUCINOL MONOMETHYL ETHER HYDRATE
  • 3,5-DIHYDROXYANISOLE
  • 3,5-DIHYDROXYANISOLE HYDRATE
  • 5-METHOXYRESORCINOL
  • 5-METHOXYRESORCINOL HYDRATE
  • 1,3-Benzenediol, 5-methoxy-
  • 5-Methoxy-1,3-benzenediol
  • Flamenol
  • 3-Methoxyresorcinol
  • 5-METHOXYRESORCINOL 97%
  • 3,5-Dihydroxyanisole, Phloroglucinol monomethyl ether
  • 5-Methoxyresorcin
  • 1,3-Dihydroxy-5-methoxybenzene
  • 1-Methoxy-3,5-benzenediol
  • 3-Hydroxy-5-methoxyphenol
  • 5-Methoxybenzene-1,3-diol
  • Phloroglucinol Impurity 23
  • 4-(5-formyl-2-furanyl)benzenesulfonamide
  • 5-Methoxyresorcinol&gt
  • Flamenol,≥95%
  • 5 Methoxyresorcinol,5Methoxyresorcinol
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  • 2174-64-2
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