ChemicalBook > CAS DataBase List > 1,2-Bis(diphenylphosphino)ethane nickel(II) chloride

1,2-Bis(diphenylphosphino)ethane nickel(II) chloride

Product Name
1,2-Bis(diphenylphosphino)ethane nickel(II) chloride
CAS No.
14647-23-5
Chemical Name
1,2-Bis(diphenylphosphino)ethane nickel(II) chloride
Synonyms
[Bis(diphenylphosphino)ethane]dichloronickel;DICHLORO[1,2-BIS(DIPHENYLPHOSPHINO)ETHANE]NICKEL(II);[1,2-Bis(diphenyL;dichloropalladium(II);phosphino)ethane]dichL;1,2-Bis-(Diphenylphosphino)Eth;[1,2-BIS(DIPHENYLPHOSPHINO)ETHANE]DICHLORON;1,2-Bis-(Diphenylphosphino)EthaneDichloroNickel;1,2-Bis (diphenylphosphino)ethane]dichlornickel;Dichloro[1,2-bis(diphenylphosphino)ethane]nickel
CBNumber
CB4676449
Molecular Formula
C26H24Cl2NiP2
Formula Weight
528.02
MOL File
14647-23-5.mol
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1,2-Bis(diphenylphosphino)ethane nickel(II) chloride Property

Melting point:
263-265 °C(lit.)
storage temp. 
Inert atmosphere,2-8°C
solubility 
Chloroform, Methanol (Sparingly)
form 
crystal
color 
orange
Water Solubility 
insoluble
Exposure limits
NIOSH: IDLH 10 mg/m3; TWA 0.015 mg/m3
Stability:
Hygroscopic
CAS DataBase Reference
14647-23-5(CAS DataBase Reference)
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Safety

Hazard Codes 
T,Xn
Risk Statements 
45-20/21/22-36/37/38-42/43-40
Safety Statements 
53-22-26-36-45-52
WGK Germany 
3
TSCA 
No
HS Code 
29319090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H334May cause allergy or asthma symptoms or breathing difficulties if inhaled

H335May cause respiratory irritation

H350May cause cancer

Precautionary statements

P202Do not handle until all safety precautions have been read and understood.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P308+P313IF exposed or concerned: Get medical advice/attention.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
328219
Product name
[1,2-Bis(diphenylphosphino)ethane]dichloronickel(II)
Packaging
1g
Price
$33.2
Updated
2024/03/01
Sigma-Aldrich
Product number
328219
Product name
[1,2-Bis(diphenylphosphino)ethane]dichloronickel(II)
Packaging
5g
Price
$102
Updated
2024/03/01
TCI Chemical
Product number
B2225
Product name
[1,2-Bis(diphenylphosphino)ethane]nickel(II) Dichloride
Purity
>96.0%(T)
Packaging
1g
Price
$28
Updated
2024/03/01
TCI Chemical
Product number
B2225
Product name
[1,2-Bis(diphenylphosphino)ethane]nickel(II) Dichloride
Purity
>96.0%(T)
Packaging
5g
Price
$78
Updated
2024/03/01
Alfa Aesar
Product number
013932
Product name
Dichloro[bis(1,2-diphenylphosphino)ethane]nickel(II), 98%
Packaging
2g
Price
$43.65
Updated
2024/03/01
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1,2-Bis(diphenylphosphino)ethane nickel(II) chloride Chemical Properties,Usage,Production

Chemical Properties

Orange to red crystalline powder

Uses

suzuki reaction

Uses

Dichloro[bis(1,2-diphenylphosphino)ethane]nickel(II) is a reactant involved in Kumada catalyst-transfer polycondensation, oxidation of carboranyl phosphine ligands, synthesis of nickel-iron dithiolato hydrides, Ullmann reactions - homocoupling reactions, co-catalyst for hydroformylation of alcohols for the synthesis of quaternary carbon centers, catalyst for Wacker-type intramolecular aerobic oxidative amination of alkenes.

reaction suitability

core: nickel
reagent type: catalyst

1,2-Bis(diphenylphosphino)ethane nickel(II) chloride Preparation Products And Raw materials

Raw materials

Preparation Products

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1,2-Bis(diphenylphosphino)ethane nickel(II) chloride Suppliers

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View Lastest Price from 1,2-Bis(diphenylphosphino)ethane nickel(II) chloride manufacturers

WUHAN FORTUNA CHEMICAL CO., LTD
Product
1,2-Bis(diphenylphosphino)ethane nickel(II) chloride 14647-23-5
Price
US $0.00/KG
Min. Order
25KG
Purity
98%min
Supply Ability
30tons/month
Release date
2023-01-29
Xinxiang Hongqi District Houyuan Trading Co.,Ltd
Product
1,2-Bis(diphenylphosphino)ethane nickel(II) chloride 14647-23-5
Price
US $30.00-28.00/Kg
Min. Order
1Kg
Purity
99.0% up
Supply Ability
50 tons per month
Release date
2022-11-10
henan kanbei chemical co.,ltd
Product
1,2-Bis(diphenylphosphino)ethane nickel(II) chloride 14647-23-5
Price
US $0.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
1000kg
Release date
2022-09-23

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