Chlorotrifluoroethylene Property

Melting point:

−158 °C(lit.)

Boiling point:

−28.4 °C(lit.)

Density 

1,305 g/cm³

vapor density 

4.13 (vs air)

vapor pressure 

612kPa at 25℃

refractive index 

1.3800

Flash point:

-28°C

Water Solubility 

380mg/L at 28℃

InChI

InChI=1S/C2ClF3/c3-1(4)2(5)6

InChIKey

UUAGAQFQZIEFAH-UHFFFAOYSA-N

SMILES

C(/Cl)(\F)=C(\F)/F

LogP

1.65

CAS DataBase Reference

79-38-9(CAS DataBase Reference)

NIST Chemistry Reference

Ethene, chlorotrifluoro-(79-38-9)

EPA Substance Registry System

Chlorotrifluoroethylene (79-38-9)

Safety

Hazard Codes 

F+,Xn,T,F

Risk Statements 

12-20/22

Safety Statements 

16-38

RIDADR 

UN 1082 2.3

WGK Germany 

3

RTECS 

KV0525000

Hazard Note 

Flammable/Toxic

HazardClass 

2.3

HS Code 

2903779010

Hazardous Substances Data

79-38-9(Hazardous Substances Data)

Toxicity

LD50 oral in mouse: 268mg/kg

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H220Extremely flammable gas

H280Contains gas under pressure; may explode if heated

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P301+P310IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.

P311Call a POISON CENTER or doctor/physician.

P410+P403Protect from sunlight. Store in a well-ventilated place.

Chlorotrifluoroethylene Chemical Properties,Usage,Production

Chemical Properties

Colorless gas; faint ethereal odor. Decomposes in water.

Uses

Intermediate, monomer for chlorotrifluoroethylene resins.

Preparation

Chlorotrifluoroethylene is prepared from ethylene by the following route:

Ethylene is treated with an excess of chlorine at 300-350??C in the presence of activated charcoal to give hexachloroethane. This product is then treated with hydrogen fluoride in the presence of antimony pentachloride to yield trichlorotrifluoroethane. Dechlorination in the liquid phase with zinc dust and ethanol results in the formation of chlorotrifluoroethylene which is washed with water to remove alcohol, dried and distilled under pressure.

Synthesis Reference(s)

The Journal of Organic Chemistry, 57, p. 5018, 1992 DOI: 10.1021/jo00044a044

General Description

Chlorotrifluoroethylene is a colorless gas with a faint ethereal odor. Chlorotrifluoroethylene is shipped as a liquefied gas under its vapor pressure. Chlorotrifluoroethylene is very toxic by inhalation and is easily ignited. The vapors are heavier than air and a flame can flash back to the source of leak very easily. This leak can either be a liquid or vapor leak. The vapors can asphyxiate by the displacement of air. Contact with the liquid can cause frostbite. Under prolonged exposure to intense heat or fire the containers may violently rupture and rocket, or the material may polymerize with possible container rupture.

Air & Water Reactions

Highly flammable.

Reactivity Profile

Halogenated aliphatic compounds, such as Chlorotrifluoroethylene, are moderately or very reactive. Reactivity generally decreases with increased degree of substitution of halogen for hydrogen atoms. Low molecular weight haloalkanes are highly flammable and can react with some metals to form dangerous products. Materials in this group are incompatible with strong oxidizing and reducing agents. Also, they are incompatible with many amines; nitrides; azo/diazo compounds; alkali metals; strong oxidizers such as chlorine perchlorate, oxygen, bromine; and epoxides.

Hazard

Dangerous fire risk. Flammable limits in air 8.4–38.7%.

Health Hazard

Inhalation causes dizziness, nausea, vomiting; liver and kidney injury may develop after several hours and cause jaundice and necrosis of the kidney. Contact with liquid causes frostbite of eyes and possibly of skin.

Flammability and Explosibility

Extremely flammable

Safety Profile

Poison by ingestion and intraperitoneal routes. Moderately toxic by inhalation. Very dangerous fire hazard when exposed to heat, flames (sparks), or oxidizers. To fight fire, stop flow of gas. Violent reaction when mixed with (Brz + 02) or (CIF3 + water). Potentially explosive polymerization reaction with ethylene. Incompatible with 1,l -dchloroethylene; oxygen. When heated to decomposition it emits toxic fumes of Fand Cl-. See also CHLORINATED HYDROCARBONS, ALIPHATIC; and FLUORIDES.

Purification Methods

Scrub it with 10% KOH solution, then 10% H2SO4 solution to remove inhibitors, dry and pass it through silica gel. It is stabilized with ~1% tributylamine. Use brass equipment. [Beilstein 1 III 646.] TOXIC GAS.