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4,4'-DIBROMOTRIPHENYLAMINE

Product Name
4,4'-DIBROMOTRIPHENYLAMINE
CAS No.
81090-53-1
Chemical Name
4,4'-DIBROMOTRIPHENYLAMINE
Synonyms
DBTPA;K0064;4,4-dibromotrisamine;Dibromotriphenylamine;4,4-Dibromotrianiline;Bis(4-bromophenyl)phenyla;4,4'-Dibromotriphenylamine;4,4'-DIBROMOTRIPHENYLAMINE;4,4''-Dibromotriphenylamine;N,N-BIS(P-BROMOPHENYL)ANILINE
CBNumber
CB4694991
Molecular Formula
C18H13Br2N
Formula Weight
403.11
MOL File
81090-53-1.mol
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4,4'-DIBROMOTRIPHENYLAMINE Property

Melting point:
69°C
Boiling point:
470.7±30.0 °C(Predicted)
Density 
1.593
Flash point:
110 °C
storage temp. 
Inert atmosphere,Room Temperature
pka
-4.29±0.50(Predicted)
form 
Solid
color 
Off-white
InChI
InChI=1S/C18H13Br2N/c19-14-6-10-17(11-7-14)21(16-4-2-1-3-5-16)18-12-8-15(20)9-13-18/h1-13H
InChIKey
KIGVOJUDEQXKII-UHFFFAOYSA-N
SMILES
C1(N(C2=CC=C(Br)C=C2)C2=CC=CC=C2)=CC=C(Br)C=C1
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Safety

Hazard Codes 
Xn
Risk Statements 
36/37/38-43-22
Safety Statements 
26-36/37/39-36/37
WGK Germany 
3
HS Code 
29214990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H317May cause an allergic skin reaction

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
679917
Product name
4,4′-Dibromotriphenylamine
Purity
96%
Packaging
1g
Price
$54.1
Updated
2023/06/20
Sigma-Aldrich
Product number
679917
Product name
4,4′-Dibromotriphenylamine
Purity
96%
Packaging
5g
Price
$189
Updated
2023/06/20
TCI Chemical
Product number
D1910
Product name
4,4'-Dibromotriphenylamine
Purity
>98.0%(GC)(T)
Packaging
1g
Price
$48
Updated
2025/07/31
TCI Chemical
Product number
D1910
Product name
4,4'-Dibromotriphenylamine
Purity
>98.0%(GC)(T)
Packaging
5g
Price
$149
Updated
2025/07/31
TCI Chemical
Product number
D5603
Product name
4,4'-Dibromotriphenylamine (purified by sublimation)
Purity
>98.0%(GC)(T)
Packaging
200mg
Price
$74
Updated
2025/07/31
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4,4'-DIBROMOTRIPHENYLAMINE Chemical Properties,Usage,Production

Uses

Polytriarylamine Semiconductors

Synthesis

603-34-9

81090-53-1

Step 1: Synthesis of 4,4'-dibromotriphenylamine 1. 12 g (50 mmol) of triphenylamine was dissolved in 250 mL of ethyl acetate in a 500 mL conical flask. 2. 18 g (100 mmol) of N-bromosuccinimide (NBS) was added to the above solution. 3. The reaction mixture was stirred at room temperature for 24 hours. 4. Upon completion of the reaction, the reaction mixture was washed with deionized water. 5. The mixture was dried by adding anhydrous magnesium sulfate to remove water. 6. The desiccant was removed by filtration and the filtrate was concentrated. 7. 7. 20 g of white solid product was obtained after drying in 99% yield.

References

[1] Patent: WO2009/72587, 2009, A1. Location in patent: Page/Page column 191
[2] Patent: WO2009/139358, 2009, A1. Location in patent: Page/Page column 90
[3] Journal of Materials Chemistry C, 2016, vol. 4, # 13, p. 2579 - 2586
[4] Journal of Materials Chemistry C, 2016, vol. 4, # 43, p. 10301 - 10308
[5] Journal of Materials Chemistry, 2012, vol. 22, # 23, p. 11629 - 11635

4,4'-DIBROMOTRIPHENYLAMINE Preparation Products And Raw materials

Raw materials

Preparation Products

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4,4'-DIBROMOTRIPHENYLAMINE Suppliers

SIGMA-RBI
Tel
--
Fax
--
Country
Switzerland
ProdList
6896
Advantage
91
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View Lastest Price from 4,4'-DIBROMOTRIPHENYLAMINE manufacturers

ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD
Product
4-Bromo-N-(4-bromophenyl)-N-phenylaniline 81090-53-1
Price
US $2.20-8.80/kg
Min. Order
1kg
Purity
99%min
Supply Ability
100kg
Release date
2025-06-17
Shanghai Daken Advanced Materials Co.,Ltd
Product
4,4'-dibromotriphenylamine 81090-53-1
Price
US $0.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
150KG /month
Release date
2021-11-19
Shanghai UCHEM Inc.
Product
4,4'-Dibromotriphenylamine 81090-53-1
Price
US $22.00-296.00/g
Min. Order
1g
Purity
0.99
Supply Ability
25kg
Release date
2023-10-11

81090-53-1, 4,4'-DIBROMOTRIPHENYLAMINERelated Search:


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  • 81090-53-1
  • C18H13Br2N
  • Reagent for High-Performance Polymer Research
  • Fluorenes, etc. (reagent for high-performance polymer research)
  • Acid Anhydrides, etc. (Reagents for Conducting Polymer Research)
  • Electroluminescence
  • Reagents for Conducting Polymer Research
  • OLED materials,pharm chemical,electronic
  • Acid Anhydrides, etc. (Reagents for Conducting Polymer Research)
  • Electroluminescence
  • Fluorenes, etc. (reagent for high-performance polymer research)
  • Functional Materials
  • Reagent for High-Performance Polymer Research
  • Reagents for Conducting Polymer Research