ChemicalBook > CAS DataBase List > 2,2,4-Trimethyl-1,3-pentanediol

2,2,4-Trimethyl-1,3-pentanediol

Product Name
2,2,4-Trimethyl-1,3-pentanediol
CAS No.
144-19-4
Chemical Name
2,2,4-Trimethyl-1,3-pentanediol
Synonyms
TMPD GLYCOL;tmpd(alcohol);UNII:WT1X081P0L;Trimethylpentanediol;2,2,4-Trimethylpentandiol;TRIMETHYL-1,3-PENTANEDIOL;1,3-PENTANEDIOL,2,2,4-TRIME;2,2,4-trimethyl-3-pentanediol;2,2,4-TriMethyl-1,3-pentandiol;3-Pentanediol,2,2,4-trimethyl-1
CBNumber
CB4711551
Molecular Formula
C8H18O2
Formula Weight
146.23
MOL File
144-19-4.mol
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2,2,4-Trimethyl-1,3-pentanediol Property

Melting point:
50-53 °C (lit.)
Boiling point:
232 °C (lit.)
Density 
0,937 g/cm3
vapor pressure 
0.314Pa at 20℃
refractive index 
1.4513
Flash point:
>230 °F
storage temp. 
Sealed in dry,Room Temperature
solubility 
Chloroform, Methanol
form 
Solid
pka
14.81±0.20(Predicted)
color 
Off-White
Water Solubility 
31.5g/L at 20℃
BRN 
1698098
InChIKey
JCTXKRPTIMZBJT-UHFFFAOYSA-N
LogP
1.25 at 22℃
CAS DataBase Reference
144-19-4(CAS DataBase Reference)
NIST Chemistry Reference
1,3-Pentanediol, 2,2,4-trimethyl-(144-19-4)
EPA Substance Registry System
2,2,4-Trimethyl-1,3-pentanediol (144-19-4)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-37/39
WGK Germany 
1
RTECS 
SA1400000
TSCA 
Yes
HS Code 
2905.39.9000
Hazardous Substances Data
144-19-4(Hazardous Substances Data)
Toxicity
guinea pig,LD50,oral,2gm/kg (2000mg/kg),Toxicology and Applied Pharmacology. Vol. 29, Pg. 87, 1974.
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
327220
Product name
2,2,4-Trimethyl-1,3-pentanediol
Purity
97%
Packaging
1kg
Price
$56
Updated
2024/03/01
TCI Chemical
Product number
T0483
Product name
2,2,4-Trimethyl-1,3-pentanediol
Purity
>97.0%(GC)
Packaging
25g
Price
$29
Updated
2024/03/01
TCI Chemical
Product number
T0483
Product name
2,2,4-Trimethyl-1,3-pentanediol
Purity
>97.0%(GC)
Packaging
500g
Price
$151
Updated
2024/03/01
Alfa Aesar
Product number
B21328
Product name
2,2,4-Trimethyl-1,3-pentanediol, 94%
Packaging
10g
Price
$33.6
Updated
2021/12/16
TRC
Product number
T796570
Product name
2,2,4-Trimethyl-1,3-pentanediol
Packaging
50g
Price
$65
Updated
2021/12/16
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2,2,4-Trimethyl-1,3-pentanediol Chemical Properties,Usage,Production

Chemical Properties

2,2,4-Trimethyl-1,3-pentanediol is a somewhat volatile liquid.

Chemical Properties

(96% pure): White solid. Slightly soluble in water; soluble in alcohol, acetone, ether, and benzene. Combustible.

Uses

Main uses of 2,2,4-Trimethyl-1,3-pentanediol are as a component of polyester resins used in food packaging and as an insect repellent. Industrial exposure is likely to be by direct contact with the liquid. Vapors or mists may be encountered under some conditions.

Uses

2,2,4-Trimethyl-1,3-pentanediol is used in the synthesis of monoisobutyrate derivatives used in film forming auxilleries in paint substances.

Uses

Polyester resins, plasticizers, lubricants, surface coatings and printing inks, insect repellent.

Production Methods

2,2,4-Trimethyl-1,3-pentanediol is made by reacting isobutyryl chloride with ethyl isobutyrate.

Definition

2,2,4-Trimethyl-1,3-pentanediol (TMPD) glycol, with one primary and one secondary hydroxyl function, shows the typical reactivity of a diol. In comparison to other diols, such as 1,4-cyclohexanedimethanol) or NPG (Neopentyl glycol), TMPD glycol has an unsymmetrical structure and shielded hydroxyl groups.    

Flammability and Explosibility

Non flammable

Toxicology

2,2,4-trimethyl-1,3-pentanediol (TMPD Glycol) is classified as "slightly toxic". In rabbits, moderate eye irritation was observed. Slight to no skin irritation occurred in guinea pigs, and no skin sensitization was found. Repeated skin application studies in humans gave no evidence of irritation, sensitization, photosensitization, or systemic toxic effects. In humans, TMPD glycol is rapidly excreted in the urine, partly unchanged, partly as the glucuronide and sulfate conjugates, and partly as 2,2,4-trimethyl-3-hydroxyvaleric acid. LD50 2000 (rat, oral), LD50 145 (rat, intravenous).

2,2,4-Trimethyl-1,3-pentanediol Preparation Products And Raw materials

Raw materials

Preparation Products

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2,2,4-Trimethyl-1,3-pentanediol Suppliers

P&S Chemicals
Tel
--
Fax
--
Email
info@pschemicals.com
Country
The Netherlands
ProdList
2724
Advantage
58
Brunschwig chemie
Tel
--
Fax
--
Email
brunschwig@brunschwig.nl
Country
The Netherlands
ProdList
4996
Advantage
67
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View Lastest Price from 2,2,4-Trimethyl-1,3-pentanediol manufacturers

Hebei Chuanghai Biotechnology Co,.LTD
Product
2,2,4-Trimethyl-1,3-pentanediol 144-19-4
Price
US $5.00-2.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
10000kg
Release date
2024-08-23
Career Henan Chemical Co
Product
2,2,4-Trimethyl-1,3-pentanediol 144-19-4
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
100kg
Release date
2019-12-26
Career Henan Chemical Co
Product
2,2,4-Trimethyl-1,3-pentanediol 144-19-4
Price
US $1.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
Customized
Release date
2018-12-22

144-19-4, 2,2,4-Trimethyl-1,3-pentanediolRelated Search:


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