ChemicalBook > CAS DataBase List > Benzenesulfonyl hydrazide

Benzenesulfonyl hydrazide

Product Name
Benzenesulfonyl hydrazide
CAS No.
80-17-1
Chemical Name
Benzenesulfonyl hydrazide
Synonyms
BSH;BENZENESULFONOHYDRAZIDE;Porofor;POROFOR BSH;Phenylsulfonylhydrazine;Phenylsulfonyl hydrazide;BENZENESULPHONYL HYDRAZIDE;chkhz9;ChKhZ 9;celogenbsh
CBNumber
CB4711849
Molecular Formula
C6H8N2O2S
Formula Weight
172.2
MOL File
80-17-1.mol
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Benzenesulfonyl hydrazide Property

Melting point:
101-103 °C(lit.)
Boiling point:
333.5±25.0 °C(Predicted)
Density 
1.303 (estimate)
refractive index 
1.6490 (estimate)
Flash point:
110 °C
storage temp. 
Flammables area
solubility 
soluble in Methanol
pka
9.30±0.50(Predicted)
form 
solid
color 
White to Almost white
Merck 
14,7598
BRN 
640079
InChIKey
VJRITMATACIYAF-UHFFFAOYSA-N
CAS DataBase Reference
80-17-1(CAS DataBase Reference)
NIST Chemistry Reference
Benzenesulfonic acid, hydrazide(80-17-1)
EPA Substance Registry System
Benzenesulfonic acid, hydrazide (80-17-1)
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Safety

Hazard Codes 
F
Risk Statements 
11
Safety Statements 
15-16-22-24/25
RIDADR 
UN 3226 4.1
WGK Germany 
3
RTECS 
DB6888000
4.9-16
TSCA 
Yes
HazardClass 
4.1
PackingGroup 
II
HS Code 
29350090
Toxicity
LDLo orl-rat: 50 mg/kg IPSTB3 3,93,76
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H242Heating may cause a fire

H302Harmful if swallowed

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P220Keep/Store away from clothing/…/combustible materials.

P234Keep only in original container.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P403+P235Store in a well-ventilated place. Keep cool.

P420Store away from other materials.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
B3809
Product name
Benzenesulfonyl hydrazide
Purity
98%
Packaging
25g
Price
$185
Updated
2024/03/01
TCI Chemical
Product number
B0038
Product name
Benzenesulfonyl Hydrazide
Purity
>98.0%(T)
Packaging
25g
Price
$27
Updated
2024/03/01
TCI Chemical
Product number
B0038
Product name
Benzenesulfonyl Hydrazide
Purity
>98.0%(T)
Packaging
100g
Price
$71
Updated
2024/03/01
Alfa Aesar
Product number
B23971
Product name
Benzenesulfonyl hydrazide, 98%
Packaging
25g
Price
$46.65
Updated
2024/03/01
Alfa Aesar
Product number
B23971
Product name
Benzenesulfonyl hydrazide, 98%
Packaging
100g
Price
$140
Updated
2024/03/01
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Benzenesulfonyl hydrazide Chemical Properties,Usage,Production

Chemical Properties

Benzenesulfonohydrazides,unlike the benzenesulfonamides, are thermally unstable. They decompose, when heated in water in some cases, to form sulfides, thiosulfonates, and nitrogen; for this reason they are used as blowing agents in the production of foams.

Chemical Properties

Benzenesulfonyl hydrazide is WHITE POWDER

Uses

Benzenesulfonyl hydrazide is used in making foam rubber and foam plastics.

Production Methods

Benzenesulfonyl hydrazides are produced by treating benzenesulfonyl chlorides with hydrazine in dioxane, alcohol, or water and in the presence of a second equivalent of hydrazineoranotherbase. They react with nitrous acid to form benzenesulfonyl azides according to the following equation:
ArSO2NHNH2 +HNO2→RSO2N3 +2H2O

General Description

Benzenesulfonyl hydrazide is a white to light-colored crystalline solid. Insoluble in water and denser than water. Contact may irritate skin, eyes and mucous membranes. May be toxic by ingestion. Readily ignited by sparks or flames and burns vigorously. Used to make other chemicals.

Air & Water Reactions

Insoluble in water.

Reactivity Profile

Self-decomposition or self-ignition may be triggered by heat, chemical reaction, friction or impact. May be ignited by heat, sparks or flames.

Safety Profile

Poison by ingestion. A flammable solid. When heated to decomposition it emits toxic vapors of NOx and SOx.

Benzenesulfonyl hydrazide Preparation Products And Raw materials

Raw materials

Preparation Products

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Benzenesulfonyl hydrazide Suppliers

Shouguang Nuomeng Chemical Co Ltd.
Tel
536-5399456 13869682027
Fax
0536-5399456
Email
1972085497@qq.com
Country
China
ProdList
47
Advantage
58
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
021-61259108 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40228
Advantage
62
Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30123
Advantage
84
TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24529
Advantage
81
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44688
Advantage
61
Beijing Ouhe Technology Co., Ltd
Tel
010-82967028 13552068683
Fax
+86-10-82967029
Email
2355560935@qq.com
Country
China
ProdList
12390
Advantage
60
Shanghai Longsheng chemical Co.,Ltd.
Tel
021-58099652-8005 13585536065
Fax
021-58099609
Email
bin.wu@shlschem.com
Country
China
ProdList
9809
Advantage
59
Shanghai Hanhong Scientific Co.,Ltd.
Tel
021-54306202 13764082696
Email
info@hanhongsci.com
Country
China
ProdList
42958
Advantage
64
XiaoGan ShenYuan ChemPharm co,ltd
Tel
15527768850
Email
1791901229@qq.com
Country
China
ProdList
8836
Advantage
52
Shandong Xiya Chemical Co., Ltd
Tel
4009903999 13355009207
Fax
0539-6365991
Email
3007715519@qq.com
Country
China
ProdList
18738
Advantage
57
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View Lastest Price from Benzenesulfonyl hydrazide manufacturers

Shouguang Nuomeng Chemical Co Ltd.
Product
Benzenesulfonyl hydrazide, BSH, Blowing Agent BSH 80-17-1
Price
US $6200.00/T
Min. Order
1KG
Purity
98%
Supply Ability
200 tons per month
Release date
2020-07-18
Henan Fengda Chemical Co., Ltd
Product
Benzenesulfonyl hydrazide 80-17-1
Price
US $100.00-1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
g-kg-tons, free sample is available
Release date
2023-12-25
Honest Joy Holdings Limited
Product
Benzenesulfonyl hydrazide 80-17-1
Price
US $0.00/KG
Min. Order
1KG
Purity
97.8%
Supply Ability
100 tons
Release date
2022-02-18

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