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Benzenesulfonyl chloride

Product Name
Benzenesulfonyl chloride
CAS No.
98-09-9
Chemical Name
Benzenesulfonyl chloride
Synonyms
bsc-refined;benzenesulfonyl;AKOS BBS-00004356;benzolsulfochloride;rcrawastenumberu020;chlorophenylsulfone;Benzenesulfchloride;Benzenosulfochlorek;BENZENSULFOCHLORIDE;Phenylchloro sulfone
CBNumber
CB6854744
Molecular Formula
C6H5ClO2S
Formula Weight
176.62
MOL File
98-09-9.mol
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Benzenesulfonyl chloride Property

Melting point:
14.5 °C
Boiling point:
251-252 °C(lit.)
Density 
1.384 g/mL at 25 °C(lit.)
vapor pressure 
0.04 mm Hg ( 20 °C)
refractive index 
n20/D 1.551(lit.)
Flash point:
>230 °F
storage temp. 
2-8°C
solubility 
alcohol: soluble
form 
Liquid
color 
Clear
Water Solubility 
may decompose
Sensitive 
Moisture Sensitive
Merck 
14,1072
BRN 
606926
Stability:
Stable. Incompatible with water, strong oxidizing agents, strong bases, methyl formamide, dimethyl sulfoxide.
CAS DataBase Reference
98-09-9(CAS DataBase Reference)
NIST Chemistry Reference
Benzenesulfonyl chloride(98-09-9)
EPA Substance Registry System
Benzenesulfonyl chloride (98-09-9)
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Safety

Hazard Codes 
C
Risk Statements 
20/22-34-42/43-29-22
Safety Statements 
23-26-36/37/39-45
RIDADR 
UN 2225 8/PG 3
WGK Germany 
1
RTECS 
DB8750000
21
TSCA 
Yes
HazardClass 
8
PackingGroup 
III
HS Code 
29049090
Hazardous Substances Data
98-09-9(Hazardous Substances Data)
Toxicity
LD50 orl-rat: 1960 mg/kg MEPAAX 20,513,69
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H290May be corrosive to metals

H302Harmful if swallowed

H314Causes severe skin burns and eye damage

H317May cause an allergic skin reaction

H318Causes serious eye damage

H334May cause allergy or asthma symptoms or breathing difficulties if inhaled

Precautionary statements

P234Keep only in original container.

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P310Immediately call a POISON CENTER or doctor/physician.

P390Absorb spillage to prevent material damage.

P301+P330+P331IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

P406Store in corrosive resistant/… container with a resistant inner liner.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
108111
Product name
Benzenesulfonyl chloride
Purity
96%
Packaging
25g
Price
$30.3
Updated
2020/08/18
Sigma-Aldrich
Product number
108111
Product name
Benzenesulfonyl chloride
Purity
96%
Packaging
1kg
Price
$121
Updated
2020/08/18
TCI Chemical
Product number
B0036
Product name
Benzenesulfonyl Chloride
Purity
>99.0%(GC)(T)
Packaging
25g
Price
$14
Updated
2020/06/24
TCI Chemical
Product number
B0036
Product name
Benzenesulfonyl Chloride
Purity
>99.0%(GC)(T)
Packaging
500g
Price
$36
Updated
2020/06/24
Alfa Aesar
Product number
A10849
Product name
Benzenesulfonyl chloride, 98%
Packaging
1000g
Price
$79.2
Updated
2020/06/24
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Benzenesulfonyl chloride Chemical Properties,Usage,Production

Chemical Properties

colourless oily liquid

Chemical Properties

Benzenesulfonyl chloride is a colorless oily liquid with a pungent odor.

Uses

Intermediates of Liquid Crystals

General Description

A colorless to slightly yellow solid that melts at approximately 40°F. Very irritating to skin, eyes and mucous membranes. May emit toxic fumes when heated to high temperatures. Used to make dyes and other chemicals.

Air & Water Reactions

Insoluble and stable in cold water [Merck]. Decomposes in hot water to produce corrosive and toxic hydrochloric acid and benzenesulfonic acid. Rate of reaction decreases as temperature decreases.

Reactivity Profile

Benzenesulfonyl chloride is incompatible with strong oxidizing agents and bases, including amines. Corrodes metals in the presence of water due to slow formation of hydrochloric acid and benzenesulfonic acid [USCG, 1999]. May react vigorously or explosively if mixed with diisopropyl ether or other ethers in the presence of trace amounts of metal salts [J. Haz. Mat., 1981, 4, 291].

Health Hazard

May be fatal if inhaled, swallowed or absorbed through skin. Contact may cause skin and eye burns. Irritating to eyes, skin and mucous membranes. INGESTION: May cause abdominal spasm and vomiting.

Safety Profile

Poison by intraperitoneal route. Adangerous storage hazard. It may explode in a sealedbottle. Explosive reaction with dimethyl sulfoxide. Reactsvigorously with methyl formamide. When heated todecomposition it emits toxic fumes of Cl- and SO

Potential Exposure

It is used as a chemical intermediate for benzenesulfonamides, thiophenol, glybuzole (hypoglycemic agent), N-2-chloroehtylamides, benzonitrile; for its esters-useful as insecticides, and miticides.

Shipping

UN2225 Benzene sulfonyl chloride, Hazard class: 8; Labels: 8—Corrosive material.

Purification Methods

Distil the sulfonyl chloride, then treat it with 3mole % each of toluene and AlCl3, and allow it to stand overnight. The sulfonyl chloride is distilled off at 1mm pressure and then carefully fractionally distilled at 10mm in an all-glass column. [Adams & Marvel Org Synth Coll Vol I 84 1941, Jensen & Brown J Am Chem Soc 80 4042 1958, Beilstein 11 IV 49.] It is TOXIC.

Incompatibilities

Violent reaction with strong oxidizers, dimethyl sulfoxide, and methyl formamide. It is very reactive with bases and many organic compounds. Incompatible with ammonia, aliphatic amines. Water contact forms hydrochloric and chlorosulfonic acids. Aqueous solutions of this chemical are strong acids that react violently with bases. Attacks metals in presence of moisture.

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Benzenesulfonyl chloride Suppliers

Jiangsu Ford Hongye Chemical Co., Ltd.
Tel
0511-86646111-
Fax
0511-86646222
Email
13861382082@126.com
Country
China
ProdList
1
Advantage
58
Beijing Ouhe Technology Co., Ltd
Tel
010-82967028-
Fax
+86-10-82967029
Email
2355560935@qq.com
Country
China
ProdList
12284
Advantage
60
Shanghai Guoyuan Chemical Co., Ltd.
Tel
0512-55170668- ;
Fax
0512-55170668
Email
shgyhg@139.com;474293744@qq.com
Country
China
ProdList
129
Advantage
58
Beijing dtftchem Technology Co., Ltd.
Tel
010-60275820-
Fax
010-60270825
Email
elainezt@sina.com
Country
China
ProdList
1403
Advantage
62
J & K SCIENTIFIC LTD.
Tel
010-82848833- ;010-82848833-
Fax
86-10-82849933
Email
jkinfo@jkchemical.com;market6@jkchemical.com
Country
China
ProdList
96815
Advantage
76
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
21-61259100-
Fax
86-21-61259102
Email
sh@meryer.com
Country
China
ProdList
40268
Advantage
62
Alfa Aesar
Tel
400-610-6006; 021-67582000
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30163
Advantage
84
TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386 / 800-988-0390
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24555
Advantage
81
Energy Chemical
Tel
021-58432009
Fax
021-58436166-800
Email
sales8178@energy-chemical.com
Country
China
ProdList
44026
Advantage
61
Capot Chemical Co., Ltd
Tel
+86 (0) 571 85 58 67 18
Fax
0086-571-85864795
Email
sales@capotchem.com
Country
China
ProdList
18228
Advantage
66
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View Lastest Price from Benzenesulfonyl chloride manufacturers

Hefei TNJ Chemical Industry Co.,Ltd.
Product
Benzenesulfonyl Chloride 98-09-9
Price
US $0.00/L
Min. Order
200L
Purity
99.5%
Supply Ability
1000MT
Release date
2019-03-08
Shaanxi Dideu Medichem Co. Ltd
Product
Benzenesulfonyl chloride 98-09-9
Price
US $0.10/KG
Min. Order
1KG
Purity
99.0%
Supply Ability
1000 tons
Release date
2020-01-07
career henan chemical co
Product
Benzenesulfonyl chloride 98-09-9
Price
US $1.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
100KG
Release date
2018-08-20

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