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alpha-Toluenesulfonyl chloride

Product Name
alpha-Toluenesulfonyl chloride
CAS No.
1939-99-7
Chemical Name
alpha-Toluenesulfonyl chloride
Synonyms
PHENYLMETHANESULFONYL CHLORIDE;BENZYLSULFONYL CHLORIDE;PMS-CL;NSC 41894;Benzylsulfochloride;OTAVA-BB BB7020430779;BENZYLSULPHONYL CHLORIDE;BENZYL SULFONIC CHLORIDE;à-benzylsulfonyl chloride;BenzylsulfonylChloride>
CBNumber
CB5356892
Molecular Formula
C7H7ClO2S
Formula Weight
190.65
MOL File
1939-99-7.mol
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alpha-Toluenesulfonyl chloride Property

Melting point:
92-94 °C(lit.)
Boiling point:
120 °C / 10mmHg
Density 
1.3264 (estimate)
refractive index 
1.624-1.626
storage temp. 
Inert atmosphere,2-8°C
solubility 
soluble in Toluene
form 
Crystalline Powder
color 
Almost white
Water Solubility 
decomposes
Sensitive 
Moisture Sensitive
BRN 
972806
InChIKey
OAHKWDDSKCRNFE-UHFFFAOYSA-N
CAS DataBase Reference
1939-99-7(CAS DataBase Reference)
NIST Chemistry Reference
Benzenemethanesulfonyl chloride(1939-99-7)
EPA Substance Registry System
Benzenemethanesulfonyl chloride (1939-99-7)
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Safety

Hazard Codes 
C
Risk Statements 
34
Safety Statements 
26-36/37/39-45
RIDADR 
UN 3261 8/PG 2
WGK Germany 
3
10-21
Hazard Note 
Corrosive
TSCA 
T
HazardClass 
8
PackingGroup 
II
HS Code 
29049020
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H314Causes severe skin burns and eye damage

Precautionary statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P363Wash contaminated clothing before reuse.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
159719
Product name
Phenylmethanesulfonyl chloride
Purity
98%
Packaging
5g
Price
$39
Updated
2023/06/20
Sigma-Aldrich
Product number
159719
Product name
Phenylmethanesulfonyl chloride
Purity
98%
Packaging
25g
Price
$90
Updated
2023/06/20
TCI Chemical
Product number
B0441
Product name
Benzylsulfonyl Chloride
Purity
>97.0%(T)
Packaging
25g
Price
$85
Updated
2024/03/01
TCI Chemical
Product number
B0441
Product name
Benzylsulfonyl Chloride
Purity
>97.0%(T)
Packaging
100g
Price
$255
Updated
2024/03/01
Alfa Aesar
Product number
A10124
Product name
alpha-Toluenesulfonyl chloride, 99%
Packaging
5g
Price
$34.65
Updated
2024/03/01
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alpha-Toluenesulfonyl chloride Chemical Properties,Usage,Production

Chemical Properties

almost white crystalline powder

Uses

a-Toluenesulfonyl Chloride inhibits intracellular protein breakdown in the L1210 ascites leukemia in mouse. It also functions as a reagent for the protection of amino groups as benzylsulfonamides which can be cleaved off through reduction.

Synthesis Reference(s)

The Journal of Organic Chemistry, 16, p. 621, 1951 DOI: 10.1021/jo01144a013
Synthesis, p. 1203, 1992 DOI: 10.1055/s-1992-26333

General Description

Phenylmethanesulfonyl chloride is an aliphatic sulfonyl chloride. It reacts with triethylamine in methylene chloride or ether to yield trans-stilbene and cis diphenylethylene sulfone. Its reaction with 1,1-bis(diethylamino)ethane has been studied. Addition of phenylmethanesulfonyl chloride to 1,3-diphenyl-2-pyrrolidinopropene in the presence of water was studied.

alpha-Toluenesulfonyl chloride Preparation Products And Raw materials

Raw materials

Preparation Products

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alpha-Toluenesulfonyl chloride Suppliers

Beijing FYF Chemicals Co., Ltd
Tel
15318973357
Fax
010-57903446
Email
1460285141@qq.com
Country
China
ProdList
2949
Advantage
58
Huai Hua Binfengchem Co., Ltd
Tel
0745-2866851 19152176695
Email
sales@bingfengchem.com
Country
China
ProdList
460
Advantage
58
J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
96815
Advantage
76
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
4006608290; 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40241
Advantage
62
Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30132
Advantage
84
TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24539
Advantage
81
BeiJing Hwrk Chemicals Limted
Tel
0757-86329057 18501085097
Fax
010-89508210
Email
sales3.gd@hwrkchemical.com
Country
China
ProdList
7583
Advantage
55
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44751
Advantage
61
Capot Chemical Co., Ltd
Tel
+86 (0) 571 85 58 67 18
Fax
0086-571-85864795
Email
sales@capotchem.com
Country
China
ProdList
18217
Advantage
66
Beijing Ouhe Technology Co., Ltd
Tel
010-82967028 13552068683
Fax
+86-10-82967029
Email
2355560935@qq.com
Country
China
ProdList
12426
Advantage
60
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View Lastest Price from alpha-Toluenesulfonyl chloride manufacturers

Hebei Dangtong Import and export Co LTD
Product
alpha-Toluenesulfonyl chloride 1939-99-7
Price
US $105.00-95.00/Kilograms
Min. Order
1Kilograms
Purity
99%
Supply Ability
100tons
Release date
2023-02-14
Henan Fengda Chemical Co., Ltd
Product
alpha-Toluenesulfonyl chloride 1939-99-7
Price
US $100.00-1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
g-kg-tons, free sample is available
Release date
2023-12-25
Henan Bao Enluo International TradeCo.,LTD
Product
alpha-Toluenesulfonyl chloride 1939-99-7
Price
US $10.00/kg
Min. Order
1kg
Purity
99.99%
Supply Ability
50000tons
Release date
2023-06-20

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