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alpha-Toluenesulfonyl chloride

Product Name
alpha-Toluenesulfonyl chloride
CAS No.
1939-99-7
Chemical Name
alpha-Toluenesulfonyl chloride
Synonyms
PHENYLMETHANESULFONYL CHLORIDE;BENZYLSULFONYL CHLORIDE;PMS-CL;NSC 41894;Benzylsulfochloride;OTAVA-BB BB7020430779;BENZYLSULPHONYL CHLORIDE;BENZYL SULFONIC CHLORIDE;à-benzylsulfonyl chloride;BenzylsulfonylChloride>
CBNumber
CB5356892
Molecular Formula
C7H7ClO2S
Formula Weight
190.65
MOL File
1939-99-7.mol
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alpha-Toluenesulfonyl chloride Property

Melting point:
92-94 °C(lit.)
Boiling point:
120 °C / 10mmHg
Density 
1.3264 (estimate)
refractive index 
1.624-1.626
storage temp. 
Inert atmosphere,2-8°C
solubility 
soluble in Toluene
form 
Crystalline Powder
color 
Almost white
Water Solubility 
decomposes
Sensitive 
Moisture Sensitive
BRN 
972806
InChIKey
OAHKWDDSKCRNFE-UHFFFAOYSA-N
CAS DataBase Reference
1939-99-7(CAS DataBase Reference)
NIST Chemistry Reference
Benzenemethanesulfonyl chloride(1939-99-7)
EPA Substance Registry System
Benzenemethanesulfonyl chloride (1939-99-7)
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Safety

Hazard Codes 
C
Risk Statements 
34
Safety Statements 
26-36/37/39-45
RIDADR 
UN 3261 8/PG 2
WGK Germany 
3
10-21
Hazard Note 
Corrosive
TSCA 
T
HazardClass 
8
PackingGroup 
II
HS Code 
29049020
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H314Causes severe skin burns and eye damage

Precautionary statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P363Wash contaminated clothing before reuse.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
159719
Product name
Phenylmethanesulfonyl chloride
Purity
98%
Packaging
5g
Price
$39
Updated
2023/06/20
Sigma-Aldrich
Product number
159719
Product name
Phenylmethanesulfonyl chloride
Purity
98%
Packaging
25g
Price
$90
Updated
2023/06/20
TCI Chemical
Product number
B0441
Product name
Benzylsulfonyl Chloride
Purity
>97.0%(T)
Packaging
25g
Price
$85
Updated
2024/03/01
TCI Chemical
Product number
B0441
Product name
Benzylsulfonyl Chloride
Purity
>97.0%(T)
Packaging
100g
Price
$255
Updated
2024/03/01
Alfa Aesar
Product number
A10124
Product name
alpha-Toluenesulfonyl chloride, 99%
Packaging
5g
Price
$34.65
Updated
2024/03/01
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alpha-Toluenesulfonyl chloride Chemical Properties,Usage,Production

Chemical Properties

almost white crystalline powder

Uses

a-Toluenesulfonyl Chloride inhibits intracellular protein breakdown in the L1210 ascites leukemia in mouse. It also functions as a reagent for the protection of amino groups as benzylsulfonamides which can be cleaved off through reduction.

Synthesis Reference(s)

The Journal of Organic Chemistry, 16, p. 621, 1951 DOI: 10.1021/jo01144a013
Synthesis, p. 1203, 1992 DOI: 10.1055/s-1992-26333

General Description

Phenylmethanesulfonyl chloride is an aliphatic sulfonyl chloride. It reacts with triethylamine in methylene chloride or ether to yield trans-stilbene and cis diphenylethylene sulfone. Its reaction with 1,1-bis(diethylamino)ethane has been studied. Addition of phenylmethanesulfonyl chloride to 1,3-diphenyl-2-pyrrolidinopropene in the presence of water was studied.

alpha-Toluenesulfonyl chloride Preparation Products And Raw materials

Raw materials

Preparation Products

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alpha-Toluenesulfonyl chloride Suppliers

Acros Organics
Tel
--
Fax
--
Email
info@acros.com
Country
Belgium
ProdList
6772
Advantage
81
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View Lastest Price from alpha-Toluenesulfonyl chloride manufacturers

HEBEI SHENGSUAN CHEMICAL INDUSTRY CO.,LTD
Product
alpha-Toluenesulfonyl chloride 1939-99-7
Price
US $99.00-66.00/kg
Min. Order
0.0010000000474974513kg
Purity
99%
Supply Ability
5000
Release date
2024-08-19
Hebei Dangtong Import and export Co LTD
Product
alpha-Toluenesulfonyl chloride 1939-99-7
Price
US $105.00-95.00/Kilograms
Min. Order
1Kilograms
Purity
99%
Supply Ability
100tons
Release date
2023-02-14
Henan Fengda Chemical Co., Ltd
Product
alpha-Toluenesulfonyl chloride 1939-99-7
Price
US $100.00-1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
g-kg-tons, free sample is available
Release date
2023-12-25

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