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Cinnamyl acetate

Product Name
Cinnamyl acetate
CAS No.
103-54-8
Chemical Name
Cinnamyl acetate
Synonyms
cinnamyl;3-PHENYLALLYL ACETATE;ACETIC ACID CINNAMYL ESTER;CF-60;FEMA 2293;binsuanguizhi;Cinnamylacetat;Ciamyl acetate;Gui acid ester;CINNAMICACETATE
CBNumber
CB4721897
Molecular Formula
C11H12O2
Formula Weight
176.21
MOL File
103-54-8.mol
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Cinnamyl acetate Property

Melting point:
30 °C
Boiling point:
265 °C(lit.)
Density 
1.057 g/mL at 25 °C
vapor pressure 
16Pa at 20℃
FEMA 
2293 | CINNAMYL ACETATE
refractive index 
n20/D 1.541(lit.)
Flash point:
>230 °F
storage temp. 
2-8°C
solubility 
alcohol: soluble(lit.)
form 
Liquid
color 
Colorless to Light yellow
Odor
at 100.00 %. sweet floral spicy balsam cinnamon
Odor Type
spicy
Water Solubility 
176.2mg/L(temperature not stated)
JECFA Number
650
LogP
2.7 at 35℃
CAS DataBase Reference
103-54-8(CAS DataBase Reference)
NIST Chemistry Reference
2-Propen-1-ol, 3-phenyl-, acetate(103-54-8)
EPA Substance Registry System
2-Propen-1-ol, 3-phenyl-, acetate (103-54-8)
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Safety

Hazard Codes 
Xi
Risk Statements 
36
Safety Statements 
26-37/39-24/25
WGK Germany 
1
RTECS 
GE2275000
HS Code 
29153900
Toxicity
The acute oral LD50 in rats was reported to be 3.3 g/kg (2.9-3.7 g/kg) (Moreno, 1972). The acute dermal LD50 was reported to be > 5 g/kg in the rabbit (Moreno, 1972).
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H319Causes serious eye irritation

Precautionary statements

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
W229318
Product name
Cinnamyl acetate
Purity
≥98%, FCC, FG
Packaging
1kg
Price
$143
Updated
2024/03/01
Sigma-Aldrich
Product number
166170
Product name
Cinnamyl acetate
Purity
99%
Packaging
250ml
Price
$66.1
Updated
2024/03/01
Sigma-Aldrich
Product number
W229318
Product name
Cinnamyl acetate
Purity
≥98%, FCC, FG
Packaging
5kg
Price
$345
Updated
2023/06/20
Sigma-Aldrich
Product number
W229301
Product name
Cinnamyl acetate
Purity
natural, 95%, FG
Packaging
100g
Price
$117
Updated
2022/05/15
Sigma-Aldrich
Product number
W229301
Product name
Cinnamyl acetate
Purity
natural, 95%, FG
Packaging
1kg
Price
$249
Updated
2022/05/15
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Cinnamyl acetate Chemical Properties,Usage,Production

Chemical Properties

clear colorless to pale yellowish liquid

Chemical Properties

Cinnamyl acetate has a characteristic balsamic-floral odor and burning, sweet taste reminiscent of pineapple. The ester obtained from natural cinnamyl alcohol exhibits a more delicate (hyacinth–jasmine-like) note.

Occurrence

Reported found in melon, starfruit, tarragon and litchi.

Uses

Cinnamyl Acetate is used in preparation and characterization of cinnamon essential oil nanocapsules and comparison of volatile components and antibacterial ability of cinnamon essential oil before and after encapsulation.

Uses

Perfumery (fixative), flavoring.

Application

Cinnamyl acetate is used as a modifier for Cinnamic alcohol and as a warm-spicy-floral note in heavy florals, Hyacinth, etc. It can also introduce warmth to a Rose composition at a discrete concentration level. Used in flavor compositions for imitation Apple, Apricol, Berry, Cherry, Cinnamon, Cassia, Grape, Peach, Pineapple, Quince, Vanilla, etc.

Preparation

By direct esterification of cinnamic alcohol with acetic acid (or anhydride) under azeotropic conditions (Arctander, 1969).

Definition

ChEBI: An acetate ester resulting from the formal condensation of cinnamyl alcohol with acetic acid. Found in cinnamon leaf oil.

Taste threshold values

Taste characteristics at 15 ppm: sweet, spicy, floral, cinnamon and honey with a tutti-fruitti nuance.

Synthesis Reference(s)

Journal of the American Chemical Society, 90, p. 5518, 1968 DOI: 10.1021/ja01022a034

General Description

Cinnamyl acetate is a fragrance ingredient. Palladium catalyzed allylic alkylation of cinnamyl acetate using sodium diethyl 2-methylmalonate and novel ferrocenyl Schiff base has been investigated.

Flammability and Explosibility

Non flammable

Safety Profile

Moderately toxic by ingestion and intraperitoneal routes. A skin irritant. Combustible liquid. When heated to decomposition it emits acrid smoke and fumes. See also ALLYL COMPOUNDS.

Cinnamyl acetate Preparation Products And Raw materials

Raw materials

Preparation Products

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Cinnamyl acetate Suppliers

TOKYO CHEMICAL INDUSTRY CO., LTD.
Tel
03-36680489
Fax
03-3668-0520
Email
Sales-JP@TCIchemicals.com
Country
Japan
ProdList
28387
Advantage
80
Hattori Corporation
Tel
--
Fax
--
Email
info@hattoricorp.com
Country
Japan
ProdList
1254
Advantage
58
Inoue Perfumery Mfg. Co., Ltd
Tel
--
Fax
--
Country
Japan
ProdList
346
Advantage
58
Inoue Perfumery MFG. Co., Ltd.
Tel
--
Fax
--
Email
ino-p@ino-p.com
Country
Japan
ProdList
137
Advantage
58
Wako Pure Chemical Industries, Ltd.
Tel
--
Fax
--
Email
labchem-tec@wako-chem.co.jp
Country
Japan
ProdList
6819
Advantage
80
Kanto Chemical Co., Inc.
Tel
--
Fax
--
Email
reag-info@gms.kanto.co.jp
Country
Japan
ProdList
6756
Advantage
74
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View Lastest Price from Cinnamyl acetate manufacturers

Hebei Zhuanglai Chemical Trading Co.,Ltd
Product
Cinnamyl acetate 103-54-8
Price
US $99.00-35.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
20ton
Release date
2024-05-17
WUHAN FORTUNA CHEMICAL CO., LTD
Product
Cinnamyl acetate 103-54-8
Price
US $0.00-0.00/kg
Min. Order
25kg
Purity
99%
Supply Ability
10000kg
Release date
2023-01-14
Hebei Weibang Biotechnology Co., Ltd
Product
Cinnamyl acetate 103-54-8
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
500000kg
Release date
2024-11-01

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