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Bis(2,4-pentanedionato-O,O')palladium(II)

Product Name
Bis(2,4-pentanedionato-O,O')palladium(II)
CAS No.
14024-61-4
Chemical Name
Bis(2,4-pentanedionato-O,O')palladium(II)
Synonyms
PALLADIUM(II) ACETYLACETONATE;PALLADIUM ACETYLACETONATE;BIS(ACETYLACETONATO)PALLADIUM(II);BIS(2,4-PENTANEDIONATO)PALLADIUM(II);ACETYLACETONE, PALLADIUM(II) DERIVATIVE;34.7%Pd;Umicore, 99%;Palladium acet;PALLADIUM-ACETYLACETONAT;Palladous acetylacetonate
CBNumber
CB4751427
Molecular Formula
C10H14O4Pd
Formula Weight
304.64
MOL File
14024-61-4.mol
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Bis(2,4-pentanedionato-O,O')palladium(II) Property

Melting point:
190 °C
vapor pressure 
0Pa at 25℃
storage temp. 
Store below +30°C.
solubility 
Soluble in benzene and chloroform.
form 
Solution
color 
Yellow to orange
Specific Gravity
1.862
Water Solubility 
INSOLUBLE
Hydrolytic Sensitivity
4: no reaction with water under neutral conditions
BRN 
4136188
InChI
InChI=1S/2C5H8O2.Pd/c2*1-4(6)3-5(2)7;/h2*3,6H,1-2H3;/q;;+2/p-2/b2*4-3-;
InChIKey
RJJXYEQOOACRKP-LNKPDPKZSA-M
SMILES
O([Pd]O/C(/C)=C\C(=O)C)/C(/C)=C\C(=O)C
LogP
2.6 at 25℃
NIST Chemistry Reference
Bis(acetylacetonato)palladium(14024-61-4)
EPA Substance Registry System
Palladium, bis(2,4-pentanedionato-.kappa.O,.kappa.O')-, (SP-4-1)- (14024-61-4)
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Safety

Hazard Codes 
Xi,Xn
Risk Statements 
36-36/37/38-22
Safety Statements 
26-37/39
RIDADR 
3181
WGK Germany 
2
TSCA 
Yes
HS Code 
28439090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H319Causes serious eye irritation

Precautionary statements

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
209015
Product name
Palladium(II) acetylacetonate
Purity
99%
Packaging
1g
Price
$102
Updated
2024/03/01
Sigma-Aldrich
Product number
209015
Product name
Palladium(II) acetylacetonate
Purity
99%
Packaging
5g
Price
$410
Updated
2024/03/01
Sigma-Aldrich
Product number
8.07103
Product name
Palladium(II) acetylacetonate
Purity
≥98% (ICP)
Packaging
1g
Price
$77.51
Updated
2021/12/16
Sigma-Aldrich
Product number
8.07103
Product name
Palladium(II) acetylacetonate
Purity
≥98% (ICP)
Packaging
5G
Price
$312.65
Updated
2021/12/16
TCI Chemical
Product number
B2018
Product name
Bis(2,4-pentanedionato)palladium(II)
Purity
>98.0%(T)
Packaging
1g
Price
$187
Updated
2024/03/01
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Bis(2,4-pentanedionato-O,O')palladium(II) Chemical Properties,Usage,Production

Chemical Properties

yellow orange needles

Uses

Palladium(II) Acetylacetonate is an active anticancer agent. Exhibits growth inhibitory effect more than cisplatin in several cancer cells and treatment with Palladium(II) Acetylacetonate inhibits H460 cells. Palladium(II) Acetylacetonate is a catalyst for various organic transformations.

Uses

Palladium(II) acetylacetonate (Pd(acac)2) was used in the following studies:

  • Typical high-temperature organic solution phase protocol for the preparation of monodisperse CuPd alloy nanoparticles (NPs).
  • Preparation of [(NHC)Pd(acac)L] (where L=Me, NHC = N-heterocyclic carbene) complexes. These complexes efficiently catalyze the Heck reaction of activated aryl bromides.
  • As catalyst in the decarboxylative cross-coupling of arylcarboxylic acids with aryl halides.

General Description

Palladium(II) acetylacetonate (Pd(acac)2) is a metal-organic complex. Sublimation of Pd(acac)2 has been investigated by thermogravimetry and XRD. The temperature range for the sublimation of Pd(acac)2, without undergoing thermal decomposition, was determined to be 100-160°C in the presence of inert gas helium.

Flammability and Explosibility

Highly flammable

Purification Methods

It can be recrystallised from *C6H6/pet ether and sublimes in vacuo. It is soluble in heptane, *C6H6 (1.2% at 20o, 2.2 at 40o), toluene (0.56% at 20o, 1.4% at 40o) and acetylacetone (1.2% at 20o, 0.05% at 40o). [West & Riley J Inorg Nucl Chem 5 295 1957/8, Fernelius & Bryant Inorg Synth V 105 1957, Beilstein 1 IV 3676.]

Bis(2,4-pentanedionato-O,O')palladium(II) Preparation Products And Raw materials

Raw materials

Acetonitrile Acetylacetone 1,3-Dichloropropane Toluene Palladium chloride

Preparation Products

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Bis(2,4-pentanedionato-O,O')palladium(II) Suppliers

Americas 1 Belgium 4 Brazil 1 China 226 Europe 1 Finland 1 France 2 Germany 9 India 19 Japan 8 Singapore 1 South Korea 2 Switzerland 2 The Netherlands 1 Ukraine 1 United Kingdom 8 United States 45 Global 332
ASCHEM GmbH
Tel
--
Fax
--
Email
info@aschem.ch
Country
Switzerland
ProdList
897
Advantage
58
SIGMA-RBI
Tel
--
Fax
--
Country
Switzerland
ProdList
6896
Advantage
91
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View Lastest Price from Bis(2,4-pentanedionato-O,O')palladium(II) manufacturers

Hebei Zhuanglai Chemical Trading Co.,Ltd
Product
Bis(2,4-pentanedionato-O,O')palladium(II) 14024-61-4
Price
US $10.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
20ton
Release date
2024-05-30
Hebei Mojin Biotechnology Co., Ltd
Product
Bis(2,4-pentanedionato-O,O')palladium(II) 14024-61-4
Price
US $0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
50000KG/month
Release date
2024-03-26
Zhuozhou Wenxi import and Export Co., Ltd
Product
Bis(2,4-pentanedionato-O,O")palladium(II) 14024-61-4
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-07-11

14024-61-4, Bis(2,4-pentanedionato-O,O')palladium(II)Related Search:

Tungsten hexacarbonyl VANADIUM(III) ACETYLACETONATE Bis(dibenzylideneacetone)palladium Palladium (II) Acetate Palladium chloride Vanadyl acetylacetonate 3-methyl-1-(2,6,6-trimethylcyclohex-1-en-1-yl)penta-1,4-dien-3-ol Vinyltrimethoxysilane CADMIUM 2,4-PENTANEDIONATE, HYDRATE Calcium acetylacetonate Vinylmagnesium chloride ZIRCONIUM(IV) ACETYLACETONATE Sodium ethylenesulphonate Platinum bis(acetylacetonate) Palladium(II) Chloride Crystals Bis(acetylacetonato)cobalt Aluminum acetylacetonate Nickel(II) acetylacetonate

  • ACETYLACETONE, PALLADIUM(II) DERIVATIVE
  • ACETYLACETONE PALLADIUM(II) SALT
  • Palladium acetylacetonate or Palladium(II)2,4-pentanedionate
  • Bis(acetylacetonato)palladium(II) dec. 205 halide free source of Pd
  • bis(2,4-pentanedionato-o,o')palladium(ii)
  • BIS(2,4-PENTANEDIONATO)PALLADIUM(II)
  • BIS(ACETYLACETONATO)PALLADIUM(II)
  • Bis(2,4-pentanedionato-O,O')palladium(II),99%
  • Bis(acetylacetonato) palladium(II) ,99%
  • Palladium(II) acetylacetonate,Palladium(II) 2,4-pentanedionate
  • Bis(acetylacetonato) palladiuM(II) ,99% [C% :39.06%-39.66%]
  • Bis(acetylacetonato)palladium(Ⅱ)
  • Bis(acetylaceto)palladium(II)
  • Bis(acetylacetonato)palladium(II)~Bis(2,4-pentanedionato)palladium(II)~Palladium(II) 2,4-pentanedionate
  • palladium (II) di(4-oxopent-2-en-2-oate)
  • bis (acetylacetonate) palladium (II)
  • 34.7%Pd
  • Palladous acetylacetonate
  • Palladium(II) acetylacetonate, 35% Pd
  • PALLADIUM-ACETYLACETONAT
  • PALLADIUM (II) ACETYLACETONATE 99%
  • Palladium(II)acetylacetonate,99%
  • Palladium, bis(2,4-pentanedionato-.kappa.O,.kappa.O)-, (SP-4-1)-
  • Bis(acetylacetonato)palladium(II), 35% Pd
  • Bis(acetylacetonato)palladium(II), 35% Pd, Product of Umicore
  • Palladium acet
  • Bis(dibenzylidenaceton)palladium
  • Palladium(II) Acetylacetonate (Pd(acac)2)
  • PalladiuM(II) acetylacetonate, 35% Pd 1GR
  • PalladiuM(II) acetylacetonate,98%
  • Acetylacetone Palladium(II) Salt Palladium(II) Acetylacetonate
  • Bis(acetylacetonato)palladiuM(Ⅱ), 35% Pd, Product of UMicore
  • PALLADIUM(II) ACETYLACETONATE FOR SYNTHE
  • Palladium(II) acetylacetonate Vetec(TM) reagent grade, 98%
  • Palladium(Ⅱ) Acetylacetonate
  • PALLADIUM(II) 2,4-ACETYLACETONATE
  • PALLADIUM (II) 2,4-PENTANEDIONATE
  • PALLADIUM ACETYLACETONATE
  • PALLADIUM 2,4-PENTANEDIONATE
  • PALLADIUM(II) ACETYLACETONATE
  • 4-pentanedionato-o,o’)-bis((sp-4-1)-palladiu
  • Bis(2,4-pentanedionato)palladium
  • Palladium bis(2,4-pentanedionate)
  • Palladium bis(acetoacetonate)
  • Palladium bis(acetylacetonate)
  • Palladium diacetylacetonate
  • Palladium, bis(2,4-pentanedionato)-
  • Palladium, bis(2,4-pentanedionato-O,O')-, (SP-4-1)-
  • Palladium(II) acetylacetonate,98%,Pd>34.9%
  • Palladium, bis(2,4-pentanedionato-kO,kO')-, (SP-4-1)-
  • Bis(2,4-pentanedionato-O,O')palladium(II) ISO 9001：2015 REACH
  • Umicore, 99%
  • Palladium (II) Acetylacetonate (Pd(acac)2) extrapure, 34.7% Pd
  • (E)-4-oxopent-2-en-2-olate
  • Bis(2,4-pentanedionato-O,O')palladium(II)
  • bis[(E)-1-acetyl-2-hydroxy-prop-1-enyl]palladium
  • Palladium(II) 2,4-pentanedionate [“Palladium acetylacetonate”
  • 14024-61-4