4,5-DIMETHOXY-2-NITROBENZYL BROMIDE

Product Name: 4,5-DIMETHOXY-2-NITROBENZYL BROMIDE
CAS No.: 53413-67-5
Chemical Name: 4,5-DIMETHOXY-2-NITROBENZYL BROMIDE
Synonyms: 6-NITROVERATRYL BROMIDE;1-(Bromomethyl)-4,5-dimethoxy-2-nitrobenzene;-4,5-dimethoxy-2-nitrobenzene;-4,5-dimethoxy-2-nitrobenzene;4,5-dimenoxy-2-nitrobenzyl bromide;3,4-Dimethoxy-6-nitrobenzyl bromide;4,5-DIMETHOXY-2-NITROBENZYL BROMIDE;4,5-Dimethoxy-2-nitrobenzyl bromide 95%;4,5-Dimethoxy-2-nitro-1-bromomethylbenzene;1-(bromomethyl)-2-nitro-4,5-dimethoxybenzene
CBNumber: CB4762285
Molecular Formula: C9H10BrNO4
Formula Weight: 276.08
MOL File: 53413-67-5.mol

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4,5-DIMETHOXY-2-NITROBENZYL BROMIDE Property

Melting point:: 131-133 °C (lit.)
Boiling point:: 372.3±37.0 °C(Predicted)
Density: 1.544
storage temp.: under inert gas (nitrogen or Argon) at 2-8°C
form: Crystalline Powder or Needles
color: Yellow to brown
Sensitive: Lachrymatory

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Safety

Hazard Codes: C
Risk Statements: 34
Safety Statements: 22-26-27-36/37/39-45
RIDADR: UN 3261 8/PG 2
WGK Germany: 3
HazardClass: 8
PackingGroup: III
HS Code: 29093090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H314Causes severe skin burns and eye damage

Precautionary statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P363Wash contaminated clothing before reuse.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 392855
Product name: 4,5-Dimethoxy-2-nitrobenzyl bromide
Purity: 97%
Packaging: 1g
Price: $124
Updated: 2024/03/01

Sigma-Aldrich

Product number: 392855
Product name: 4,5-Dimethoxy-2-nitrobenzyl bromide
Purity: 97%
Packaging: 5g
Price: $196.8
Updated: 2024/03/01

Biosynth Carbosynth

Product number: FB139514
Product name: 4,5-Dimethoxy-2-nitrobenzyl bromide
Packaging: 5G
Price: $550
Updated: 2021/12/16

AK Scientific

Product number: 7598AB
Product name: 1-(Bromomethyl)-4,5-dimethoxy-2-nitrobenzene
Packaging: 5g
Price: $271
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FB139514
Product name: 4,5-Dimethoxy-2-nitrobenzyl bromide
Packaging: 2g
Price: $320
Updated: 2021/12/16

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4,5-DIMETHOXY-2-NITROBENZYL BROMIDE Chemical Properties,Usage,Production

Uses

1-(Bromomethyl)-4,5-dimethoxy-2-nitrobenzene is a useful research chemical.

Uses

4,5-Dimethoxy-2-nitrobenzyl bromide (DMNB bromide, 6-nitroveratryl bromide) is suitable reagent used in the synthesis of N-(4,5-dimethoxy-2-nitrobenzyl)vanillylamine which forms caged vanilloid. It may be used in the synthesis of the following:

4-(4′,5′-dimethoxy-2-nitrobenzyloxy)benzaldehyde, a DMNB-caged aldehyde
N-[4-[(4,5-dimethoxy-2-nitrobenzyl)oxy]-3-methoxybenzyl]acetamide
caged derivative of pyridostatin ([C]-PDS)
photosensitive polyimide (PI-DMNB)
caged β-ecdysone
4-tert-butyldimethylsilyloxy-1-(2-deoxy-3,5-di-O-toluoyl-β-D-ribofuranosyl)-2-(6-nitroveratrylthio)-1H-benzimidazole, an intermediate in synthesis of phosphoramidite bearing 4-hydroxy-2-mercaptobenzimidazole (SB^NV) nucleobase
alkylation of dihydrofluorescein
4-(4′,5′-Dimethoxy-2′-nitrobenzyloxy)benzaldehyde

General Description

4,5-Dimethoxy-2-nitrobenzyl bromide (DMNBB, 1-(Bromomethyl)-4,5-dimethoxy-2-nitrobenzene) is a 4,5-dimethoxy-2-nitrobenzyl derivative. 4,5-Dimethoxy-2-nitrobenzyl (DMNB) group of DMNBB is used as a photolabile protecting group in caging technology to develop pro-drugs. Synthesis of 1-(bromomethyl)-4,5-dimethoxy-2-nitrobenzene by using 6-nitroveratraldehyde as starting reagent has been reported.

4,5-DIMETHOXY-2-NITROBENZYL BROMIDE Preparation Products And Raw materials

Raw materials

Preparation Products

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4,5-DIMETHOXY-2-NITROBENZYL BROMIDE Suppliers

China 64 India 1 Switzerland 1 United Kingdom 2 United States 12 Global 80

Henan Alpha Chemical Co., Ltd.

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53413-67-5, 4,5-DIMETHOXY-2-NITROBENZYL BROMIDERelated Search:

3-(BROMOMETHYL)PHENOL 3-METHOXYBENZYL BROMIDE 2-(bromomethyl)-Benzenamine 4-Methoxybenzyl bromide 4,5-DIMETHOXY-2-NITROBENZYL BROMIDE 4-AMINOCATECHOL HBR 4-Methoxy-2-nitrobenzyl bromide 2-Nitrobenzyl bromide 4-(BROMOMETHYL)PHENOL 3,4-DIMETHOXYBENZYL BROMIDE 2-(BROMOMETHYL)-4-METHOXY-1-NITROBENZENE

4,5-DIMETHOXY-2-NITROBENZYL BROMIDE

6-NITROVERATRYL BROMIDE

1-(Bromomethyl)-4,5-dimethoxy-2-nitrobenzene

4,5-Dimethoxy-2-nitrobenzyl bromide 95%

1-(bromomethyl)-2-nitro-4,5-dimethoxybenzene

4,5-dimenoxy-2-nitrobenzyl bromide

3,4-Dimethoxy-6-nitrobenzyl bromide

4,5-Dimethoxy-2-nitro-1-bromomethylbenzene

-4,5-dimethoxy-2-nitrobenzene

JR-13611, 1-(Bromomethyl)-4,5-dimethoxy-2-nitrobenzene, 97%

Benzene, 1-(bromomethyl)-4,5-dimethoxy-2-nitro-

-4,5-dimethoxy-2-nitrobenzene

53413-67-5

O2NC6H2OCH32CH2Br

Organic Building Blocks

Nitrogen Compounds

Nitro Compounds

Building Blocks