ChemicalBook > CAS DataBase List > 4,5-DIMETHOXY-2-NITROBENZYL BROMIDE

4,5-DIMETHOXY-2-NITROBENZYL BROMIDE

Product Name
4,5-DIMETHOXY-2-NITROBENZYL BROMIDE
CAS No.
53413-67-5
Chemical Name
4,5-DIMETHOXY-2-NITROBENZYL BROMIDE
Synonyms
6-NITROVERATRYL BROMIDE;1-(Bromomethyl)-4,5-dimethoxy-2-nitrobenzene;-4,5-dimethoxy-2-nitrobenzene;-4,5-dimethoxy-2-nitrobenzene;4,5-dimenoxy-2-nitrobenzyl bromide;3,4-Dimethoxy-6-nitrobenzyl bromide;4,5-DIMETHOXY-2-NITROBENZYL BROMIDE;4,5-Dimethoxy-2-nitrobenzyl bromide 95%;4,5-Dimethoxy-2-nitro-1-bromomethylbenzene;1-(bromomethyl)-2-nitro-4,5-dimethoxybenzene
CBNumber
CB4762285
Molecular Formula
C9H10BrNO4
Formula Weight
276.08
MOL File
53413-67-5.mol
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4,5-DIMETHOXY-2-NITROBENZYL BROMIDE Property

Melting point:
131-133 °C (lit.)
Boiling point:
372.3±37.0 °C(Predicted)
Density 
1.544
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
form 
Crystalline Powder or Needles
color 
Yellow to brown
Sensitive 
Lachrymatory
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Safety

Hazard Codes 
C
Risk Statements 
34
Safety Statements 
22-26-27-36/37/39-45
RIDADR 
UN 3261 8/PG 2
WGK Germany 
3
HazardClass 
8
PackingGroup 
III
HS Code 
29093090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H314Causes severe skin burns and eye damage

Precautionary statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P363Wash contaminated clothing before reuse.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
392855
Product name
4,5-Dimethoxy-2-nitrobenzyl bromide
Purity
97%
Packaging
1g
Price
$124
Updated
2024/03/01
Sigma-Aldrich
Product number
392855
Product name
4,5-Dimethoxy-2-nitrobenzyl bromide
Purity
97%
Packaging
5g
Price
$196.8
Updated
2024/03/01
Biosynth Carbosynth
Product number
FB139514
Product name
4,5-Dimethoxy-2-nitrobenzyl bromide
Packaging
250mg
Price
$75
Updated
2021/12/16
Biosynth Carbosynth
Product number
FB139514
Product name
4,5-Dimethoxy-2-nitrobenzyl bromide
Packaging
500mg
Price
$120
Updated
2021/12/16
SynQuest Laboratories
Product number
4754-9-00
Product name
4,5-Dimethoxy-2-nitrobenzyl bromide
Purity
95%
Packaging
1g
Price
$125
Updated
2021/12/16
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4,5-DIMETHOXY-2-NITROBENZYL BROMIDE Chemical Properties,Usage,Production

Uses

1-(Bromomethyl)-4,5-dimethoxy-2-nitrobenzene is a useful research chemical.

Uses

4,5-Dimethoxy-2-nitrobenzyl bromide (DMNB bromide, 6-nitroveratryl bromide) is suitable reagent used in the synthesis of N-(4,5-dimethoxy-2-nitrobenzyl)vanillylamine which forms caged vanilloid. It may be used in the synthesis of the following:

  • 4-(4′,5′-dimethoxy-2-nitrobenzyloxy)benzaldehyde, a DMNB-caged aldehyde
  • N-[4-[(4,5-dimethoxy-2-nitrobenzyl)oxy]-3-methoxybenzyl]acetamide
  • caged derivative of pyridostatin ([C]-PDS)
  • photosensitive polyimide (PI-DMNB)
  • caged β-ecdysone
  • 4-tert-butyldimethylsilyloxy-1-(2-deoxy-3,5-di-O-toluoyl-β-D-ribofuranosyl)-2-(6-nitroveratrylthio)-1H-benzimidazole, an intermediate in synthesis of phosphoramidite bearing 4-hydroxy-2-mercaptobenzimidazole (SBNV) nucleobase
  • alkylation of dihydrofluorescein
  • 4-(4′,5′-Dimethoxy-2′-nitrobenzyloxy)benzaldehyde

General Description

4,5-Dimethoxy-2-nitrobenzyl bromide (DMNBB, 1-(Bromomethyl)-4,5-dimethoxy-2-nitrobenzene) is a 4,5-dimethoxy-2-nitrobenzyl derivative. 4,5-Dimethoxy-2-nitrobenzyl (DMNB) group of DMNBB is used as a photolabile protecting group in caging technology to develop pro-drugs. Synthesis of 1-(bromomethyl)-4,5-dimethoxy-2-nitrobenzene by using 6-nitroveratraldehyde as starting reagent has been reported.

4,5-DIMETHOXY-2-NITROBENZYL BROMIDE Preparation Products And Raw materials

Raw materials

Preparation Products

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4,5-DIMETHOXY-2-NITROBENZYL BROMIDE Suppliers

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53413-67-5, 4,5-DIMETHOXY-2-NITROBENZYL BROMIDERelated Search:

3-(BROMOMETHYL)PHENOL 3-METHOXYBENZYL BROMIDE 2-(bromomethyl)-Benzenamine 4-Methoxybenzyl bromide 4,5-DIMETHOXY-2-NITROBENZYL BROMIDE 4-AMINOCATECHOL HBR 4-Methoxy-2-nitrobenzyl bromide 2-Nitrobenzyl bromide 4-(BROMOMETHYL)PHENOL 3,4-DIMETHOXYBENZYL BROMIDE 2-(BROMOMETHYL)-4-METHOXY-1-NITROBENZENE

  • 4,5-DIMETHOXY-2-NITROBENZYL BROMIDE
  • 6-NITROVERATRYL BROMIDE
  • 1-(Bromomethyl)-4,5-dimethoxy-2-nitrobenzene
  • 4,5-Dimethoxy-2-nitrobenzyl bromide 95%
  • 1-(bromomethyl)-2-nitro-4,5-dimethoxybenzene
  • 4,5-dimenoxy-2-nitrobenzyl bromide
  • 3,4-Dimethoxy-6-nitrobenzyl bromide
  • 4,5-Dimethoxy-2-nitro-1-bromomethylbenzene
  • -4,5-dimethoxy-2-nitrobenzene
  • JR-13611, 1-(Bromomethyl)-4,5-dimethoxy-2-nitrobenzene, 97%
  • Benzene, 1-(bromomethyl)-4,5-dimethoxy-2-nitro-
  • -4,5-dimethoxy-2-nitrobenzene
  • 53413-67-5
  • O2NC6H2OCH32CH2Br
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  • Nitrogen Compounds
  • Nitro Compounds
  • Building Blocks