Iodine trichloride
Uses Preparation Reactions Toxicity- Product Name
- Iodine trichloride
- CAS No.
- 865-44-1
- Chemical Name
- Iodine trichloride
- Synonyms
- Trichloroiodine;Iodine trichlorid;IODINE TRICHLORIDE;IODINE TRICHLOHIDE;Indine Trichloride;Iodine richloride;IODINE CHLORIDE, TRI;iodinechloride(icl3);Iodine(III) trichloride;IodineTrichlorideForSynthesis
- CBNumber
- CB4854487
- Molecular Formula
- Cl3I
- Formula Weight
- 233.26
- MOL File
- 865-44-1.mol
Iodine trichloride Property
- Melting point:
- ~33°; mp 101° at 16 atm (pressure of its satd vapor)
- Density
- 3.12 g/cm3 (20℃)
- vapor pressure
- 1.3 hPa (64 °C)
- storage temp.
- Store at <= 20°C.
- solubility
- Soluble with decomposition.
- form
- yellow triclinic crystals
- color
- yellow triclinic crystals, crystalline; hygroscopic
- Water Solubility
- decomposes in H2O; soluble alcohol, benzene [HAW93]
- Sensitive
- Light Sensitive
- Merck
- 13,5042
- CAS DataBase Reference
- 865-44-1(CAS DataBase Reference)
- NIST Chemistry Reference
- iodine chloride(865-44-1)
- EPA Substance Registry System
- Iodine chloride (ICl3) (865-44-1)
Safety
- Hazard Codes
- C,T,O
- Risk Statements
- 34-9
- Safety Statements
- 26-36/37/39-45
- RIDADR
- UN 3085 5.1/PG 2
- WGK Germany
- 3
- F
- 8-10
- TSCA
- Yes
- HazardClass
- 8
- PackingGroup
- II
- HS Code
- 28121099
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H290May be corrosive to metals
H314Causes severe skin burns and eye damage
H335May cause respiratory irritation
- Precautionary statements
-
P234Keep only in original container.
P260Do not breathe dust/fume/gas/mist/vapours/spray.
P271Use only outdoors or in a well-ventilated area.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- 8.04772
- Product name
- Iodine trichloride
- Purity
- for synthesis
- Packaging
- 25g
- Price
- $92.3
- Updated
- 2024/03/01
- Product number
- 8.04772
- Product name
- Iodine trichloride
- Purity
- for synthesis
- Packaging
- 100g
- Price
- $222
- Updated
- 2024/03/01
- Product number
- 8.04772
- Product name
- Iodine trichloride
- Purity
- for synthesis
- Packaging
- 2.5kg
- Price
- $4470
- Updated
- 2024/03/01
- Product number
- 359122
- Product name
- Iodine trichloride
- Purity
- 97%
- Packaging
- 50g
- Price
- $119
- Updated
- 2024/03/01
- Product number
- H56005
- Product name
- Iodine trichloride, 97%
- Packaging
- 5g
- Price
- $27.65
- Updated
- 2024/03/01
Iodine trichloride Chemical Properties,Usage,Production
Uses
Iodine trichloride is used in organic synthesis as a chlorinating and iodinating agent to introduce chlorine and iodine into organic compounds producing their halogen derivatives. It also is used as a topical antiseptic.
Preparation
Iodine trichloride is prepared by adding iodine to liquid chlorine in a stoichiometric amount:
3Cl2 + I2 → 2ICl3
Reactions
Iodine trichloride decomposes on heating at 77°C, forming iodine monochloride and chlorine:
ICl3 →ICl + Cl2
It dissolves in concentrated hydrochloric acid , forming HICl4•4H2O:
ICl3 + HCl + 4H2O → HICl4•4H2O
Iodine trichloride hydrolyzes in water or dilute acids, the products depending upon reaction conditions. This reaction usually is similar to iodine monochloride:
4ICl3 + 6H2O → I2 + 6HCl + 2HIO3 + 3Cl2
It combines with potassium chloride, forming a complex salt, KICl4:
ICl3 + KCl → KICl4
Reaction with acetylene produces chlorovinyl iododichloride, containing two active chlorine atoms attached to the iodine atom:
ICl3 + HC≡CH → ClCH=CHICl2
The above product has many applications in chemical synthesis.
Toxicity
Iodine trichloride is highly corrosive. Contact with skin can cause a burn. Vapors are highly irritating to eyes and respiratory tract.
Chemical Properties
Orange-yellow, deliquescent, crystalline powder; pungent irritating odor. Soluble in water (with decomposition), alcohol, and benzene.
Physical properties
Orange yellow triclinic crystals or fluffy powder; hygroscopic; density 3.111g/cm3at 15°C; sublimes at 64°C with decomposition; melts at 101°C at 16 atm;hydrolyzes in water; soluble in ethanol, carbon tetrachloride and benzene; soluble in concentrated hydrochloric acid but hydrolyzes in dilute acid.
Uses
Iodine trichloride can be used to introduce iodine and chlorine in organic synthesis. It is also used as topical antiseptic and as laboratory reagent.
Uses
Iodine trichloride is used as a chlorinatingand oxidizing agent.
Uses
Chlorinating and oxidizing agent.
Hazard
Toxic by ingestion and inhalation, corrosive to tissue.
Health Hazard
Iodine trichloride is a highly corrosive sub stance. Skin contact can cause burn. Vaporsare irritating to the skin, eyes, and mucousmembranes. When heated at 77°C (170°F),it decomposes to chlorine and iodine mono chloride.
Fire Hazard
Noncombustible solid. Violent reaction oc curs with potassium. It reacts violently when heated with sodium, aluminum, phosphorus, phosphorus trichloride, or organic matter.
Purification Methods
Purify ICl3 by sublimation at room temperature. Irritant vapours. [Booth & Morris Inorg Synth I 167 1939.]
Iodine trichloride Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from Iodine trichloride manufacturers
- Product
- Iodine trichloride 865-44-1
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 25kg
- Release date
- 2019-07-11