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HEXARHODIUM HEXADECACARBONYL

Product Name
HEXARHODIUM HEXADECACARBONYL
CAS No.
28407-51-4
Chemical Name
HEXARHODIUM HEXADECACARBONYL
Synonyms
RHODIUM CARBONYL;rhodium(0) carbonyl;[Rh6(CO)12(μ3-CO)4];rhodium hexacarbonyl;Hexadecacarbonylhexa;Carbon Monoxide rhodiuM;HEXADECACARBONYLHEXARHODIUM;HEXARHODIUM HEXADECACARBONYL;HEXADECACARBONYLHEXARHODIUM (0);hexarhodium(0) hexadecacarbonyl
CBNumber
CB5101874
Molecular Formula
C16O16Rh6
Formula Weight
1065.59
MOL File
28407-51-4.mol
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HEXARHODIUM HEXADECACARBONYL Property

Melting point:
238-242°C
Density 
2,87 g/cm3
solubility 
Very sparingly soluble in chloroform, carbon tetrachloride and dichloromethane
form 
crystal
Specific Gravity
2.87
color 
black
Sensitive 
Air Sensitive
Exposure limits
ACGIH: TWA 1 mg/m3
NIOSH: IDLH 100 mg/m3; TWA 0.1 mg/m3
EPA Substance Registry System
Rhodium, tetra-.mu.3-carbonyldodecacarbonylhexa-, octahedro (28407-51-4)
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Safety

Hazard Codes 
Xn
Risk Statements 
20/21/22
Safety Statements 
36/37
RIDADR 
1325
WGK Germany 
3
F 
10
TSCA 
Yes
HazardClass 
6.1
PackingGroup 
II
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
247650
Product name
Hexarhodium(0) hexadecacarbonyl
Purity
Rh 57-60 % (approx.)
Packaging
1g
Price
$289.2
Updated
2024/03/01
Alfa Aesar
Product number
B24185
Product name
Hexarhodium hexadecacarbonyl, 98%
Packaging
0.1g
Price
$144
Updated
2023/06/20
Alfa Aesar
Product number
B24185
Product name
Hexarhodium hexadecacarbonyl, 98%
Packaging
0.5g
Price
$720
Updated
2023/06/20
Strem Chemicals
Product number
45-0820
Product name
Hexarhodium hexadecacarbonyl, min. 98%
Packaging
250mg
Price
$278
Updated
2024/03/01
Strem Chemicals
Product number
45-0820
Product name
Hexarhodium hexadecacarbonyl, min. 98%
Packaging
1g
Price
$828
Updated
2024/03/01
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HEXARHODIUM HEXADECACARBONYL Chemical Properties,Usage,Production

Chemical Properties

black crystal(s); cluster structure; used as a catalyst [COT88] [ALD94] [ALF95]

Uses

Catalyst for hydrogenation of alkenes, hydroformylations ofalkenes; reducing agent for aldehydes, ketones, and nitro groups; catalyst for carbenoid reactions of diazo compounds

Purification Methods

It slowly loses CO when heated in air, but may be regenerated by heating at 80-200o in the presence of CO at 200atmospheres pressure for 15hours, preferably in the presence of Cu. It forms black crystals which are insoluble in hexane. It has bands at 2073, 2026 and 1800cm-1 in the IR. [Hieber & Lagally Z Anorg Allgem Chem 251 96 1963, Corey & Dahl J Am Chem Soc 85 1202 1963, Doyle et al. Tetrahedron Lett 22 1783 1981.] POISONOUS.

HEXARHODIUM HEXADECACARBONYL Preparation Products And Raw materials

Raw materials

Preparation Products

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HEXARHODIUM HEXADECACARBONYL Suppliers

Belgium 1 China 81 Denmark 1 Germany 4 India 3 Japan 2 Switzerland 2 The Netherlands 1 United Kingdom 5 United States 10 Global 110
J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
96815
Advantage
76
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
021-61259108 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40228
Advantage
62
Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30123
Advantage
84
Hangzhou Yuhao Chemical Technology Co., Ltd
Tel
0571-82693216
Fax
+86-571-82880190
Email
info@yuhaochemical.com
Country
China
ProdList
9387
Advantage
52
Shaanxi Rock New Materials Co., Ltd.
Tel
0917-8888777, 3380777,18691786767; 15619786767
Email
xuya@bjrock.com
Country
China
ProdList
310
Advantage
62
Sigma-Aldrich
Tel
021-61415566 800-8193336
Email
orderCN@merckgroup.com
Country
China
ProdList
51456
Advantage
80
Chengdu RunZeBenTu Chemical Co., Ltd
Tel
028-88469284 18000562381
Email
rzbtsj@163.com
Country
China
ProdList
9951
Advantage
56
Shandong Xiya Chemical Co., Ltd.
Tel
4009903999 13395398332
Fax
0539-6365991
Email
sales@xiyashiji.com
Country
China
ProdList
20806
Advantage
60
Shanghai SuperLan Chemcial Technique Centre
Tel
021-2022843681 15618226720
Fax
+86-21-51601218
Email
lucy@atkchemical.com
Country
China
ProdList
9204
Advantage
58
Zhengzhou Acme Chemical Co., Ltd.
Tel
0371-0371-55629727 13323845623
Fax
037155629727
Email
2885676761@qq.com
Country
China
ProdList
10009
Advantage
58
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View Lastest Price from HEXARHODIUM HEXADECACARBONYL manufacturers

Career Henan Chemical Co
Product
Carbon monooxide - rhodium (8:3) 28407-51-4
Price
US $1.00/g
Min. Order
1g
Purity
Min98%HPLC
Supply Ability
g/kg/ton
Release date
2020-01-09

28407-51-4, HEXARHODIUM HEXADECACARBONYLRelated Search:

YTTRIUM SCANDIUM Platinum dioxide HEXARHODIUM HEXADECACARBONYL Rhodium TETRARHODIUM DODECACARBONYL

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  • HEXARHODIUM(0) HEXADECACARBONYL, 57-60% RH
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  • Hexadecacarbonylhexa
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  • Hexarhodium hexadecacarbonyl, min. 98%
  • Carbon Monoxide rhodiuM
  • Hexarhodium(0) hexadecacarbonyl Rh 57-60 % (approx.)
  • Carbon monooxide - rhodium (8:3)
  • [Rh6(CO)12(μ3-CO)4]
  • HEXARHODIUM HEXADECACARBONYL ISO 9001：2015 REACH
  • Di-μ-chlorobis[2-[(dimethylamino)methy]phenyl-C,N]
  • 28407-51-4
  • Rh6CO16
  • C16O16Rh6
  • 16CORh6
  • Catalysis and Inorganic Chemistry
  • metal carbonyl complexes