HEXARHODIUM HEXADECACARBONYL
- Product Name
- HEXARHODIUM HEXADECACARBONYL
- CAS No.
- 28407-51-4
- Chemical Name
- HEXARHODIUM HEXADECACARBONYL
- Synonyms
- RHODIUM CARBONYL;rhodium(0) carbonyl;[Rh6(CO)12(μ3-CO)4];rhodium hexacarbonyl;Hexadecacarbonylhexa;Carbon Monoxide rhodiuM;HEXADECACARBONYLHEXARHODIUM;HEXARHODIUM HEXADECACARBONYL;HEXADECACARBONYLHEXARHODIUM (0);hexarhodium(0) hexadecacarbonyl
- CBNumber
- CB5101874
- Molecular Formula
- C16O16Rh6
- Formula Weight
- 1065.59
- MOL File
- 28407-51-4.mol
HEXARHODIUM HEXADECACARBONYL Property
- Melting point:
- 238-242°C
- Density
- 2,87 g/cm3
- solubility
- Very sparingly soluble in chloroform, carbon tetrachloride and dichloromethane
- form
- crystal
- Specific Gravity
- 2.87
- color
- black
- Sensitive
- Air Sensitive
- Exposure limits
- ACGIH: TWA 1 mg/m3
NIOSH: IDLH 100 mg/m3; TWA 0.1 mg/m3 - EPA Substance Registry System
- Rhodium, tetra-.mu.3-carbonyldodecacarbonylhexa-, octahedro (28407-51-4)
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
N-Bromosuccinimide Price
- Product number
- 247650
- Product name
- Hexarhodium(0) hexadecacarbonyl
- Purity
- Rh 57-60 % (approx.)
- Packaging
- 1g
- Price
- $289.2
- Updated
- 2024/03/01
- Product number
- B24185
- Product name
- Hexarhodium hexadecacarbonyl, 98%
- Packaging
- 0.1g
- Price
- $144
- Updated
- 2023/06/20
- Product number
- B24185
- Product name
- Hexarhodium hexadecacarbonyl, 98%
- Packaging
- 0.5g
- Price
- $720
- Updated
- 2023/06/20
- Product number
- 45-0820
- Product name
- Hexarhodium hexadecacarbonyl, min. 98%
- Packaging
- 250mg
- Price
- $278
- Updated
- 2024/03/01
- Product number
- 45-0820
- Product name
- Hexarhodium hexadecacarbonyl, min. 98%
- Packaging
- 1g
- Price
- $828
- Updated
- 2024/03/01
HEXARHODIUM HEXADECACARBONYL Chemical Properties,Usage,Production
Chemical Properties
black crystal(s); cluster structure; used as a catalyst [COT88] [ALD94] [ALF95]
Uses
Catalyst for hydrogenation of alkenes, hydroformylations ofalkenes; reducing agent for aldehydes, ketones, and nitro groups; catalyst for carbenoid reactions of diazo compounds
Purification Methods
It slowly loses CO when heated in air, but may be regenerated by heating at 80-200o in the presence of CO at 200atmospheres pressure for 15hours, preferably in the presence of Cu. It forms black crystals which are insoluble in hexane. It has bands at 2073, 2026 and 1800cm-1 in the IR. [Hieber & Lagally Z Anorg Allgem Chem 251 96 1963, Corey & Dahl J Am Chem Soc 85 1202 1963, Doyle et al. Tetrahedron Lett 22 1783 1981.] POISONOUS.
HEXARHODIUM HEXADECACARBONYL Preparation Products And Raw materials
Raw materials
Preparation Products
HEXARHODIUM HEXADECACARBONYL Suppliers
- Tel
- --
- Fax
- --
- ffwk-cservice@fujifilm.com
- Country
- Japan
- ProdList
- 6222
- Advantage
- 58
- Tel
- --
- Fax
- --
- labchem-tec@wako-chem.co.jp
- Country
- Japan
- ProdList
- 6819
- Advantage
- 80
View Lastest Price from HEXARHODIUM HEXADECACARBONYL manufacturers
- Product
- Carbon monooxide - rhodium (8:3) 28407-51-4
- Price
- US $1.00/g
- Min. Order
- 1g
- Purity
- Min98%HPLC
- Supply Ability
- g/kg/ton
- Release date
- 2020-01-09