(S)-(+)-1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate

Reaction

Product Name: (S)-(+)-1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate
CAS No.: 35193-64-7
Chemical Name: (S)-(+)-1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate
Synonyms: (R)-(-)-BNP ACID;(R)-(-)-BPA;(R)-(-)-BNPA;(11bS)-;(S)-(+)-BPA;(S)-(+)-BNPA;(S)-(+)-BNDHP.;(S)-(+)-BNP ACID;(S)-(+)-1,1'-Binapht;Galactose Impurity 11
CBNumber: CB5107331
Molecular Formula: C20H13O4P
Formula Weight: 348.29
MOL File: 35193-64-7.mol

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(S)-(+)-1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate Property

Melting point:: ≥300 °C
alpha: 607.5 º (c=1.4,MeOH)
Boiling point:: 619.5±38.0 °C(Predicted)
Density: 1.49±0.1 g/cm3(Predicted)
refractive index: 595 ° (C=1, MeOH)
storage temp.: Sealed in dry,Room Temperature
solubility: Soluble in DMSO and methanol (hot).
form: Powder
pka: 1.14±0.20(Predicted)
color: white
optical activity: [α]22/D +595°, c = 1.35 in methanol
BRN: 4787775
CAS DataBase Reference: 35193-64-7(CAS DataBase Reference)

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Safety

Hazard Codes: Xi,Xn
Risk Statements: 36/37/38-20/21/22
Safety Statements: 26-36-36/37/39-22
WGK Germany: 3
RTECS: RZ2475100
F: 10-23
HS Code: 29199000

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word: Warning
Hazard statements: H315Causes skin irritation
Precautionary statements: P302+P352IF ON SKIN: wash with plenty of soap and water.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 248940
Product name: (S)-(+)-1,1′-Binaphthyl-2,2′-diyl hydrogenphosphate
Purity: 97%
Packaging: 1g
Price: $114
Updated: 2024/03/01

Sigma-Aldrich

Product number: 248940
Product name: (S)-(+)-1,1′-Binaphthyl-2,2′-diyl hydrogenphosphate
Purity: 97%
Packaging: 5g
Price: $249
Updated: 2024/03/01

TCI Chemical

Product number: B1144
Product name: (S)-(+)-1,1'-Binaphthyl-2,2'-diyl Hydrogen Phosphate
Purity: >97.0%(T)
Packaging: 1g
Price: $59
Updated: 2024/03/01

TCI Chemical

Product number: B1144
Product name: (S)-(+)-1,1'-Binaphthyl-2,2'-diyl Hydrogen Phosphate
Purity: >97.0%(T)
Packaging: 100mg
Price: $16
Updated: 2024/03/01

Alfa Aesar

Product number: L14137
Product name: (S)-(+)-1,1'-Binaphthyl-2,2'-diyl hydrogen phosphate, 98+%
Packaging: 1g
Price: $57.65
Updated: 2024/03/01

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(S)-(+)-1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate Chemical Properties,Usage,Production

Reaction

Asymmetric hetero Diels-Alder reaction catalyzed by chiral lanthanide(III) complex.
Highly efficient Mannich reaction
Acidic Resolving agent for certain amine/racemic mixtures.

Chemical Properties

white to light yellow crystal powde

Uses

The S enantiomer of binaphthol derivative as chiral quenching agent.

Uses

Used as a chiral Bronsted acid catalyst in the enantoselective Mannich reaction.

Purification Methods

Recrystallise it from EtOH. Reflux for 3hours in N NaOH is required to hydrolyse the cyclic phosphate. [Jacques et al. Tetrahedron Lett 4617 1971, Arnold et al. Tetrahedron 24, 343 1983.]

(S)-(+)-1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate Preparation Products And Raw materials

Raw materials

Preparation Products

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(S)-(+)-1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate Suppliers

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Xinxiang Runyu Material Co., Ltd.

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Alfa Aesar

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View Lastest Price from (S)-(+)-1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate manufacturers

Shanghai UCHEM Inc.

Product: (S)-(+)-1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate 35193-64-7
Price: US $65.00-213.00/g
Min. Order: 25g
Purity: 0.98
Supply Ability: 25kg
Release date: 2023-12-13

Shaanxi Dideu Medichem Co. Ltd

Product: (S)-(+)-1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate 35193-64-7
Price: US $1.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 20T
Release date: 2024-08-09

XINXIANG RUNYU MATERIAL CO., LTD.

Product: (S)-(+)-1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate 35193-64-7
Price: US $0.00-0.00/kg
Min. Order: 1kg
Purity: 99
Supply Ability: 500
Release date: 2024-02-07

35193-64-7, (S)-(+)-1,1'-Binaphthyl-2,2'-diyl hydrogenphosphateRelated Search:

(S)-(-)-1,1'-Bi-2-naphthol Clindamycin phosphate 1,1'-Bi-2-naphthol SULPHOSUCCINIC ACID ESTER 1,1'-BINAPHTHYL (+/-)-1,1''-BINAPHTHYL-2,2''-DIYL HYDROGENPHOSPHATE 99%,(+/-)-1,1'-BINAPHTHYL-2,2'-DIYL HYDROGENPHOSPHATE,1,1'-BINAPHTHYL-2,2'-DIYL HYDROGENPHOSPHATE Water treatment agent POE (R)-(-)-1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate (R)-(-)-3,3'-BIS(TRIPHENYLSILYL)-1,1'-BINAPHTHYL-2,2'-DIYL HYDROGENPHOSPHATE, 95% (R)-3,3'-BIS[3,5-BIS(TRIFLUOROMETHYL)PHENYL]-1,1'-BINAPHTHYL-2,2'-DIYL HYDROGENPHOSPHATE (S)-(+)-3,3'-BIS(3,5-BIS(TRIFLUOROMETHYL)PHENYL)-1,1'-BINAPHTHYL-2,2'-DIYL HYDROGENPHOSPHATE, 95% (S)-(+)-1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate

(S)-(+)-BNP ACID

(S)-(+)-BNPA

(S)-(+)-BPA

(S)-4-HYDROXY DINAPHTHO[2,1-D:1',2'-F][1,3,2]-DIOXAPHOPHEPIN-4-OXID

(S)-4-HYDROXYDINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-OXIDE

(S)-(+)-1,1'-BINAPHTHELENE-2,2'-DIYL-PHOSPHATE

(S)-(+)-1,1'-BINAPHTHYL-2,2'-DIYL HYDROGENPHOSPHATE

S-1,1'-BINAPHTHYL-2,2'-DIYL HYDROGENPHOSPHATE

(S)-(-)-1,1'-BINAPHTHALENE-2,2'-DIYL HYDROGEN PHOSPHATE

S(+)-1,1'-BINAPHTHALENE-2,2'-DIYL HYDROGEN PHOSPHATE

S(+)-1,1'-BI-2-NAPHTHYL-2,2'-DIYL HYDROGEN PHOSPHATE

(S)-(+)-2,2'-DIHYDROXY-1,1'-BINAPHTHYL HYDROGENPHOSPHATE

(S)-4-HYDROXYDINAPHTHO[2,1-D:1'',2''-F][1,3,2]DIOXAPHOSPHEPIN-4-OXIDE: (S)-(+)-BNP ACID

(S)-(+)-1,1'-Binaphthyl-2,2'-diyl hydrogen phosphate, 98+%

(11bS)-4-Hydroxydinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin 4-Oxide

(S)-(+)-1,1μ-Binaphthalene-2,2μ-diyl hydrogen phosphate, (S)-4-Hydroxydinaphtho[2,1-d:1μ,2μ-f][1,3,2]dioxaphosphepin-4-oxide

(S)-(+)-1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate, min. 98%

[aS,(+)]-2,2'-Phosphinicobisoxy-1,1'-binaphthalene

(S)-(+)-1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate,99%

(S)-(+)-1,1'-Binapht

(S)-5,5',6,6',7,7',8,8'-Octahydro-1,1'-binaphthyl-2,2'-diyl hydrogen phosphate

(11bS)-

(<i>S</i>)-(+)-1,1'-Binaphthyl-2,2'-diyl hydrogen phosphate

(S)-(+)-Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-ol 4-oxide, (S)-(+)-BNDHP

(11bS)-4-Hydroxydinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine 4-oxide

(S)-(+)-1,1'-Binaphthyl-2,2'-diyl Hydrogen Phosphate,(S)-(-)-BNDHP

(R)-(-)-BPA

(R)-(-)-BNPA

(R)-(-)-BNP ACID

(R)-(-)-1,1'-BINAPHTHALENE-2,2'-DIYL-PHOSPHATE

(R)-(-)-1,1'-BINAPHTHALENE-2,2'-DIYL HYDROGEN PHOSPHATE

R(-)-1,1'-BI-2-NAPHTHYL-2,2'-DIYL HYDROGEN PHOSPHATE

(R)-4-HYDROXYDINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-OXIDE

(R)-4-HYDROXY DINAPHTHO[2,1-D:1',2'-F][1,3,2]-DIOXAPHOSPHEPIN-4-OXID

(R)-(-)-2,2'-DIHYDROXY-1,1'-BINAPHTHYL HYDROGENPHOSPHATE

2-HYDROXY-2LAMBDA5-DINAPHTHO[2,1-D:1,2-F][1,3,2]DIOXAPHOSPHEPIN-2-ONE

(+/-)-2,2'-DIHYDROXY-1,1'-BINAPHTHYL HYDROGENPHOSPHATE

(S)-(+)-BNDHP.

S-(+)BNP ACID / S-(-)-1,1''-BINAPHTHYL-2,2''-DIPHEMYL PHOSPHINE

(S)-(+)-1,1-Binaphthyl-2,2'-dihydrogenphosphate

(S)-(+)-1,1'-binaphthyl-2

(S)-(+)-BINAPHTHYL-2,2'-DIYL HYDROGENPHO SPHATE

S-(+)-1,1Binaphthalene-2,2Dihydrogen Phosphate

(S)-(+)-1,1'-Binaphthyl-2,2'-diylhydrogenephosphate

(S)-(+)-1,1'-BINAPHTHALENE-2,2'-DIYL-PHOSPHATE

(S)-(+)-1,1'-Binaphthyl-2,2'-d

(S)-(+)-1,1'-Binaphthyl-2,2'-diylhydrogenphosphate,min.98%

Dinaphtho2,1-d:1,2-f1,3,2dioxaphosphepin, 4-hydroxy-, 4-oxide, (11bS)-

S)-(+)-1,1'-Binaphthyl-2,2'-diyl

(S)-(+)-1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate 97%

(S)-(+)-1,1'-Biphthyl-2,2'-diyl hydrogenphosphate

(S)-1,1'-Binaphthalene-2,2'-diyl Hydrogen Phosphate,99%e.e.

(S)-(+)-1,1'-Binaphthalene-2,2'-diyl-phosphate for synthesis

Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin, 4-hydroxy-, 4-oxide, (S)-

(11bS)-4-Hydroxy-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin

(S)-(+)-1,1'-BINAPHTHE

(S)-(+)-1,1'-Binaphthyl-2,2'-diyl Hydrogen Phosphate &gt

(+)-1,1'-Binaphthyl-2,2'-diyl hydrogen phosphate