(R)-(-)-3,3'-BIS(TRIPHENYLSILYL)-1,1'-BINAPHTHYL-2,2'-DIYL HYDROGENPHOSPHATE, 95%

Reaction

Product Name: (R)-(-)-3,3'-BIS(TRIPHENYLSILYL)-1,1'-BINAPHTHYL-2,2'-DIYL HYDROGENPHOSPHATE, 95%
CAS No.: 791616-55-2
Chemical Name: (R)-(-)-3,3'-BIS(TRIPHENYLSILYL)-1,1'-BINAPHTHYL-2,2'-DIYL HYDROGENPHOSPHATE, 95%
Synonyms: )-3，3′(R)-(–-binaphthyl-2，2′-diyl hydrogenphosphate;Carreira SALDIPAC Ligand;-Bis(triphenylsilyl)-1，1′(S)-3,3μ-Bis(triphenylsilyl)-1,1μ-binaphthyl-2,2μ-diyl hydrogenphosphate;(R)-(-)-3,3'Bis(triphenylsilyl)-1,1'binaphthyl-2,2'diyl hydrogenphosphaste;(R)-(-)-3,3'-BIS(TRIPHENYLSILYL)-1,1'-BINAPHTHYL-2,2'-DIYLHYDROGENPHOSPHATE,95%;(R)-(-)-3,3'-Bis(triphenylsilyl)-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate 96%
CBNumber: CB7972898
Molecular Formula: C56H41O4PSi2
Formula Weight: 865.07
MOL File: 791616-55-2.mol

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(R)-(-)-3,3'-BIS(TRIPHENYLSILYL)-1,1'-BINAPHTHYL-2,2'-DIYL HYDROGENPHOSPHATE, 95% Property

Melting point:: 329-335 °C
alpha: -197° (c=1, CHCl3)
Density: 1.32±0.1 g/cm3(Predicted)
storage temp.: Sealed in dry,Room Temperature
form: Powder
pka: 1.17±0.20(Predicted)
color: white to light-yellow
optical activity: [α]22/D -197°, c = 1 in chloroform

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Safety

Hazard Codes: Xi
Risk Statements: 36/37/38
Safety Statements: 26-36/37
WGK Germany: 3
HS Code: 29319090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 674745
Product name: (R)-(–)-3,3′-Bis(triphenylsilyl)-1,1′-binaphthyl-2,2′-diyl hydrogenphosphate
Purity: 95%
Packaging: 100mg
Price: $256.8
Updated: 2024/03/01

Strem Chemicals

Product number: 15-0340
Product name: (R)-(-)-3,3'-Bis(triphenylsilyl)-1,1'-binaphthyl-2,2'-diyl hydrogen phosphate, min. 98% [(R)-TiPSY]
Packaging: 10mg
Price: $65
Updated: 2024/03/01

Strem Chemicals

Product number: 15-0340
Product name: (R)-(-)-3,3'-Bis(triphenylsilyl)-1,1'-binaphthyl-2,2'-diyl hydrogen phosphate, min. 98% [(R)-TiPSY]
Packaging: 100mg
Price: $493
Updated: 2024/03/01

Biosynth Carbosynth

Product number: FB158782
Product name: (R)-(-)-3,3′-Bis(triphenylsilyl)-1,1′-binaphthyl-2,2′-diyl hydrogenphosphate
Packaging: 100mg
Price: $500
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FB158782
Product name: (R)-(-)-3,3′-Bis(triphenylsilyl)-1,1′-binaphthyl-2,2′-diyl hydrogenphosphate
Packaging: 10mg
Price: $100
Updated: 2021/12/16

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(R)-(-)-3,3'-BIS(TRIPHENYLSILYL)-1,1'-BINAPHTHYL-2,2'-DIYL HYDROGENPHOSPHATE, 95% Chemical Properties,Usage,Production

Reaction

A chiral phosphoric acid catalyst providing a convenient strategy for the enantioselective construction of protected primary amines and a highly stereoselective method for the reductive amination of heterocyclic amines.
Chiral phosphoric acid used for the enantioselective Biginelli and Biginelli-like reactions.
Chiral phosphoric acid organocatalyst used in the asymmetric, three-component Povarov reaction involving 2-hydroxystyrenes. An efficient method to access structurally diverse cis-disubstituted tetrahydroquinolines in high stereoselectivities of up to >99:1 dr and 97% ee.
A gold/chiral phosphoric acid catalyst used for the highly stereoselective, three-component reaction of salicylaldehydes, anilines, and alkynols to give aromatic spiroacetals in high yields and stereoselectivities.
The first highly enantioselective catalytic protocol for the reductive coupling of ketones and hydrozones.
Reagent-controlled regioselectivity enabled by dual activation.

Chemical Properties

Solid

Uses

Organocatalyst for the first enatioselective organocatalytic reductive amination reaction.

(R)-(-)-3,3'-BIS(TRIPHENYLSILYL)-1,1'-BINAPHTHYL-2,2'-DIYL HYDROGENPHOSPHATE, 95% Preparation Products And Raw materials

Raw materials

Preparation Products

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(R)-(-)-3,3'-BIS(TRIPHENYLSILYL)-1,1'-BINAPHTHYL-2,2'-DIYL HYDROGENPHOSPHATE, 95% Suppliers

China 47 Switzerland 1 United Kingdom 1 United States 4 Global 53

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Sigma-Aldrich

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View Lastest Price from (R)-(-)-3,3'-BIS(TRIPHENYLSILYL)-1,1'-BINAPHTHYL-2,2'-DIYL HYDROGENPHOSPHATE, 95% manufacturers

Zhuozhou Wenxi import and Export Co., Ltd

Product: (R)-(–)-3,3′-Bis(triphenylsilyl)-1,1′-binaphthyl-2,2′-diyl hydrogenphosphate 791616-55-2
Price: US $15.00-10.00/KG
Min. Order: 1KG
Purity: 99%+ HPLC
Supply Ability: Monthly supply of 1 ton
Release date: 2021-06-27

791616-55-2, (R)-(-)-3,3'-BIS(TRIPHENYLSILYL)-1,1'-BINAPHTHYL-2,2'-DIYL HYDROGENPHOSPHATE, 95%Related Search:

(11bR)-2,6-Di-9-anthracenyl-4-hydroxy-dinaphtho[2,1-d:1μ,2μ-f][1,3,2]dioxaphosphepin-4-oxide R-4-oxide-4-hydroxy-2,6-bis(4-nitrophenyl)- Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin (11bR)-2,6-Di-1-pyrenyl-4-hydroxy-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin R-4-oxide-4-hydroxy-2,6-di-1-naphthalenyl-Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin (R)-3,3'-BIS(3,5-BIS(TRIFLUOROMETHYL)PH& R-3,3'-Bis(phenyl)-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate (11bR)-4-Hydroxy-2,6-bis[2,3,4,5,6-pentafluorophenyl]-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin R-4-oxide-4-hydroxy-2,6-di-2-naphthalenyl-Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin R- 4-oxide-2,6-bis([1,1'-biphenyl]-4-yl)-4-hydroxy-Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin (11bR)-2,6-Di-9-phenanthrenyl-4-hydroxy-dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-oxide 1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate Tetraphenylsilane (R)-(+)-1,1'-Bi-2-naphthol Triphenylsilane (R)-3,3'-BIS(TRIPHENYLSILYL)-1,1'-BI-2-& 2,2'-BIPHENYLDIOL, CYCLIC PHOSPHATE (R)-(-)-3,3'-BIS(TRIPHENYLSILYL)-1,1'-BINAPHTHYL-2,2'-DIYL HYDROGENPHOSPHATE, 95% o-(Trimethylsilyl)phenol

(R)-(-)-3,3'-BIS(TRIPHENYLSILYL)-1,1'-BINAPHTHYL-2,2'-DIYL HYDROGENPHOSPHATE, 95%

MacMillan TiPSY catalyst, (11bR)-4-Hydroxy-2,6-bis(triphenylsilyl)dinaphtho-[2,1-d:1μ,2μf]-1,3,2-dioxaphosphepin 4-oxide

(S)-3,3μ-Bis(triphenylsilyl)-1,1μ-binaphthyl-2,2μ-diyl hydrogenphosphate

MacMillan TiPSY catalyst, (11bS)-4-Hydroxy-2,6-bis(triphenylsilyl)dinaphtho-[2,1-d1μ,2μf]-[1,3,2]-dioxaphosphepin 4-oxide

(R)-(-)-3,3'Bis(triphenylsilyl)-1,1'binaphthyl-2,2'diyl hydrogenphosphaste

(R)-(-)-3,3'-BIS(TRIPHENYLSILYL)-1,1'-BINAPHTHYL-2,2'-DIYLHYDROGENPHOSPHATE,95%

(R)-(-)-3,3'-Bis(triphenylsilyl)-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate 96%

Carreira SALDIPAC Ligand

2,6-bis(triphenylsilyl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-ol 4-oxide

(11bS)-4-hydroxy-2,6-bis(triphenylsilyl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine 4-oxide

(R)-(-)-3,3'-BIS(TRIPHENYLSILYL)-1,1'-BINAPHTHYL-2,2'-DIYLHYDROGENPHOSPHATE,MIN.98%[(R)-TIPSY]

(11bR)-4-Hydroxy-2,6-bis(triphenylsilyl)-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin

(11bR)-2,6-Bis(triphenylsilyl)-4-hydroxy-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin

(R)-3,3'-Bis(triphenylsilyl)-1,1'-binaphthyl-2,2'-diyl Hydrogen Phosphate,99%e.e.

Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin, 4-hydroxy-2,6-bis(triphenylsilyl)-, 4-oxide, (11bR)-

(11bR)-4-Hydroxy-2,6-bis(triphenylsilyl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine 4-oxide

4-hydroxy-2,6-bis(triphenylsilyl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine 4-oxide

(R)-(&#x2013

)-3，3&#8242

-binaphthyl-2，2&#8242

-Bis(triphenylsilyl)-1，1&#8242

-diyl hydrogenphosphate

(R)-(-)-3,3'-BIS(TRIPHENYLSILYL)-1,1'-BINAPHTHYL-2,2'-DIYL HYDROGENPHOSPHATE, 95%

(R)-(-)-3,3''-Bis(triphenylsilyl)-1,1''-binaphthyl-2,2''-diyl hydrogen phosphate

(11bR)-4-Hydroxy-2,6-bis(triphenylsilyl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine 4-oxide

791616-55-2

C56H41O4PSi2