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ChemicalBook > CAS DataBase List > R-4-oxide-4-hydroxy-2,6-bis(4-nitrophenyl)- Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin

R-4-oxide-4-hydroxy-2,6-bis(4-nitrophenyl)- Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin

Application
Product Name
R-4-oxide-4-hydroxy-2,6-bis(4-nitrophenyl)- Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin
CAS No.
695162-89-1
Chemical Name
R-4-oxide-4-hydroxy-2,6-bis(4-nitrophenyl)- Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin
Synonyms
SF110017;R-4-oxide-4-hydroxy-2,6-bis(4-nitrophenyl)- Dinaphtho[2,1-d;R-3,3'-Bis(4-nitrophenyl)-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate;(R)-3,3'-Bis(4-nitrophenyl)-1,1'-binapthyl-2,2'-diyl hydrogenphosphate;R-4-oxide-4-hydroxy-2,6-bis(4-nitrophenyl)- Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin;(11bR)-4-Hydroxy-2,6-bis(4-nitrophenyl)-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin;(11bR)-4-hydroxy-2,6-bis(4-nitrophenyl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine 4-oxide;(11bR)-4-Hydroxy-2,6-bis(4-nitrophenyl)-4-oxidedinaphtho[ 2,1-d:1',2'-f][1,3,2]dioxaphosphepin;(11bR)-4-hydroxy-2,6-bis(4-nitrophenyl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine 4-oxide;Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin, 4-hydroxy-2,6-bis(4-nitrophenyl)-, 4-oxide, (11bR)-
CBNumber
CB82614278
Molecular Formula
C32H19N2O8P
Formula Weight
590.48
MOL File
695162-89-1.mol
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R-4-oxide-4-hydroxy-2,6-bis(4-nitrophenyl)- Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin Property

Melting point:
223.5-249.0 °C (decomp)
Boiling point:
856.0±75.0 °C(Predicted)
Density 
1.59±0.1 g/cm3(Predicted)
storage temp. 
2-8°C, protect from light, stored under nitrogen
form 
solid
pka
1.08±0.20(Predicted)
color 
Yellow
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Safety

HS Code 
2809200000
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

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N-Bromosuccinimide Price

Strem Chemicals
Product number
15-0344
Product name
(11bR)-4-Hydroxy-2,6-bis(4-nitrophenyl)-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin, 98%, (99% ee)
Purity
(99% ee)
Packaging
50mg
Price
$137
Updated
2024/03/01
SynQuest Laboratories
Product number
8675-1-05
Product name
(R)-3,3'-Bis(4-nitrophenyl)-1,1'-binapthyl-2,2'-diyl hydrogenphosphate
Packaging
250mg
Price
$592
Updated
2021/12/16
Ambeed
Product number
A968560
Product name
(11bR)-4-hydroxy-2,6-bis(4-nitrophenyl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine4-oxide
Purity
98%99%ee
Packaging
1g
Price
$595
Updated
2021/12/16
Ambeed
Product number
A968560
Product name
(11bR)-4-hydroxy-2,6-bis(4-nitrophenyl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine4-oxide
Purity
98%99%ee
Packaging
250mg
Price
$180
Updated
2021/12/16
Ambeed
Product number
A968560
Product name
(11bR)-4-hydroxy-2,6-bis(4-nitrophenyl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine4-oxide
Purity
98%99%ee
Packaging
100mg
Price
$105
Updated
2021/12/16
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R-4-oxide-4-hydroxy-2,6-bis(4-nitrophenyl)- Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin Chemical Properties,Usage,Production

Application

(R)-3,3'-bis(4-nitrophenyl)-1,1'-binaphthol phosphate is a chiral binaphthol-phosphate derivative that can be used as a catalyst for asymmetric synthesis reactions such as asymmetric Mannich-type reactions, asymmetric hydrogenation phosphorylation reactions, and asymmetric azir-Dies-Adel reactions.

Synthesis

1. An (R)-binaphthyl boronic acid derivative undergoes Suzuki coupling with 1-bromo-4-nitrobenzene. Subsequent demethylation with BBr yields (R)-3,3'-bis(4-nitrophenyl)-1,1'-binaphthol (a BINOL derivative).
2. This binaphthol reacts with POCI in pyridine, followed by hydrolysis, to give the target phosphate ester compound.

R-4-oxide-4-hydroxy-2,6-bis(4-nitrophenyl)- Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin Preparation Products And Raw materials

Raw materials

Preparation Products

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R-4-oxide-4-hydroxy-2,6-bis(4-nitrophenyl)- Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin Suppliers

China 26 United Kingdom 1 United States 3 Global 30
Daicel Chiral Technologies (China)CO.,LTD
Tel
021-50460086-9 15921403865
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+86-21-50462321
Email
han_yajun@dctc.daicel.com
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China
ProdList
7440
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65
Tianjin Derchemist Science & Technology Co., Ltd.
Tel
22-58627059 13920586291
Fax
022-58620305
Email
zdcomcon@126.com
Country
China
ProdList
4015
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50
Shanghai Chiral bio-compound co., Ltd.
Tel
021-5068 3667/17749785980/1029026415; 17749785980
Fax
021-50683667
Email
1029026415@qq.com
Country
China
ProdList
4359
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58
LaaJoo
Tel
021-60702684 18516024827
Email
huang.jiayi@sinocompound.com
Country
China
ProdList
2280
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58
Greenherbs Science and Technology Development Co., Ltd.
Tel
010-61136123
Fax
+86 (10) 8857-9127
Email
pub02@greenherbs.com.cn
Country
China
ProdList
4049
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58
Shanghai Anyinuo Biomedical Technology Co., Ltd.
Tel
021-34625901 18018851262;
Email
420970979@qq.com
Country
China
ProdList
5919
Advantage
58
Shanghai Suifu Chemical Technology CO.,LTD.
Tel
33738187 19945655289
Email
suifuchemical@163.com
Country
China
ProdList
500
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58
Zhengzhou Acme Chemical Co., Ltd.
Tel
0371-63315541 13323832564
Fax
QQ:3001332135
Email
3001332135@qq.com
Country
China
ProdList
9945
Advantage
58
Shanghai Jizhi Biochemical Technology Co. Ltd.
Tel
021-4009004166/18616739031 18616739031
Email
3007523370@qq.com
Country
China
ProdList
52678
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58
Jiangsu aikang biomedical research and development co., LTD
Tel
025-58859352 17714375163
Email
qzhang@aikonchem.com
Country
China
ProdList
15525
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58

695162-89-1, R-4-oxide-4-hydroxy-2,6-bis(4-nitrophenyl)- Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepinRelated Search:

(R)-3,3'-BIS(3,5-BIS(TRIFLUOROMETHYL)PH& (R)-3,3'-BIS(TRIPHENYLSILYL)-1,1'-BI-2-& (S)-5,5',6,6',7,7',8,8'-Octahydro-1,1'-bi-2-naphthyl phosphate (R)-3,3'-BIS(3,5-BIS(TRIFLUOROMETHYL)PH& (S)-3,3'-DI(ANTHRACEN-9-YL)-1,1'-BINAPHTHYL-2,2'-DIOL R-3,3'-bis[4-(2-naphthalenyl)phenyl]-1,1'-Binaphthalene]-2,2'-diol R-3,3'-bis((3,5-bis(trifluoroMethyl)phenyl)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate R-5,5',6,6',7,7',8,8'-octahydro-3,3'-diphenyl-[1,1'-Binaphthalene]-2,2'-diol R-4-oxide-4-hydroxy-2,6-di-1-naphthalenyl-Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin (11bS)-4-Hydroxy-2,6-bis(4-methoxyphenyl)-4-oxidedinaphtho[ 2,1-d:1',2'-f][1,3,2]dioxaphosphepin S-4-oxide-4-hydroxy-2,6-bis[4-(trifluoroMethyl)phenyl]-Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin (S)-3,3'-Bis(3,5-diphenyl)phenyl-1,1'-binaphthyl-2,2'-diyl Hydrogen Phosphate R-4-oxide-4-hydroxy-2,6-bis(4-Methoxyphenyl)-Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin R-4-oxide-4-hydroxy-2,6-bis[4-(trifluoroMethyl)phenyl]-Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin R- 4-oxide-4-hydroxy-2,6-bis([1,1':3',1''-terphenyl]-5'-yl)-Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin R-3,3'-Bis(phenyl)-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate (11bR)-4-Hydroxy-2,6-bis[2,3,4,5,6-pentafluorophenyl]-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin R-4-oxide-4-hydroxy-2,6-di-2-naphthalenyl-Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin

  • R-4-oxide-4-hydroxy-2,6-bis(4-nitrophenyl)- Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin
  • (R)-3,3'-Bis(4-nitrophenyl)-1,1'-binapthyl-2,2'-diyl hydrogenphosphate
  • R-3,3'-Bis(4-nitrophenyl)-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate
  • (11bR)-4-Hydroxy-2,6-bis(4-nitrophenyl)-4-oxidedinaphtho[ 2,1-d:1',2'-f][1,3,2]dioxaphosphepin
  • (11bR)-4-Hydroxy-2,6-bis(4-nitrophenyl)-4-oxidedinaphtho[ 2,1-d:1',2'-f][1,3,2]dioxaphosphepin,98%e.e.
  • R-4-oxide-4-hydroxy-2,6-bis(4-nitrophenyl)- Dinaphtho[2,1-d
  • Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin, 4-hydroxy-2,6-bis(4-nitrophenyl)-, 4-oxide, (11bR)-
  • (11bR)-4-Hydroxy-2,6-bis(4-nitrophenyl)-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin, 98%, (99% ee)
  • SF110017
  • (11bR)-4-hydroxy-2,6-bis(4-nitrophenyl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine 4-oxide
  • (11bR)-4-Hydroxy-2,6-bis(4-nitrophenyl)-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin
  • (11bR)-4-hydroxy-2,6-bis(4-nitrophenyl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine 4-oxide
  • 695162-89-1
  • C32H19N2O8P