ChemicalBook > CAS DataBase List > (R)-3,3'-BIS(3,5-BIS(TRIFLUOROMETHYL)PH&

(R)-3,3'-BIS(3,5-BIS(TRIFLUOROMETHYL)PH&

Product Name
(R)-3,3'-BIS(3,5-BIS(TRIFLUOROMETHYL)PH&
CAS No.
756491-54-0
Chemical Name
(R)-3,3'-BIS(3,5-BIS(TRIFLUOROMETHYL)PH&
Synonyms
SF120021;(R)-CF3-BINOL;(R)-3,3'-BIS(3,5-BIS(TRIFLUOROMETHYL)PH&;(R)-3,3'-BIS(3,5-BIS(TRIFLUOROMETHYL)PH&;r-3-3'-bis(3,5-bis(trifluoromethyl)phenyl)-1,1'-bi-2-naphthol;(R)-3,3'-Bis(3,5-bis(trifluoromethyl)phenyl)-1,1'-bi-2-napthol;(R)-3,3'- bis [3,5- bis (trifluoromethyl) phenyl ]-1,1'- binaphthol;(R)-3,3'- bis [3,5- bis (trifluoromethyl) phenyl ]-1,1'- binaphthol;(R)-(+)-3,3'-Bis(3,5-bis(trifluoromethyl)phenyl)-1,1'-bi-2,2'-naphtho;(R)-(+)-3,3'-Bis(3,5-bis(trifluoromethyl)phenyl)-1,1'-bi-2,2'-naphthol
CBNumber
CB4972721
Molecular Formula
C36H18F12O2
Formula Weight
710.51
MOL File
756491-54-0.mol
More
Less

(R)-3,3'-BIS(3,5-BIS(TRIFLUOROMETHYL)PH& Property

Melting point:
216-220 °C
Boiling point:
574.7±50.0 °C(Predicted)
Density 
1.466±0.06 g/cm3(Predicted)
storage temp. 
2-8°C
form 
solid
pka
7.62±0.50(Predicted)
color 
White to yellow
optical activity
[α]22/D 45°, c = 1 in chloroform
More
Less

Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26
WGK Germany 
3
HS Code 
29081990
More
Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

More
Less

N-Bromosuccinimide Price

Sigma-Aldrich
Product number
674591
Product name
(R)-(+)-3,3′-Bis(3,5-bis(trifluoromethyl)phenyl)-1,1′-bi-2-naphthol
Purity
95%
Packaging
100mg
Price
$96.8
Updated
2024/03/01
ChemScene
Product number
CS-0086114
Product name
(R)-CF3-BINOL
Purity
>97.0%
Packaging
250mg
Price
$153
Updated
2021/12/16
ChemScene
Product number
CS-0086114
Product name
(R)-CF3-BINOL
Purity
>97.0%
Packaging
100mg
Price
$78
Updated
2021/12/16
Apolloscientific
Product number
PC440000
Product name
(R)-3,3'-Bis(3,5-bis(trifluoromethyl)phenyl)-1,1'-bi-2-napthol
Packaging
250mg
Price
$414
Updated
2021/12/16
SynQuest Laboratories
Product number
2804-3-R0
Product name
(R)-3,3'-Bis(3,5-bis(trifluoromethyl)phenyl)-1,1'-bi-2-napthol
Packaging
250mg
Price
$456
Updated
2021/12/16
More
Less

(R)-3,3'-BIS(3,5-BIS(TRIFLUOROMETHYL)PH& Chemical Properties,Usage,Production

Chemical Properties

Colorless solid

Uses

Precursor to a chiral Bronsted acid (680184) used to catalyze an enantioselective aza Diels-Alder reaction providing bicyclic lactams. Rare earth metal complexes of this chiral binapthol catalyze an intramolecular hydroamination of amino olefins leading to chiral pyrrolidines.

(R)-3,3'-BIS(3,5-BIS(TRIFLUOROMETHYL)PH& Preparation Products And Raw materials

Raw materials

Preparation Products

More
Less

(R)-3,3'-BIS(3,5-BIS(TRIFLUOROMETHYL)PH& Suppliers

China 31 Switzerland 1 United Kingdom 1 United States 5 Global 38
J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
96815
Advantage
76
Daicel Chiral Technologies (China)CO.,LTD
Tel
021-50460086-9 15921403865
Fax
+86-21-50462321
Email
han_yajun@dctc.daicel.com
Country
China
ProdList
6943
Advantage
65
Tianjin Derchemist Science & Technology Co., Ltd.
Tel
22-58627059 13920586291
Fax
022-58620305
Email
zdcomcon@126.com
Country
China
ProdList
3021
Advantage
50
Bide Pharmatech Ltd.
Tel
400-1647117 15221909166
Fax
+86-21-61629029
Email
product02@bidepharm.com
Country
China
ProdList
41438
Advantage
60
Sigma-Aldrich
Tel
021-61415566 800-8193336
Email
orderCN@merckgroup.com
Country
China
ProdList
51471
Advantage
80
Shanghai Chiral bio-compound co., Ltd.
Tel
021-5068 3667/17749785980/1029026415; 17749785980
Fax
021-50683667
Email
1029026415@qq.com
Country
China
ProdList
2884
Advantage
58
LaaJoo
Tel
021-60702684 18516024827
Email
huang.jiayi@sinocompound.com
Country
China
ProdList
2654
Advantage
58
Greenherbs Science and Technology Development Co., Ltd.
Tel
010-61136123
Fax
+86 (10) 8857-9127
Email
pub02@greenherbs.com.cn
Country
China
ProdList
4049
Advantage
58
Aikon International Limited
Tel
025-66113011 18112977050
Fax
(5)02557626880
Email
cb6@aikonchem.com
Country
China
ProdList
15495
Advantage
58
Rhawn Reagent
Tel
400-400-1332688 18019345275
Fax
400-133-2688
Email
amy@rhawn.cn
Country
China
ProdList
15503
Advantage
58

756491-54-0, (R)-3,3'-BIS(3,5-BIS(TRIFLUOROMETHYL)PH&Related Search:

(R)-(+)-3,3'-DIBROMO-5,5',6,6',7,7',8,8'-OCTAHYDRO(1,1'BINAPHTHALENE)-2,2'-DIOL R-3,3'-Bis(triphenylsilyl)-5,5',6,6',7,7',8,8'-Octahydro-1,1'-bi-2-naphthyl phosphate R-3,3'-bis(4-nitrophenyl)-1,1'-Binaphthalene]-2,2'-diol R-4-oxide-4-hydroxy-2,6-bis(4-nitrophenyl)- Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin R- 4-oxide--hydroxy-2,6-bis[4-(2-naphthalenyl)phenyl]-Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin (R)-3,3'-BIS(TRIPHENYLSILYL)-1,1'-BI-2-& (S)-5,5',6,6',7,7',8,8'-Octahydro-1,1'-bi-2-naphthyl phosphate (R)-3,3'-BIS(3,5-BIS(TRIFLUOROMETHYL)PH& (S)-3,3'-DI(ANTHRACEN-9-YL)-1,1'-BINAPHTHYL-2,2'-DIOL R-3,3'-bis[4-(2-naphthalenyl)phenyl]-1,1'-Binaphthalene]-2,2'-diol R-3,3'-bis((3,5-bis(trifluoroMethyl)phenyl)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate R-5,5',6,6',7,7',8,8'-octahydro-3,3'-diphenyl-[1,1'-Binaphthalene]-2,2'-diol 2,6-Diphenylphenol (R)-(+)-1,1'-Bi-2-naphthol (R)-3,3'-DIMETHYL-1,1'-BINAPHTHALENE-2,2'-DIOL 3,3'-DIPHENYLBIPHENYL (S)-(+)-3,3'-BIS(3,5-BIS(TRIFLUOROMETHYL)PHENYL)-1,1'-BINAPHTHYL-2,2'-DIYL HYDROGENPHOSPHATE, 95% (R)-3,3'-BIS(3,5-BIS(TRIFLUOROMETHYL)PH&

  • (R)-3,3'-BIS(3,5-BIS(TRIFLUOROMETHYL)PH&
  • (R)-(+)-3,3'-Bis(3,5-bis(trifluoromethyl)phenyl)-1,1'-bi-2,2'-naphthol
  • (R)-(+)-3,3'-Bis(3,5-bis(trifluoromethyl)phenyl)-1,1'-bi-2-naphthol 95%
  • (R)-3,3'-Bis(3,5-bis(trifluoromethyl)phenyl)-1,1'-bi-2-napthol
  • (R)-(+)-3,3'-Bis(3,5-bis(trifluoromethyl)phenyl)-1,1'-bi-2,2'-naphtho
  • (R)-3,3'-Bis[3,5-bis(trifluoromethyl)phenyl]-1,1'-bi-2- naphthol, 98%e.e.
  • SF120021
  • [1,1'-Binaphthalene]-2,2'-diol, 3,3'-bis[3,5-bis(trifluoromethyl)phenyl]-, (1R)-
  • (R)-3,3'-Bis(3,5-bis(trifluoromethyl)phenyl)-[1,1'-binaphthalene]-2,2'-diol
  • (R)-CF3-BINOL
  • (R)-3,3'- bis [3,5- bis (trifluoromethyl) phenyl ]-1,1'- binaphthol
  • (R)-3,3'-BIS(3,5-BIS(TRIFLUOROMETHYL)PH&
  • r-3-3'-bis(3,5-bis(trifluoromethyl)phenyl)-1,1'-bi-2-naphthol
  • (R)-3,3'-Bis(3,5-bis(trifluoromethyl)phenyl)-[1,1'-binaphthalene]-2,2'-diol
  • (R)-3,3'- bis [3,5- bis (trifluoromethyl) phenyl ]-1,1'- binaphthol
  • 756491-54-0
  • BINOLs
  • Chiral Catalysts, Ligands, and Reagents
  • Privileged Ligands and Complexes