ChemicalBook > CAS DataBase List > (R)-3,3'-BIS(3,5-BIS(TRIFLUOROMETHYL)PH&

(R)-3,3'-BIS(3,5-BIS(TRIFLUOROMETHYL)PH&

Product Name
(R)-3,3'-BIS(3,5-BIS(TRIFLUOROMETHYL)PH&
CAS No.
756491-54-0
Chemical Name
(R)-3,3'-BIS(3,5-BIS(TRIFLUOROMETHYL)PH&
Synonyms
SF120021;(R)-CF3-BINOL;(R)-3,3'-BIS(3,5-BIS(TRIFLUOROMETHYL)PH&;(R)-3,3'-BIS(3,5-BIS(TRIFLUOROMETHYL)PH&;r-3-3'-bis(3,5-bis(trifluoromethyl)phenyl)-1,1'-bi-2-naphthol;(R)-3,3'-Bis(3,5-bis(trifluoromethyl)phenyl)-1,1'-bi-2-napthol;(R)-3,3'- bis [3,5- bis (trifluoromethyl) phenyl ]-1,1'- binaphthol;(R)-3,3'- bis [3,5- bis (trifluoromethyl) phenyl ]-1,1'- binaphthol;(R)-(+)-3,3'-Bis(3,5-bis(trifluoromethyl)phenyl)-1,1'-bi-2,2'-naphtho;(R)-(+)-3,3'-Bis(3,5-bis(trifluoromethyl)phenyl)-1,1'-bi-2,2'-naphthol
CBNumber
CB4972721
Molecular Formula
C36H18F12O2
Formula Weight
710.51
MOL File
756491-54-0.mol
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(R)-3,3'-BIS(3,5-BIS(TRIFLUOROMETHYL)PH& Property

Melting point:
216-220 °C
Boiling point:
574.7±50.0 °C(Predicted)
Density 
1.466±0.06 g/cm3(Predicted)
storage temp. 
2-8°C
form 
solid
pka
7.62±0.50(Predicted)
color 
White to yellow
optical activity
[α]22/D 45°, c = 1 in chloroform
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26
WGK Germany 
3
HS Code 
29081990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
674591
Product name
(R)-(+)-3,3′-Bis(3,5-bis(trifluoromethyl)phenyl)-1,1′-bi-2-naphthol
Purity
95%
Packaging
100mg
Price
$96.8
Updated
2024/03/01
ChemScene
Product number
CS-0086114
Product name
(R)-CF3-BINOL
Purity
>97.0%
Packaging
100mg
Price
$78
Updated
2021/12/16
ChemScene
Product number
CS-0086114
Product name
(R)-CF3-BINOL
Purity
>97.0%
Packaging
250mg
Price
$153
Updated
2021/12/16
AK Scientific
Product number
X3444
Product name
(R)-(+)-3,3'-Bis(3,5-bis(trifluoromethyl)phenyl)-1,1'-bi-2,2'-naphthol
Packaging
100mg
Price
$221
Updated
2021/12/16
Matrix Scientific
Product number
118675
Product name
(R)-3,3'-Bis(3,5-bis(trifluoromethyl)-phenyl)-1,1'-bi-2-napthol
Purity
99.1%
Packaging
250mg
Price
$376
Updated
2021/12/16
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(R)-3,3'-BIS(3,5-BIS(TRIFLUOROMETHYL)PH& Chemical Properties,Usage,Production

Chemical Properties

Colorless solid

Uses

Precursor to a chiral Bronsted acid (680184) used to catalyze an enantioselective aza Diels-Alder reaction providing bicyclic lactams. Rare earth metal complexes of this chiral binapthol catalyze an intramolecular hydroamination of amino olefins leading to chiral pyrrolidines.

(R)-3,3'-BIS(3,5-BIS(TRIFLUOROMETHYL)PH& Preparation Products And Raw materials

Raw materials

Preparation Products

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(R)-3,3'-BIS(3,5-BIS(TRIFLUOROMETHYL)PH& Suppliers

China 31 Switzerland 1 United Kingdom 1 United States 5 Global 38
SIGMA-RBI
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Country
Switzerland
ProdList
6896
Advantage
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756491-54-0, (R)-3,3'-BIS(3,5-BIS(TRIFLUOROMETHYL)PH&Related Search:

(R)-(+)-3,3'-DIBROMO-5,5',6,6',7,7',8,8'-OCTAHYDRO(1,1'BINAPHTHALENE)-2,2'-DIOL R-3,3'-Bis(triphenylsilyl)-5,5',6,6',7,7',8,8'-Octahydro-1,1'-bi-2-naphthyl phosphate R-3,3'-bis(4-nitrophenyl)-1,1'-Binaphthalene]-2,2'-diol R-4-oxide-4-hydroxy-2,6-bis(4-nitrophenyl)- Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin R- 4-oxide--hydroxy-2,6-bis[4-(2-naphthalenyl)phenyl]-Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin (R)-3,3'-BIS(TRIPHENYLSILYL)-1,1'-BI-2-& (S)-5,5',6,6',7,7',8,8'-Octahydro-1,1'-bi-2-naphthyl phosphate (R)-3,3'-BIS(3,5-BIS(TRIFLUOROMETHYL)PH& (S)-3,3'-DI(ANTHRACEN-9-YL)-1,1'-BINAPHTHYL-2,2'-DIOL R-3,3'-bis[4-(2-naphthalenyl)phenyl]-1,1'-Binaphthalene]-2,2'-diol R-3,3'-bis((3,5-bis(trifluoroMethyl)phenyl)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate R-5,5',6,6',7,7',8,8'-octahydro-3,3'-diphenyl-[1,1'-Binaphthalene]-2,2'-diol 2,6-Diphenylphenol (R)-(+)-1,1'-Bi-2-naphthol (R)-3,3'-DIMETHYL-1,1'-BINAPHTHALENE-2,2'-DIOL 3,3'-DIPHENYLBIPHENYL (S)-(+)-3,3'-BIS(3,5-BIS(TRIFLUOROMETHYL)PHENYL)-1,1'-BINAPHTHYL-2,2'-DIYL HYDROGENPHOSPHATE, 95% (R)-3,3'-BIS(3,5-BIS(TRIFLUOROMETHYL)PH&

  • (R)-3,3'-BIS(3,5-BIS(TRIFLUOROMETHYL)PH&
  • (R)-(+)-3,3'-Bis(3,5-bis(trifluoromethyl)phenyl)-1,1'-bi-2,2'-naphthol
  • (R)-(+)-3,3'-Bis(3,5-bis(trifluoromethyl)phenyl)-1,1'-bi-2-naphthol 95%
  • (R)-3,3'-Bis(3,5-bis(trifluoromethyl)phenyl)-1,1'-bi-2-napthol
  • (R)-(+)-3,3'-Bis(3,5-bis(trifluoromethyl)phenyl)-1,1'-bi-2,2'-naphtho
  • (R)-3,3'-Bis[3,5-bis(trifluoromethyl)phenyl]-1,1'-bi-2- naphthol, 98%e.e.
  • SF120021
  • [1,1'-Binaphthalene]-2,2'-diol, 3,3'-bis[3,5-bis(trifluoromethyl)phenyl]-, (1R)-
  • (R)-3,3'-Bis(3,5-bis(trifluoromethyl)phenyl)-[1,1'-binaphthalene]-2,2'-diol
  • (R)-CF3-BINOL
  • (R)-3,3'- bis [3,5- bis (trifluoromethyl) phenyl ]-1,1'- binaphthol
  • (R)-3,3'-BIS(3,5-BIS(TRIFLUOROMETHYL)PH&
  • r-3-3'-bis(3,5-bis(trifluoromethyl)phenyl)-1,1'-bi-2-naphthol
  • (R)-3,3'-Bis(3,5-bis(trifluoromethyl)phenyl)-[1,1'-binaphthalene]-2,2'-diol
  • (R)-3,3'- bis [3,5- bis (trifluoromethyl) phenyl ]-1,1'- binaphthol
  • 756491-54-0
  • BINOLs
  • Chiral Catalysts, Ligands, and Reagents
  • Privileged Ligands and Complexes