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(R)-3,3'-BIS(3,5-BIS(TRIFLUOROMETHYL)PH&

Product Name
(R)-3,3'-BIS(3,5-BIS(TRIFLUOROMETHYL)PH&
CAS No.
791616-62-1
Chemical Name
(R)-3,3'-BIS(3,5-BIS(TRIFLUOROMETHYL)PH&
Synonyms
SF110005;(R)-3,3'-Bis[3,5-bis(trifluoromethyl)phenyl]-1,1'-binaphthalene-;1-{[(2-Methyl-2-propanyl)oxy]carbonyl}-7-indolinecarboxylic acid;(R)-3,3'-Bis(3,5-bis(trifluoromethoxyphenyl)-1,1'-bi-(2-naphthol) phosphate;(R)-3,3''-BIS(3,5-BIS(TRIFLUOROMETHYL)PHENYL)-1,1''-BINAPH-2,2''-DIYL HYDRPHOS;(R)-3,3'-Bis[3,5-bis(trifluoromethyl)phenyl]-1,1'-binapthyl-2,2'-diyl hydrogenphosphate;(R)-3,3'-Bis[3,5-bis(trifluoromethyl)phenyl]-1,1'-binaphthyl-2,2'-diyl Hydrogen Phosphate;(R)-3,3'-Bis[3,5-bis(trifluoroMethyl)phenyl]-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate 95%;(R)-3,3'-bis[3,5-Bis(trifluoromethyl)phenyl]-1,1'-binaphthalene-2,2'-diyl hydrogen phosphate;(R)-3,3′-Bis[3,5-bis(trifluoromethyl)phenyl]-1,1′-binaphthyl-2,2′-diyl hydrogenphosphate
CBNumber
CB3972825
Molecular Formula
C36H17F12O4P
Formula Weight
772.47
MOL File
791616-62-1.mol
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(R)-3,3'-BIS(3,5-BIS(TRIFLUOROMETHYL)PH& Property

Melting point:
162-175 °C
Boiling point:
722.1±70.0 °C(Predicted)
Density 
1.63±0.1 g/cm3(Predicted)
storage temp. 
2-8°C
pka
1.09±0.20(Predicted)
form 
Powder
color 
white to light-yellow
optical activity
[α]20/D -220°, c = 1 in chloroform (typical)
InChIKey
DQORDVSQWPKAQJ-UHFFFAOYSA-N
SMILES
O1C2=C(C3=CC(C(F)(F)F)=CC(C(F)(F)F)=C3)C=C3C(=C2C2=C4C(C=CC=C4)=CC(C4=CC(C(F)(F)F)=CC(C(F)(F)F)=C4)=C2OP1(=O)O)C=CC=C3
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26
WGK Germany 
3
HS Code 
29319090
Storage Class
11 - Combustible Solids
Hazard Classifications
Eye Irrit. 2
Skin Irrit. 2
STOT SE 3
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
674605
Product name
(R)-3,3′-Bis[3,5-bis(trifluoromethyl)phenyl]-1,1′-binaphthyl-2,2′-diyl hydrogenphosphate
Purity
95%
Packaging
100mg
Price
$176.67
Updated
2025/07/31
Strem Chemicals
Product number
15-1366
Product name
(11bR)-2,6-Bis[3,5-bis(trifluoromethyl)phenyl]-4-hydroxy-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin, 98%, (99% ee)
Packaging
100mg
Price
$127
Updated
2024/03/01
Biosynth Carbosynth
Product number
FB103049
Product name
(11bR)-2,6-Bis[3,5-Bis(Trifluoromethyl)Phenyl]-4-Hydroxy-Dinaphtho[2,1-d:1',2'-f][1,3,2]Dioxaphosphepin 4-Oxide
Packaging
25mg
Price
$65
Updated
2021/12/16
Biosynth Carbosynth
Product number
FB103049
Product name
(11bR)-2,6-Bis[3,5-Bis(Trifluoromethyl)Phenyl]-4-Hydroxy-Dinaphtho[2,1-d:1',2'-f][1,3,2]Dioxaphosphepin 4-Oxide
Packaging
250mg
Price
$400
Updated
2021/12/16
Matrix Scientific
Product number
118696
Product name
(R)-3,3'-Bis[3,5-bis(trifluoromethyl)phenyl]-1,1'-binapthyl-2,2'-diyl hydrogenphosphate
Purity
99.0%
Packaging
250mg
Price
$713
Updated
2021/12/16
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(R)-3,3'-BIS(3,5-BIS(TRIFLUOROMETHYL)PH& Chemical Properties,Usage,Production

Uses

As a chiral Bronsted acid, BINOL- derived cyclic phosphoric acid (such as Akiyama chiral Bronsted acid) was also shown to be an efficient catalyst for the hydrophosphonylation of aldimines at room temperature.

General Description

(R)-3,3′-Bis[3,5-bis(trifluoromethyl)phenyl]-1,1′-binaphthyl-2,2′-diyl hydrogenphosphate is a BINOL-based chiral phosphoric acid, which can efficiently catalyze the nucleophilic addition to imine substrates. [BINOL=1,1′-bi-2-naphthol]

(R)-3,3'-BIS(3,5-BIS(TRIFLUOROMETHYL)PH& Preparation Products And Raw materials

Raw materials

Preparation Products

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(R)-3,3'-BIS(3,5-BIS(TRIFLUOROMETHYL)PH& Suppliers

Shanghai Suifu Chemical Technology CO.,LTD.
Tel
021-33738187 13341700213
Email
suifuchemical@163.com
Country
China
ProdList
501
Advantage
58
Daicel Chiral Technologies (China)CO.,LTD
Tel
021-50460086-9 15921403865
Fax
+86-21-50462321
Email
han_yajun@dctc.daicel.com
Country
China
ProdList
7440
Advantage
65
Tianjin Derchemist Science & Technology Co., Ltd.
Tel
22-58627059 13920586291
Fax
022-58620305
Email
zdcomcon@126.com
Country
China
ProdList
3978
Advantage
50
Shanghai Topbiochem Technology Co., Ltd
Tel
+86-21-60341587
Fax
+86-21-61294319
Email
sales@topbiochem.com
Country
China
ProdList
6175
Advantage
58
Sigma-Aldrich
Tel
021-61415566 800-8193336
Email
orderCN@merckgroup.com
Country
China
ProdList
51395
Advantage
80
Alfa Chemistry
Tel
1-516-6625404
Fax
1-516-927-0118
Email
support@alfa-chemistry.com
Country
United States
ProdList
9171
Advantage
60
Shanghai Chiral bio-compound co., Ltd.
Tel
021-5068 3667/17749785980/1029026415; 17749785980
Fax
021-50683667
Email
1029026415@qq.com
Country
China
ProdList
3397
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58
Shanghai Haozhixiang Biotechnology Co., Ltd
Tel
526763801 13301653310
Fax
+86-21-51619052
Email
526763801@qq.com
Country
China
ProdList
9295
Advantage
55
Henan CoreyChem Co., Ltd
Tel
0371-86658258
Fax
0371-60996044
Email
info@coreychem.com
Country
China
ProdList
10453
Advantage
58
Zhengzhou Alfachem Co.,Ltd.
Tel
0371-53778726 18003825608
Fax
2885354392
Email
liuxiaoyan@alfachem.cn
Country
China
ProdList
1988
Advantage
58
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View Lastest Price from (R)-3,3'-BIS(3,5-BIS(TRIFLUOROMETHYL)PH& manufacturers

ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD
Product
(R)-3,3'-bis[3,5-Bis(trifluoromethyl)phenyl]-1,1'-binaphthalene-2,2'-diyl hydrogen phosphate 791616-62-1
Price
US $2.20-8.80/kg
Min. Order
1kg
Purity
99%
Supply Ability
50kg
Release date
2025-06-24

791616-62-1, (R)-3,3'-BIS(3,5-BIS(TRIFLUOROMETHYL)PH&Related Search:


  • (R)-3,3''-BIS(3,5-BIS(TRIFLUOROMETHYL)PHENYL)-1,1''-BINAPH-2,2''-DIYL HYDRPHOS
  • (R)-3,3μ-Bis[3,5-bis(trifluoromethyl)phenyl]-1,1μ-bi-2-naphthol cyclic monophosphate, (11bR)-2,6-Bis[3,5-bis(trifluoromethyl)phenyl]-4-hydroxydinaphtho[2,1-d:1μ,2μ-f]-1,3,2-dioxaphosphepin 4-oxide
  • (R)-2,6-bis(3,5-bis(trifluoromethyl)phenyl)-4-hydroxydinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine 4-oxide
  • (11bR)-2,6-Bis[3,5-Bis(Trifluoromethyl)Phenyl]-4-Hydroxy-Dinaphtho[2,1-d:1',2'-f][1,3,2]Dioxaphosphepin 4-Oxide
  • (R)-3,3'-Bis[3,5-bis(trifluoroMethyl)phenyl]-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate 95%
  • (R)-3,3'-Bis[3,5-bis(trifluoromethyl)phenyl]-1,1'-binapthyl-2,2'-diyl hydrogenphosphate
  • (R)-3,3'-Bis[3,5-bis(trifluoromethyl)phenyl]-1,1'-binaphthalene-
  • (11BR)-2,6-BIS[3,5-BIS(TRIFLUOROMETHYL)PHENYL]-4-HYDROXY-4-OXIDE-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN,98%,(99%EE)
  • (11bR)-2,6-Bis[3,5-bis(trifluoromethyl)phenyl]-4-hydroxy-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin
  • 2,6-bis(3,5-bis(trifluoromethyl)phenyl)-4-hydroxydinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine 4-oxide
  • SF110005
  • Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin, 2,6-bis[3,5-bis(trifluoromethyl)phenyl]-4-hydroxy-, 4-oxide, (11bR)-
  • (R)-3,3'-bis[3,5-Bis(trifluoromethyl)phenyl]-1,1'-binaphthalene-2,2'-diyl hydrogen phosphate
  • 1-{[(2-Methyl-2-propanyl)oxy]carbonyl}-7-indolinecarboxylic acid
  • (R)-3,3'-Bis[3,5-bis(trifluoromethyl)phenyl]-1,1'-binaphthyl-2,2'-diyl Hydrogen Phosphate
  • (<i>R</i>)-3,3′-Bis[3,5-bis(trifluoromethyl)phenyl]-1,1′-binaphthyl-2,2′-diyl hydrogenphosphate
  • (R)-3,3′-Bis[3,5-bis(trifluoromethyl)phenyl]-1,1′-binaphthyl-2,2′-diyl hydrogenphosphate, CAS 791616-62-1
  • (R)-3,3'-Bis(3,5-bis(trifluoromethoxyphenyl)-1,1'-bi-(2-naphthol) phosphate
  • 791616-62-1