(R)-3,3'-BIS(3,5-BIS(TRIFLUOROMETHYL)PH&

ChemicalBook > CAS DataBase List > (R)-3,3'-BIS(3,5-BIS(TRIFLUOROMETHYL)PH&

(R)-3,3'-BIS(3,5-BIS(TRIFLUOROMETHYL)PH&

Product Name: (R)-3,3'-BIS(3,5-BIS(TRIFLUOROMETHYL)PH&
CAS No.: 791616-62-1
Chemical Name: (R)-3,3'-BIS(3,5-BIS(TRIFLUOROMETHYL)PH&
Synonyms: SF110005;(R)-3,3'-Bis[3,5-bis(trifluoromethyl)phenyl]-1,1'-binaphthalene-;1-{[(2-Methyl-2-propanyl)oxy]carbonyl}-7-indolinecarboxylic acid;(R)-3,3''-BIS(3,5-BIS(TRIFLUOROMETHYL)PHENYL)-1,1''-BINAPH-2,2''-DIYL HYDRPHOS;(R)-3,3'-Bis[3,5-bis(trifluoromethyl)phenyl]-1,1'-binapthyl-2,2'-diyl hydrogenphosphate;(R)-3,3'-Bis[3,5-bis(trifluoromethyl)phenyl]-1,1'-binaphthyl-2,2'-diyl Hydrogen Phosphate;(R)-3,3'-Bis[3,5-bis(trifluoroMethyl)phenyl]-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate 95%;(R)-3,3'-bis[3,5-Bis(trifluoromethyl)phenyl]-1,1'-binaphthalene-2,2'-diyl hydrogen phosphate;2,6-bis(3,5-bis(trifluoromethyl)phenyl)-4-hydroxydinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine 4-oxide;(R)-2,6-bis(3,5-bis(trifluoromethyl)phenyl)-4-hydroxydinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine 4-oxide
CBNumber: CB3972825
Molecular Formula: C36H17F12O4P
Formula Weight: 772.47
MOL File: 791616-62-1.mol

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(R)-3,3'-BIS(3,5-BIS(TRIFLUOROMETHYL)PH& Property

Melting point:: 162-175 °C
Boiling point:: 722.1±70.0 °C(Predicted)
Density: 1.63±0.1 g/cm3(Predicted)
storage temp.: 2-8°C
pka: 1.09±0.20(Predicted)
form: Powder
color: white to light-yellow
optical activity: [α]20/D -220°, c = 1 in chloroform (typical)
InChIKey: DQORDVSQWPKAQJ-UHFFFAOYSA-N

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Safety

Hazard Codes: Xi
Risk Statements: 36/37/38
Safety Statements: 26
WGK Germany: 3
HS Code: 29319090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 674605
Product name: (R)-3,3′-Bis[3,5-bis(trifluoromethyl)phenyl]-1,1′-binaphthyl-2,2′-diyl hydrogenphosphate
Purity: 95%
Packaging: 100mg
Price: $189
Updated: 2024/03/01

Strem Chemicals

Product number: 15-1366
Product name: (11bR)-2,6-Bis[3,5-bis(trifluoromethyl)phenyl]-4-hydroxy-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin, 98%, (99% ee)
Packaging: 100mg
Price: $127
Updated: 2024/03/01

Biosynth Carbosynth

Product number: FB103049
Product name: (11bR)-2,6-Bis[3,5-Bis(Trifluoromethyl)Phenyl]-4-Hydroxy-Dinaphtho[2,1-d:1',2'-f][1,3,2]Dioxaphosphepin 4-Oxide
Packaging: 25mg
Price: $65
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FB103049
Product name: (11bR)-2,6-Bis[3,5-Bis(Trifluoromethyl)Phenyl]-4-Hydroxy-Dinaphtho[2,1-d:1',2'-f][1,3,2]Dioxaphosphepin 4-Oxide
Packaging: 250mg
Price: $400
Updated: 2021/12/16

Matrix Scientific

Product number: 118696
Product name: (R)-3,3'-Bis[3,5-bis(trifluoromethyl)phenyl]-1,1'-binapthyl-2,2'-diyl hydrogenphosphate
Purity: 99.0%
Packaging: 250mg
Price: $713
Updated: 2021/12/16

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(R)-3,3'-BIS(3,5-BIS(TRIFLUOROMETHYL)PH& Chemical Properties,Usage,Production

Uses

As a chiral Bronsted acid, BINOL- derived cyclic phosphoric acid (such as Akiyama chiral Bronsted acid) was also shown to be an efficient catalyst for the hydrophosphonylation of aldimines at room temperature.

General Description

(R)-3,3′-Bis[3,5-bis(trifluoromethyl)phenyl]-1,1′-binaphthyl-2,2′-diyl hydrogenphosphate is a BINOL-based chiral phosphoric acid, which can efficiently catalyze the nucleophilic addition to imine substrates. [BINOL=1,1′-bi-2-naphthol]

(R)-3,3'-BIS(3,5-BIS(TRIFLUOROMETHYL)PH& Preparation Products And Raw materials

Raw materials

Preparation Products

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(R)-3,3'-BIS(3,5-BIS(TRIFLUOROMETHYL)PH& Suppliers

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791616-62-1, (R)-3,3'-BIS(3,5-BIS(TRIFLUOROMETHYL)PH&Related Search:

S-3,3'-Bis(4-(1,1-diMethylethyl)phenyl)-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate R-4-oxide-4-hydroxy-2,6-bis[4-(trifluoroMethyl)phenyl]-Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin R- 4-oxide-4-hydroxy-2,6-bis([1,1':3',1''-terphenyl]-5'-yl)-Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin (S)-(+)-3,3'-BIS(3,5-BIS(TRIFLUOROMETHYL)PHENYL)-1,1'-BINAPHTHYL-2,2'-DIYL HYDROGENPHOSPHATE, 95% S-3,3'-Bis(9-anthracenyl)-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate S-4-oxide-4-hydroxy-2,6-bis(4-nitrophenyl)- Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin R-3,3'-Bis(4-(1,1-diMethylethyl)phenyl)-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate R-3,3'-Bis(triphenylsilyl)-5,5',6,6',7,7',8,8'-Octahydro-1,1'-bi-2-naphthyl phosphate R-3,3'-bis(4-nitrophenyl)-1,1'-Binaphthalene]-2,2'-diol R-4-oxide-4-hydroxy-2,6-bis(4-nitrophenyl)- Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin R- 4-oxide--hydroxy-2,6-bis[4-(2-naphthalenyl)phenyl]-Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin (R)-3,3'-BIS(3,5-BIS(TRIFLUOROMETHYL)PH& (R)-3,3'-BIS(TRIPHENYLSILYL)-1,1'-BI-2-& (S)-5,5',6,6',7,7',8,8'-Octahydro-1,1'-bi-2-naphthyl phosphate (S)-3,3'-DI(ANTHRACEN-9-YL)-1,1'-BINAPHTHYL-2,2'-DIOL R-3,3'-bis[4-(2-naphthalenyl)phenyl]-1,1'-Binaphthalene]-2,2'-diol R-3,3'-bis((3,5-bis(trifluoroMethyl)phenyl)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate R-5,5',6,6',7,7',8,8'-octahydro-3,3'-diphenyl-[1,1'-Binaphthalene]-2,2'-diol

(R)-3,3''-BIS(3,5-BIS(TRIFLUOROMETHYL)PHENYL)-1,1''-BINAPH-2,2''-DIYL HYDRPHOS

(R)-3,3μ-Bis[3,5-bis(trifluoromethyl)phenyl]-1,1μ-bi-2-naphthol cyclic monophosphate, (11bR)-2,6-Bis[3,5-bis(trifluoromethyl)phenyl]-4-hydroxydinaphtho[2,1-d:1μ,2μ-f]-1,3,2-dioxaphosphepin 4-oxide

(R)-2,6-bis(3,5-bis(trifluoromethyl)phenyl)-4-hydroxydinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine 4-oxide

(11bR)-2,6-Bis[3,5-Bis(Trifluoromethyl)Phenyl]-4-Hydroxy-Dinaphtho[2,1-d:1',2'-f][1,3,2]Dioxaphosphepin 4-Oxide

(R)-3,3'-Bis[3,5-bis(trifluoroMethyl)phenyl]-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate 95%

(R)-3,3'-Bis[3,5-bis(trifluoromethyl)phenyl]-1,1'-binapthyl-2,2'-diyl hydrogenphosphate

(R)-3,3'-Bis[3,5-bis(trifluoromethyl)phenyl]-1,1'-binaphthalene-

(11BR)-2,6-BIS[3,5-BIS(TRIFLUOROMETHYL)PHENYL]-4-HYDROXY-4-OXIDE-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN,98%,(99%EE)

(11bR)-2,6-Bis[3,5-bis(trifluoromethyl)phenyl]-4-hydroxy-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin

2,6-bis(3,5-bis(trifluoromethyl)phenyl)-4-hydroxydinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine 4-oxide

SF110005

Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin, 2,6-bis[3,5-bis(trifluoromethyl)phenyl]-4-hydroxy-, 4-oxide, (11bR)-

(R)-3,3'-bis[3,5-Bis(trifluoromethyl)phenyl]-1,1'-binaphthalene-2,2'-diyl hydrogen phosphate

1-{[(2-Methyl-2-propanyl)oxy]carbonyl}-7-indolinecarboxylic acid

(R)-3,3'-Bis[3,5-bis(trifluoromethyl)phenyl]-1,1'-binaphthyl-2,2'-diyl Hydrogen Phosphate

(R)-2,6-bis(3,5-bis(trifluoromethyl)phenyl)-4-hydroxydinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine 4-oxide

791616-62-1