(R)-3,3'-BIS(3,5-BIS(TRIFLUOROMETHYL)PH&

Product Name: (R)-3,3'-BIS(3,5-BIS(TRIFLUOROMETHYL)PH&
CAS No.: 756491-54-0
Chemical Name: (R)-3,3'-BIS(3,5-BIS(TRIFLUOROMETHYL)PH&
Synonyms: SF120021;(R)-CF3-BINOL;(R)-3,3'-BIS(3,5-BIS(TRIFLUOROMETHYL)PH&;(R)-3,3'-BIS(3,5-BIS(TRIFLUOROMETHYL)PH&;r-3-3'-bis(3,5-bis(trifluoromethyl)phenyl)-1,1'-bi-2-naphthol;(R)-3,3'-Bis(3,5-bis(trifluoromethyl)phenyl)-1,1'-bi-2-napthol;(R)-3,3'- bis [3,5- bis (trifluoromethyl) phenyl ]-1,1'- binaphthol;(R)-3,3'- bis [3,5- bis (trifluoromethyl) phenyl ]-1,1'- binaphthol;(R)-(+)-3,3'-Bis(3,5-bis(trifluoromethyl)phenyl)-1,1'-bi-2,2'-naphtho;(R)-(+)-3,3'-Bis(3,5-bis(trifluoromethyl)phenyl)-1,1'-bi-2,2'-naphthol
CBNumber: CB4972721
Molecular Formula: C36H18F12O2
Formula Weight: 710.51
MOL File: 756491-54-0.mol

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(R)-3,3'-BIS(3,5-BIS(TRIFLUOROMETHYL)PH& Property

Melting point:: 216-220 °C
Boiling point:: 574.7±50.0 °C(Predicted)
Density: 1.466±0.06 g/cm3(Predicted)
storage temp.: 2-8°C
form: solid
pka: 7.62±0.50(Predicted)
color: White to yellow
optical activity: [α]22/D 45°, c = 1 in chloroform

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Safety

Hazard Codes: Xi
Risk Statements: 36/37/38
Safety Statements: 26
WGK Germany: 3
HS Code: 29081990

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 674591
Product name: (R)-(+)-3,3′-Bis(3,5-bis(trifluoromethyl)phenyl)-1,1′-bi-2-naphthol
Purity: 95%
Packaging: 100mg
Price: $96.8
Updated: 2024/03/01

ChemScene

Product number: CS-0086114
Product name: (R)-CF3-BINOL
Purity: >97.0%
Packaging: 250mg
Price: $153
Updated: 2021/12/16

ChemScene

Product number: CS-0086114
Product name: (R)-CF3-BINOL
Purity: >97.0%
Packaging: 100mg
Price: $78
Updated: 2021/12/16

Apolloscientific

Product number: PC440000
Product name: (R)-3,3'-Bis(3,5-bis(trifluoromethyl)phenyl)-1,1'-bi-2-napthol
Packaging: 250mg
Price: $414
Updated: 2021/12/16

SynQuest Laboratories

Product number: 2804-3-R0
Product name: (R)-3,3'-Bis(3,5-bis(trifluoromethyl)phenyl)-1,1'-bi-2-napthol
Packaging: 250mg
Price: $456
Updated: 2021/12/16

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(R)-3,3'-BIS(3,5-BIS(TRIFLUOROMETHYL)PH& Chemical Properties,Usage,Production

Chemical Properties

Colorless solid

Uses

Precursor to a chiral Bronsted acid (680184) used to catalyze an enantioselective aza Diels-Alder reaction providing bicyclic lactams. Rare earth metal complexes of this chiral binapthol catalyze an intramolecular hydroamination of amino olefins leading to chiral pyrrolidines.

(R)-3,3'-BIS(3,5-BIS(TRIFLUOROMETHYL)PH& Preparation Products And Raw materials

Raw materials

Preparation Products

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(R)-3,3'-BIS(3,5-BIS(TRIFLUOROMETHYL)PH& Suppliers

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756491-54-0, (R)-3,3'-BIS(3,5-BIS(TRIFLUOROMETHYL)PH&Related Search:

(R)-(+)-3,3'-DIBROMO-5,5',6,6',7,7',8,8'-OCTAHYDRO(1,1'BINAPHTHALENE)-2,2'-DIOL R-3,3'-Bis(triphenylsilyl)-5,5',6,6',7,7',8,8'-Octahydro-1,1'-bi-2-naphthyl phosphate R-3,3'-bis(4-nitrophenyl)-1,1'-Binaphthalene]-2,2'-diol R-4-oxide-4-hydroxy-2,6-bis(4-nitrophenyl)- Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin R- 4-oxide--hydroxy-2,6-bis[4-(2-naphthalenyl)phenyl]-Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin (R)-3,3'-BIS(TRIPHENYLSILYL)-1,1'-BI-2-& (S)-5,5',6,6',7,7',8,8'-Octahydro-1,1'-bi-2-naphthyl phosphate (R)-3,3'-BIS(3,5-BIS(TRIFLUOROMETHYL)PH& (S)-3,3'-DI(ANTHRACEN-9-YL)-1,1'-BINAPHTHYL-2,2'-DIOL R-3,3'-bis[4-(2-naphthalenyl)phenyl]-1,1'-Binaphthalene]-2,2'-diol R-3,3'-bis((3,5-bis(trifluoroMethyl)phenyl)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate R-5,5',6,6',7,7',8,8'-octahydro-3,3'-diphenyl-[1,1'-Binaphthalene]-2,2'-diol 2,6-Diphenylphenol (R)-(+)-1,1'-Bi-2-naphthol (R)-3,3'-DIMETHYL-1,1'-BINAPHTHALENE-2,2'-DIOL 3,3'-DIPHENYLBIPHENYL (S)-(+)-3,3'-BIS(3,5-BIS(TRIFLUOROMETHYL)PHENYL)-1,1'-BINAPHTHYL-2,2'-DIYL HYDROGENPHOSPHATE, 95% (R)-3,3'-BIS(3,5-BIS(TRIFLUOROMETHYL)PH&

(R)-3,3'-BIS(3,5-BIS(TRIFLUOROMETHYL)PH&

(R)-(+)-3,3'-Bis(3,5-bis(trifluoromethyl)phenyl)-1,1'-bi-2,2'-naphthol

(R)-(+)-3,3'-Bis(3,5-bis(trifluoromethyl)phenyl)-1,1'-bi-2-naphthol 95%

(R)-3,3'-Bis(3,5-bis(trifluoromethyl)phenyl)-1,1'-bi-2-napthol

(R)-(+)-3,3'-Bis(3,5-bis(trifluoromethyl)phenyl)-1,1'-bi-2,2'-naphtho

(R)-3,3'-Bis[3,5-bis(trifluoromethyl)phenyl]-1,1'-bi-2- naphthol, 98%e.e.

SF120021

[1,1'-Binaphthalene]-2,2'-diol, 3,3'-bis[3,5-bis(trifluoromethyl)phenyl]-, (1R)-

(R)-3,3'-Bis(3,5-bis(trifluoromethyl)phenyl)-[1,1'-binaphthalene]-2,2'-diol

(R)-CF3-BINOL

(R)-3,3'- bis [3,5- bis (trifluoromethyl) phenyl ]-1,1'- binaphthol

(R)-3,3'-BIS(3,5-BIS(TRIFLUOROMETHYL)PH&

r-3-3'-bis(3,5-bis(trifluoromethyl)phenyl)-1,1'-bi-2-naphthol

(R)-3,3'-Bis(3,5-bis(trifluoromethyl)phenyl)-[1,1'-binaphthalene]-2,2'-diol

(R)-3,3'- bis [3,5- bis (trifluoromethyl) phenyl ]-1,1'- binaphthol

756491-54-0

BINOLs

Chiral Catalysts, Ligands, and Reagents

Privileged Ligands and Complexes