ChemicalBook > CAS DataBase List > (1S,2R,5S)-(+)-MENTHYL (R)-P-TOLUENESULFINATE

(1S,2R,5S)-(+)-MENTHYL (R)-P-TOLUENESULFINATE

Product Name
(1S,2R,5S)-(+)-MENTHYL (R)-P-TOLUENESULFINATE
CAS No.
91796-57-5
Chemical Name
(1S,2R,5S)-(+)-MENTHYL (R)-P-TOLUENESULFINATE
Synonyms
(+)-Menthyl (R)-p-toluenesulfinate;(R)-(+)-MENTHYL P-TOLUENESULFINATE;(+)-(1S)-Menthyl (R)-p-toluenesulfinate;(+)-(1S)-MENTHYL (R)-TOLUENE-4-SULFINATE;(1S,2R,5S)-MENTHYL (R)-P-TOLUENESULFINATE;(1S,2R,5S)-(+)-MENTHYL (R)-P-TOLUENESULFINATE;(R)-(+)-P-TOLUENESULFINIC ACID D-MENTHYL ESTER;(1S,2R,5S)-(+)-Menthyl(R)-p-Toluenesulfinate>(+)-(1S)-Menthyl (R)-p-toluenesulfinate;(R)-(5S)-2-Isopropyl-5-methylcyclohexyl 4-methylbenzenesulfinate
CBNumber
CB5112980
Molecular Formula
C17H26O2S
Formula Weight
294.45
MOL File
91796-57-5.mol
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(1S,2R,5S)-(+)-MENTHYL (R)-P-TOLUENESULFINATE Property

Melting point:
104-106 °C(lit.)
Boiling point:
402.3±38.0 °C(Predicted)
Density 
1.08±0.1 g/cm3(Predicted)
refractive index 
200 ° (C=2, Acetone)
storage temp. 
2-8°C
form 
powder to crystal
color 
White to Almost white
optical activity
[α]20/D +200°, c = 2 in acetone
BRN 
4907352
CAS DataBase Reference
91796-57-5(CAS DataBase Reference)
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Safety

Safety Statements 
22-24/25
WGK Germany 
3
HS Code 
2930.90.2900
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Hazard and Precautionary Statements (GHS)

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
278742
Product name
(1S,2R,5S)-(+)-Menthyl (R)-p-toluenesulfinate
Purity
98%
Packaging
10g
Price
$297
Updated
2023/06/20
Sigma-Aldrich
Product number
89714
Product name
(+)-(1S)-Menthyl (R)-p-toluenesulfinate
Purity
≥98.0% (sum of enantiomers, HPLC)
Packaging
5g
Price
$130
Updated
2023/01/07
TCI Chemical
Product number
M1066
Product name
(1S,2R,5S)-(+)-Menthyl (R)-p-Toluenesulfinate
Purity
>97.0%(HPLC)
Packaging
1g
Price
$41
Updated
2025/07/31
TCI Chemical
Product number
M1066
Product name
(1S,2R,5S)-(+)-Menthyl (R)-p-Toluenesulfinate
Purity
>97.0%(HPLC)
Packaging
5g
Price
$122
Updated
2025/07/31
TRC
Product number
M220403
Product name
(1S,2R,5S)-(+)-Menthyl (R)-p-Toluenesulfinate
Packaging
50mg
Price
$45
Updated
2021/12/16
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(1S,2R,5S)-(+)-MENTHYL (R)-P-TOLUENESULFINATE Chemical Properties,Usage,Production

Chemical Properties

white to light yellow crystal powde

Uses

(1S,2R,5S)-(+)-Menthyl (R)-p-Toluenesulfinate is used as a reactant in the stereoselective synthesis of pyrazole derivatives using tert-butansulfonamide as a chiral auxiliary.

Uses

(1S,2R,5S)-(+)-Menthyl (R)-p-toluenesulfinate can be used:

  • As a chiral electrophile in the synthesis of fluorescent triazolopyridine ligands.
  • To prepare various sulfinimines, which are further used in the synthesis of α-aminophosphonic acids by reacting with borane complexes.
  • In one of the key synthetic steps for the synthesis of (S)-(+)-ethyl β-amino-3-pyridinepropanoate, a component of an antiplatelet agent.

(1S,2R,5S)-(+)-MENTHYL (R)-P-TOLUENESULFINATE Preparation Products And Raw materials

Raw materials

Preparation Products

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(1S,2R,5S)-(+)-MENTHYL (R)-P-TOLUENESULFINATE Suppliers

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View Lastest Price from (1S,2R,5S)-(+)-MENTHYL (R)-P-TOLUENESULFINATE manufacturers

Career Henan Chemical Co
Product
(1S,2R,5S)-(+)-MENTHYL (R)-P-TOLUENESULFINATE 91796-57-5
Price
US $6.60/KG
Min. Order
1KG
Purity
97%-99%
Supply Ability
1kg -1000kg
Release date
2020-01-02

91796-57-5, (1S,2R,5S)-(+)-MENTHYL (R)-P-TOLUENESULFINATERelated Search:

Methyl p-toluenesulfonate P-TOLUENESULFINIC ACID p-Toluenesulfonic acid (1R,2S,5R)-(-)-MENTHYL (S)-P-TOLUENESULFINATE 11-ALPHA-HYDROXYPROGESTERONE TOSYLATE (1S,2R,5S)-(+)-MENTHYL (R)-P-TOLUENESULFINATE

  • (1S,2R,5S)-(+)-MENTHYL (R)-P-TOLUENESULFINATE
  • (1S,2R,5S)-MENTHYL (R)-P-TOLUENESULFINATE
  • (+)-(1S)-MENTHYL (R)-TOLUENE-4-SULFINATE
  • (+)-(1S)-Menthyl (R)-p-toluenesulfinate
  • (R)-(5S)-2-Isopropyl-5-methylcyclohexyl 4-methylbenzenesulfinate
  • (R)-(+)-MENTHYL P-TOLUENESULFINATE
  • (R)-(+)-P-TOLUENESULFINIC ACID D-MENTHYL ESTER
  • p-Toluenesulfinic acid (1R)-5β-methyl-2β-isopropylcyclohexan-1β-yl ester
  • Benzenesulfinic acid, 4-Methyl-,(1S,2R,5S)-5-Methyl-2-(1-Methylethyl)cyclohexylester, [S(R)]-
  • (+)-Menthyl (R)-p-toluenesulfinate
  • (1S,2R,5S)-(+)-Menthyl(R)-p-Toluenesulfinate&gt
  • (R)-(1S,2R,5S)-2-Isopropyl-5-methylcyclohexyl 4-Methylbenzenesulfinate
  • (1S,2R,5S)-5-Methyl-2-(1-methylethyl)cyclohexyl [S(R)]-4-methylbenzenesulfinate
  • (1<i>S</i>,2<i>R</i>,5<i>S</i>)-(+)-Menthyl (<i>R</i>)-<i>p</i>-toluenesulfinate
  • (+)-(1<i>S</i>)-Menthyl (<i>R</i>)-<i>p</i>-toluenesulfinate
  • 91796-57-5
  • C17H26O2S
  • Organic Building Blocks
  • Sulfonates/Sulfinates
  • Terpenes
  • Asymmetric Synthesis
  • Monocyclic Monoterpenes
  • Chiral Building Blocks
  • chiral
  • Asymmetric Synthesis
  • Biochemistry
  • Monocyclic Monoterpenes
  • Synthetic Organic Chemistry
  • Terpenes