(1S,2R,5S)-(+)-MENTHYL (R)-P-TOLUENESULFINATE

ChemicalBook > CAS DataBase List > (1S,2R,5S)-(+)-MENTHYL (R)-P-TOLUENESULFINATE

(1S,2R,5S)-(+)-MENTHYL (R)-P-TOLUENESULFINATE

Product Name: (1S,2R,5S)-(+)-MENTHYL (R)-P-TOLUENESULFINATE
CAS No.: 91796-57-5
Chemical Name: (1S,2R,5S)-(+)-MENTHYL (R)-P-TOLUENESULFINATE
Synonyms: (+)-Menthyl (R)-p-toluenesulfinate;(R)-(+)-MENTHYL P-TOLUENESULFINATE;(+)-(1S)-Menthyl (R)-p-toluenesulfinate;(+)-(1S)-MENTHYL (R)-TOLUENE-4-SULFINATE;(1S,2R,5S)-MENTHYL (R)-P-TOLUENESULFINATE;(1S,2R,5S)-(+)-MENTHYL (R)-P-TOLUENESULFINATE;(R)-(+)-P-TOLUENESULFINIC ACID D-MENTHYL ESTER;(1S,2R,5S)-(+)-Menthyl(R)-p-Toluenesulfinate>(R)-(5S)-2-Isopropyl-5-methylcyclohexyl 4-methylbenzenesulfinate;(R)-(1S,2R,5S)-2-Isopropyl-5-methylcyclohexyl 4-Methylbenzenesulfinate
CBNumber: CB5112980
Molecular Formula: C17H26O2S
Formula Weight: 294.45
MOL File: 91796-57-5.mol

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(1S,2R,5S)-(+)-MENTHYL (R)-P-TOLUENESULFINATE Property

Melting point:: 104-106 °C(lit.)
Boiling point:: 402.3±38.0 °C(Predicted)
Density: 1.08±0.1 g/cm3(Predicted)
refractive index: 200 ° (C=2, Acetone)
storage temp.: 2-8°C
form: powder to crystal
color: White to Almost white
optical activity: [α]20/D +200°, c = 2 in acetone
BRN: 4907352
CAS DataBase Reference: 91796-57-5(CAS DataBase Reference)

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Safety

Safety Statements: 22-24/25
WGK Germany: 3
HS Code: 2930.90.2900

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Hazard and Precautionary Statements (GHS)

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 278742
Product name: (1S,2R,5S)-(+)-Menthyl (R)-p-toluenesulfinate
Purity: 98%
Packaging: 10g
Price: $297
Updated: 2023/06/20

Sigma-Aldrich

Product number: 89714
Product name: (+)-(1S)-Menthyl (R)-p-toluenesulfinate
Purity: ≥98.0% (sum of enantiomers, HPLC)
Packaging: 5g
Price: $130
Updated: 2023/01/07

TCI Chemical

Product number: M1066
Product name: (1S,2R,5S)-(+)-Menthyl (R)-p-Toluenesulfinate
Purity: >97.0%(HPLC)
Packaging: 1g
Price: $41
Updated: 2024/03/01

TCI Chemical

Product number: M1066
Product name: (1S,2R,5S)-(+)-Menthyl (R)-p-Toluenesulfinate
Purity: >97.0%(HPLC)
Packaging: 5g
Price: $121
Updated: 2024/03/01

TRC

Product number: M220403
Product name: (1S,2R,5S)-(+)-Menthyl (R)-p-Toluenesulfinate
Packaging: 50mg
Price: $45
Updated: 2021/12/16

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(1S,2R,5S)-(+)-MENTHYL (R)-P-TOLUENESULFINATE Chemical Properties,Usage,Production

Chemical Properties

white to light yellow crystal powde

Uses

(1S,2R,5S)-(+)-Menthyl (R)-p-Toluenesulfinate is used as a reactant in the stereoselective synthesis of pyrazole derivatives using tert-butansulfonamide as a chiral auxiliary.

Uses

(1S,2R,5S)-(+)-Menthyl (R)-p-toluenesulfinate can be used:

As a chiral electrophile in the synthesis of fluorescent triazolopyridine ligands.
To prepare various sulfinimines, which are further used in the synthesis of α-aminophosphonic acids by reacting with borane complexes.
In one of the key synthetic steps for the synthesis of (S)-(+)-ethyl β-amino-3-pyridinepropanoate, a component of an antiplatelet agent.

(1S,2R,5S)-(+)-MENTHYL (R)-P-TOLUENESULFINATE Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from (1S,2R,5S)-(+)-MENTHYL (R)-P-TOLUENESULFINATE manufacturers

Career Henan Chemical Co

Product: (1S,2R,5S)-(+)-MENTHYL (R)-P-TOLUENESULFINATE 91796-57-5
Price: US $6.60/KG
Min. Order: 1KG
Purity: 97%-99%
Supply Ability: 1kg -1000kg
Release date: 2020-01-02

91796-57-5, (1S,2R,5S)-(+)-MENTHYL (R)-P-TOLUENESULFINATERelated Search:

Methyl p-toluenesulfonate P-TOLUENESULFINIC ACID p-Toluenesulfonic acid (1R,2S,5R)-(-)-MENTHYL (S)-P-TOLUENESULFINATE 11-ALPHA-HYDROXYPROGESTERONE TOSYLATE (1S,2R,5S)-(+)-MENTHYL (R)-P-TOLUENESULFINATE

(1S,2R,5S)-(+)-MENTHYL (R)-P-TOLUENESULFINATE

(1S,2R,5S)-MENTHYL (R)-P-TOLUENESULFINATE

(+)-(1S)-MENTHYL (R)-TOLUENE-4-SULFINATE

(+)-(1S)-Menthyl (R)-p-toluenesulfinate

(R)-(5S)-2-Isopropyl-5-methylcyclohexyl 4-methylbenzenesulfinate

(R)-(+)-MENTHYL P-TOLUENESULFINATE

(R)-(+)-P-TOLUENESULFINIC ACID D-MENTHYL ESTER

p-Toluenesulfinic acid (1R)-5β-methyl-2β-isopropylcyclohexan-1β-yl ester

Benzenesulfinic acid, 4-Methyl-,(1S,2R,5S)-5-Methyl-2-(1-Methylethyl)cyclohexylester, [S(R)]-

(+)-Menthyl (R)-p-toluenesulfinate

(1S,2R,5S)-(+)-Menthyl(R)-p-Toluenesulfinate&gt

(R)-(1S,2R,5S)-2-Isopropyl-5-methylcyclohexyl 4-Methylbenzenesulfinate

(1S,2R,5S)-5-Methyl-2-(1-methylethyl)cyclohexyl [S(R)]-4-methylbenzenesulfinate

91796-57-5

C17H26O2S

Organic Building Blocks

Sulfonates/Sulfinates

Terpenes

Asymmetric Synthesis

Monocyclic Monoterpenes

Chiral Building Blocks

chiral

Asymmetric Synthesis

Biochemistry

Monocyclic Monoterpenes

Synthetic Organic Chemistry

Terpenes