ChemicalBook > CAS DataBase List > (1R,2S,5R)-(-)-MENTHYL (S)-P-TOLUENESULFINATE

(1R,2S,5R)-(-)-MENTHYL (S)-P-TOLUENESULFINATE

Product Name
(1R,2S,5R)-(-)-MENTHYL (S)-P-TOLUENESULFINATE
CAS No.
1517-82-4
Chemical Name
(1R,2S,5R)-(-)-MENTHYL (S)-P-TOLUENESULFINATE
Synonyms
(S)-p-toL;(1R,2S,5R)-(-)-MenthyL;menthyl p-toluenesulfinate;(S)-(-)-MENTHYL P-TOLUENESULFINATE;Menthyl (S)-4-methylbenzenesulfinate;(?-(1R)-Menthyl (S)-p-toluenesulfinate;(-)-Menthyl (S)-4-methylbenzenesulfinate;(-)-(1R)-MENTHYL (S)-TOLUENE-4-SULFINATE;(-)-(1R)-Menthyl (S)-toluene-4-sulfinate;(1R,2S,5R)-MENTHYL (S)-P-TOLUENESULFINATE
CBNumber
CB6129035
Molecular Formula
C17H26O2S
Formula Weight
294.45
MOL File
1517-82-4.mol
More
Less

(1R,2S,5R)-(-)-MENTHYL (S)-P-TOLUENESULFINATE Property

Melting point:
99-104 °C
Boiling point:
402.3±38.0 °C(Predicted)
Density 
1.08
refractive index 
-199 ° (C=1.5, Acetone)
storage temp. 
-20°C
solubility 
Acetone (Slightly), Chloroform (Slightly)
form 
Solution
color 
Yellow to brown or gray
optical activity
[α]20/D 195°, c = 2 in acetone
BRN 
3207468
More
Less

Safety

Safety Statements 
22-24/25
WGK Germany 
3
HS Code 
29309090
More
Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

More
Less

N-Bromosuccinimide Price

Sigma-Aldrich
Product number
278750
Product name
(1R,2S,5R)-(?)-Menthyl (S)-p-toluenesulfinate
Purity
98%
Packaging
10g
Price
$182
Updated
2023/06/20
TCI Chemical
Product number
M1044
Product name
(1R,2S,5R)-(-)-Menthyl (S)-p-Toluenesulfinate
Purity
>98.0%(HPLC)
Packaging
5g
Price
$115
Updated
2024/03/01
TCI Chemical
Product number
M1044
Product name
(1R,2S,5R)-(-)-Menthyl (S)-p-Toluenesulfinate
Purity
>98.0%(HPLC)
Packaging
25g
Price
$390
Updated
2024/03/01
TRC
Product number
M220400
Product name
(1R,2S,5R)-(?)-Menthyl (S)-p-toluenesulfinate
Packaging
2.5g
Price
$70
Updated
2021/12/16
ChemScene
Product number
CS-M1307
Product name
(S)-((1R,2S,5R)-2-isopropyl-5-methylcyclohexyl)4-methylbenzenesulfinate
Packaging
5g
Price
$75
Updated
2021/12/16
More
Less

(1R,2S,5R)-(-)-MENTHYL (S)-P-TOLUENESULFINATE Chemical Properties,Usage,Production

Chemical Properties

White crystalline powder

Uses

(1R,2S,5R)-(-)-Menthyl (S)-p-Toluenesulfinate is a reactant used in the synthesis of sulfoxide pincer complexes of Mg, Rh and Ir.

Uses

(1R,2S,5R)-(-)-Menthyl (S)-p-toluenesulfinate can react with:

  • metal ketimines to form enantiopure sulfinimines
  • p-(methylthio)benzaldehyde to form (S)-(-)-N-(4-methylthiobenzylidene)-p-toluenesulfinimine

General Description

(1R,2S,5R)-(-)-Menthyl (S)-p-toluenesulfinate is mainly used for the introduction of p-toluenesulfinyl group in asymmetric synthesis.

(1R,2S,5R)-(-)-MENTHYL (S)-P-TOLUENESULFINATE Preparation Products And Raw materials

Raw materials

Preparation Products

More
Less

(1R,2S,5R)-(-)-MENTHYL (S)-P-TOLUENESULFINATE Suppliers

J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
94838
Advantage
76
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
4006608290; 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40241
Advantage
62
TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24539
Advantage
81
Ark Pharm, Inc.
Tel
847-367-3680
Fax
847-367-3681
Email
sales@arkpharminc.com
Country
United States
ProdList
1670
Advantage
56
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44751
Advantage
61
Capot Chemical Co., Ltd
Tel
+86 (0) 571 85 58 67 18
Fax
0086-571-85864795
Email
sales@capotchem.com
Country
China
ProdList
18217
Advantage
66
Adamas Reagent, Ltd.
Tel
400-6009262 16621234537
Fax
021-64823266
Email
zhangsn@titansci.com
Country
China
ProdList
14113
Advantage
59
Shanghai Longsheng chemical Co.,Ltd.
Tel
021-58099652-8005 13585536065
Fax
021-58099609
Email
bin.wu@shlschem.com
Country
China
ProdList
9816
Advantage
59
Shanghai Hanhong Scientific Co.,Ltd.
Tel
021-54306202 13764082696;
Email
info@hanhongsci.com
Country
China
ProdList
42982
Advantage
64
Beijing HuaMeiHuLiBiological Chemical
Tel
010-56205725
Fax
010-65763397
Email
waley188@sohu.com
Country
China
ProdList
12338
Advantage
58
More
Less

View Lastest Price from (1R,2S,5R)-(-)-MENTHYL (S)-P-TOLUENESULFINATE manufacturers

Career Henan Chemical Co
Product
(1R,2S,5R)-(-)-MENTHYL (S)-P-TOLUENESULFINATE 1517-82-4
Price
US $2.00/KG
Min. Order
1g
Purity
98%min
Supply Ability
ask
Release date
2020-01-08
Career Henan Chemical Co
Product
(1R,2S,5R)-(-)-MENTHYL (S)-P-TOLUENESULFINATE (1R,2S,5R)-(-)-MENTHYL (S)-P-TOLUENESULFINATE
Price
US $1.00/g
Min. Order
100g
Purity
99%
Supply Ability
G/KG/T
Release date
2019-12-20

1517-82-4, (1R,2S,5R)-(-)-MENTHYL (S)-P-TOLUENESULFINATERelated Search:


  • (S)-(-)-Menthyl p-toluenesulfinate, (-)-(1R)-Menthyl (S)-p-toluenesulfinate
  • 4-Methylbenzenesulfinic acid (1R)-2α-isopropyl-5β-methylcyclohexane-1β-yl ester
  • 4-Methylbenzenesulfinic acid (1R,3R,4S)-p-menthane-3-yl ester
  • p-Toluenesulfinic acid (1R,1β)-2α-isopropyl-5β-methylcyclohexyl ester
  • p-Toluenesulfinic acid (1R,2S,5R)-2-isopropyl-5-methylcyclohexyl ester
  • p-Toluenesulfinic acid (1R,3R,4S)-menthyl ester
  • p-Toluenesulfinic acid (1R,3R,4S)-p-menthane-3-yl ester
  • (1R,2S,5R)-(-)-Menthyl (S)-p-toluenesulfinate,98%
  • [S(S)]-4-Methylbenzenesulfinic acid (1R,2S,5R)-5-methyl-2-(1-methylethyl)cyclohexyl ester
  • Menthyl (S)-4-methylbenzenesulfinate
  • (S)-((1R,2S,5R)-2-isopropyl-5-Methylcyclohexyl) 4-Methylbenzenesulfinate
  • (-)-Menthyl (S)-4-methylbenzenesulfinate
  • (1S)-2-Isopropyl-5-methylcyclohexyl 4-methylbenzenesulfinate
  • (1R,2S,5R)-(-)-MENTHYL (S)-P-TOLUENESULFITE
  • (-)-(1R)-MENTHYL (S)-TOLUENE-4-SULFINATE
  • (1R,2S,5R)-(-)-MENTHYL (S)-P-TOLUENESULFINATE
  • (1R,2S,5R)-MENTHYL (S)-P-TOLUENESULFINATE
  • (S)-(-)-MENTHYL P-TOLUENESULFINATE
  • (S)-(-)-P-TOLUENESULFINIC ACID L-MENTHYL ESTER
  • (?-(1R)-Menthyl (S)-p-toluenesulfinate
  • menthyl p-toluenesulfinate
  • 4-Methylbenzenesulfinic acid (1R,3R,4S)-p-menthane-3-
  • (1R,2S,5R)-(-)-Menthyl(S)-p-Toluenesulfinate&gt
  • (1R,2S,5R)-(-)-MenthyL
  • (S)-p-toL
  • Benzenesulfinic acid, 4-methyl-, (1R,2S,5R)-5-methyl-2-(1-methylethyl)cyclohexyl ester, [S(S)]-
  • (-)-(1R)-Menthyl (S)-toluene-4-sulfinate
  • 1517-82-4
  • Organic Building Blocks
  • Sulfonates/Sulfinates
  • Chiral Building Blocks
  • Terpenes
  • Monocyclic Monoterpenes
  • Asymmetric Synthesis
  • Chiral Building Blocks
  • Organic Building Blocks
  • Sulfonates/Sulfinates
  • chiral
  • Asymmetric Synthesis
  • Biochemistry
  • Monocyclic Monoterpenes
  • Synthetic Organic Chemistry
  • Terpenes