ChemicalBook > CAS DataBase List > (1R,2S,5R)-(-)-MENTHYL (S)-P-TOLUENESULFINATE

(1R,2S,5R)-(-)-MENTHYL (S)-P-TOLUENESULFINATE

Product Name
(1R,2S,5R)-(-)-MENTHYL (S)-P-TOLUENESULFINATE
CAS No.
1517-82-4
Chemical Name
(1R,2S,5R)-(-)-MENTHYL (S)-P-TOLUENESULFINATE
Synonyms
(S)-p-toL;(1R,2S,5R)-(-)-MenthyL;menthyl p-toluenesulfinate;(S)-(-)-MENTHYL P-TOLUENESULFINATE;Menthyl (S)-4-methylbenzenesulfinate;(?-(1R)-Menthyl (S)-p-toluenesulfinate;(-)-Menthyl (S)-4-methylbenzenesulfinate;(-)-(1R)-MENTHYL (S)-TOLUENE-4-SULFINATE;(-)-(1R)-Menthyl (S)-toluene-4-sulfinate;(1R,2S,5R)-MENTHYL (S)-P-TOLUENESULFINATE
CBNumber
CB6129035
Molecular Formula
C17H26O2S
Formula Weight
294.45
MOL File
1517-82-4.mol
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(1R,2S,5R)-(-)-MENTHYL (S)-P-TOLUENESULFINATE Property

Melting point:
99-104 °C
Boiling point:
402.3±38.0 °C(Predicted)
Density 
1.08
refractive index 
-199 ° (C=1.5, Acetone)
storage temp. 
-20°C
solubility 
Acetone (Slightly), Chloroform (Slightly)
form 
Solution
color 
Yellow to brown or gray
optical activity
[α]20/D 195°, c = 2 in acetone
BRN 
3207468
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Safety

Safety Statements 
22-24/25
WGK Germany 
3
HS Code 
29309090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
278750
Product name
(1R,2S,5R)-(?)-Menthyl (S)-p-toluenesulfinate
Purity
98%
Packaging
10g
Price
$182
Updated
2023/06/20
TCI Chemical
Product number
M1044
Product name
(1R,2S,5R)-(-)-Menthyl (S)-p-Toluenesulfinate
Purity
>98.0%(HPLC)
Packaging
5g
Price
$115
Updated
2024/03/01
TCI Chemical
Product number
M1044
Product name
(1R,2S,5R)-(-)-Menthyl (S)-p-Toluenesulfinate
Purity
>98.0%(HPLC)
Packaging
25g
Price
$390
Updated
2024/03/01
TRC
Product number
M220400
Product name
(1R,2S,5R)-(?)-Menthyl (S)-p-toluenesulfinate
Packaging
2.5g
Price
$70
Updated
2021/12/16
ChemScene
Product number
CS-M1307
Product name
(S)-((1R,2S,5R)-2-isopropyl-5-methylcyclohexyl)4-methylbenzenesulfinate
Packaging
5g
Price
$75
Updated
2021/12/16
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(1R,2S,5R)-(-)-MENTHYL (S)-P-TOLUENESULFINATE Chemical Properties,Usage,Production

Chemical Properties

White crystalline powder

Uses

(1R,2S,5R)-(-)-Menthyl (S)-p-Toluenesulfinate is a reactant used in the synthesis of sulfoxide pincer complexes of Mg, Rh and Ir.

Uses

(1R,2S,5R)-(-)-Menthyl (S)-p-toluenesulfinate can react with:

  • metal ketimines to form enantiopure sulfinimines
  • p-(methylthio)benzaldehyde to form (S)-(-)-N-(4-methylthiobenzylidene)-p-toluenesulfinimine

General Description

(1R,2S,5R)-(-)-Menthyl (S)-p-toluenesulfinate is mainly used for the introduction of p-toluenesulfinyl group in asymmetric synthesis.

(1R,2S,5R)-(-)-MENTHYL (S)-P-TOLUENESULFINATE Preparation Products And Raw materials

Raw materials

Preparation Products

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(1R,2S,5R)-(-)-MENTHYL (S)-P-TOLUENESULFINATE Suppliers

Americas 1 Belgium 2 China 97 Europe 1 France 1 Germany 3 India 4 Japan 2 Switzerland 1 The Netherlands 1 United Kingdom 4 United States 21 Global 138
TOKYO CHEMICAL INDUSTRY CO., LTD.
Tel
03-36680489
Fax
03-3668-0520
Email
Sales-JP@TCIchemicals.com
Country
Japan
ProdList
28387
Advantage
80
TCI Japan
Tel
--
Fax
--
Email
@TCIchemicals.com
Country
Japan
ProdList
2741
Advantage
58
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View Lastest Price from (1R,2S,5R)-(-)-MENTHYL (S)-P-TOLUENESULFINATE manufacturers

Career Henan Chemical Co
Product
(1R,2S,5R)-(-)-MENTHYL (S)-P-TOLUENESULFINATE 1517-82-4
Price
US $2.00/KG
Min. Order
1g
Purity
98%min
Supply Ability
ask
Release date
2020-01-08
Career Henan Chemical Co
Product
(1R,2S,5R)-(-)-MENTHYL (S)-P-TOLUENESULFINATE (1R,2S,5R)-(-)-MENTHYL (S)-P-TOLUENESULFINATE
Price
US $1.00/g
Min. Order
100g
Purity
99%
Supply Ability
G/KG/T
Release date
2019-12-20

1517-82-4, (1R,2S,5R)-(-)-MENTHYL (S)-P-TOLUENESULFINATERelated Search:

p-Toluenesulfonic acid P-TOLUENESULFINIC ACID (1S,2R,5S)-MENTHYL (R)-P-TOLUENESULFINATE,(1S,2R,5S)-(+)-MENTHYL (R)-P-TOLUENESULFINATE,(+)-(1S)-Menthyl (R)-p-toluenesulfinate DL-Menthol 2,5-DIMETHYLCYCLOHEXANOL 3,7-DIMETHYL-1-OCTANOL METHYL P-TOLUENESULFINATE (1R,2S,5R)-(-)-MENTHYL (S)-P-TOLUENESULFINATE 2-Methylcyclohexanol (+)-MENTHOL DL-Menthol 2-ETHYLCYCLOHEXANOL

  • (S)-(-)-Menthyl p-toluenesulfinate, (-)-(1R)-Menthyl (S)-p-toluenesulfinate
  • 4-Methylbenzenesulfinic acid (1R)-2α-isopropyl-5β-methylcyclohexane-1β-yl ester
  • 4-Methylbenzenesulfinic acid (1R,3R,4S)-p-menthane-3-yl ester
  • p-Toluenesulfinic acid (1R,1β)-2α-isopropyl-5β-methylcyclohexyl ester
  • p-Toluenesulfinic acid (1R,2S,5R)-2-isopropyl-5-methylcyclohexyl ester
  • p-Toluenesulfinic acid (1R,3R,4S)-menthyl ester
  • p-Toluenesulfinic acid (1R,3R,4S)-p-menthane-3-yl ester
  • (1R,2S,5R)-(-)-Menthyl (S)-p-toluenesulfinate,98%
  • [S(S)]-4-Methylbenzenesulfinic acid (1R,2S,5R)-5-methyl-2-(1-methylethyl)cyclohexyl ester
  • Menthyl (S)-4-methylbenzenesulfinate
  • (S)-((1R,2S,5R)-2-isopropyl-5-Methylcyclohexyl) 4-Methylbenzenesulfinate
  • (-)-Menthyl (S)-4-methylbenzenesulfinate
  • (1S)-2-Isopropyl-5-methylcyclohexyl 4-methylbenzenesulfinate
  • (1R,2S,5R)-(-)-MENTHYL (S)-P-TOLUENESULFITE
  • (-)-(1R)-MENTHYL (S)-TOLUENE-4-SULFINATE
  • (1R,2S,5R)-(-)-MENTHYL (S)-P-TOLUENESULFINATE
  • (1R,2S,5R)-MENTHYL (S)-P-TOLUENESULFINATE
  • (S)-(-)-MENTHYL P-TOLUENESULFINATE
  • (S)-(-)-P-TOLUENESULFINIC ACID L-MENTHYL ESTER
  • (?-(1R)-Menthyl (S)-p-toluenesulfinate
  • menthyl p-toluenesulfinate
  • 4-Methylbenzenesulfinic acid (1R,3R,4S)-p-menthane-3-
  • (1R,2S,5R)-(-)-Menthyl(S)-p-Toluenesulfinate&gt
  • (1R,2S,5R)-(-)-MenthyL
  • (S)-p-toL
  • Benzenesulfinic acid, 4-methyl-, (1R,2S,5R)-5-methyl-2-(1-methylethyl)cyclohexyl ester, [S(S)]-
  • (-)-(1R)-Menthyl (S)-toluene-4-sulfinate
  • 1517-82-4
  • Organic Building Blocks
  • Sulfonates/Sulfinates
  • Chiral Building Blocks
  • Terpenes
  • Monocyclic Monoterpenes
  • Asymmetric Synthesis
  • Chiral Building Blocks
  • Organic Building Blocks
  • Sulfonates/Sulfinates
  • chiral
  • Asymmetric Synthesis
  • Biochemistry
  • Monocyclic Monoterpenes
  • Synthetic Organic Chemistry
  • Terpenes