(1R,2S,5R)-(-)-MENTHYL (S)-P-TOLUENESULFINATE

Product Name: (1R,2S,5R)-(-)-MENTHYL (S)-P-TOLUENESULFINATE
CAS No.: 1517-82-4
Chemical Name: (1R,2S,5R)-(-)-MENTHYL (S)-P-TOLUENESULFINATE
Synonyms: (S)-p-toL;(1R,2S,5R)-(-)-MenthyL;menthyl p-toluenesulfinate;(S)-(-)-MENTHYL P-TOLUENESULFINATE;Menthyl (S)-4-methylbenzenesulfinate;(?-(1R)-Menthyl (S)-p-toluenesulfinate;(-)-Menthyl (S)-4-methylbenzenesulfinate;(-)-(1R)-MENTHYL (S)-TOLUENE-4-SULFINATE;(-)-(1R)-Menthyl (S)-toluene-4-sulfinate;(1R,2S,5R)-MENTHYL (S)-P-TOLUENESULFINATE
CBNumber: CB6129035
Molecular Formula: C17H26O2S
Formula Weight: 294.45
MOL File: 1517-82-4.mol

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(1R,2S,5R)-(-)-MENTHYL (S)-P-TOLUENESULFINATE Property

Melting point:: 99-104 °C
Boiling point:: 402.3±38.0 °C(Predicted)
Density: 1.08
refractive index: -199 ° (C=1.5, Acetone)
storage temp.: -20°C
solubility: Acetone (Slightly), Chloroform (Slightly)
form: Solution
color: Yellow to brown or gray
optical activity: [α]20/D 195°, c = 2 in acetone
BRN: 3207468

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Safety

Safety Statements: 22-24/25
WGK Germany: 3
HS Code: 29309090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 278750
Product name: (1R,2S,5R)-(?)-Menthyl (S)-p-toluenesulfinate
Purity: 98%
Packaging: 10g
Price: $182
Updated: 2023/06/20

TCI Chemical

Product number: M1044
Product name: (1R,2S,5R)-(-)-Menthyl (S)-p-Toluenesulfinate
Purity: >98.0%(HPLC)
Packaging: 5g
Price: $115
Updated: 2024/03/01

TCI Chemical

Product number: M1044
Product name: (1R,2S,5R)-(-)-Menthyl (S)-p-Toluenesulfinate
Purity: >98.0%(HPLC)
Packaging: 25g
Price: $390
Updated: 2024/03/01

TRC

Product number: M220400
Product name: (1R,2S,5R)-(?)-Menthyl (S)-p-toluenesulfinate
Packaging: 2.5g
Price: $70
Updated: 2021/12/16

ChemScene

Product number: CS-M1307
Product name: (S)-((1R,2S,5R)-2-isopropyl-5-methylcyclohexyl)4-methylbenzenesulfinate
Packaging: 5g
Price: $75
Updated: 2021/12/16

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(1R,2S,5R)-(-)-MENTHYL (S)-P-TOLUENESULFINATE Chemical Properties,Usage,Production

Chemical Properties

White crystalline powder

Uses

(1R,2S,5R)-(-)-Menthyl (S)-p-Toluenesulfinate is a reactant used in the synthesis of sulfoxide pincer complexes of Mg, Rh and Ir.

Uses

(1R,2S,5R)-(-)-Menthyl (S)-p-toluenesulfinate can react with:

metal ketimines to form enantiopure sulfinimines
p-(methylthio)benzaldehyde to form (S)-(-)-N-(4-methylthiobenzylidene)-p-toluenesulfinimine

General Description

(1R,2S,5R)-(-)-Menthyl (S)-p-toluenesulfinate is mainly used for the introduction of p-toluenesulfinyl group in asymmetric synthesis.

(1R,2S,5R)-(-)-MENTHYL (S)-P-TOLUENESULFINATE Preparation Products And Raw materials

Raw materials

Preparation Products

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(1R,2S,5R)-(-)-MENTHYL (S)-P-TOLUENESULFINATE Suppliers

Americas 1 Belgium 2 China 97 Europe 1 France 1 Germany 3 India 4 Japan 2 Switzerland 1 The Netherlands 1 United Kingdom 4 United States 21 Global 138

J & K SCIENTIFIC LTD.

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View Lastest Price from (1R,2S,5R)-(-)-MENTHYL (S)-P-TOLUENESULFINATE manufacturers

Career Henan Chemical Co

Product: (1R,2S,5R)-(-)-MENTHYL (S)-P-TOLUENESULFINATE 1517-82-4
Price: US $2.00/KG
Min. Order: 1g
Purity: 98%min
Supply Ability: ask
Release date: 2020-01-08

Career Henan Chemical Co

Product: (1R,2S,5R)-(-)-MENTHYL (S)-P-TOLUENESULFINATE (1R,2S,5R)-(-)-MENTHYL (S)-P-TOLUENESULFINATE
Price: US $1.00/g
Min. Order: 100g
Purity: 99%
Supply Ability: G/KG/T
Release date: 2019-12-20

1517-82-4, (1R,2S,5R)-(-)-MENTHYL (S)-P-TOLUENESULFINATERelated Search:

p-Toluenesulfonic acid P-TOLUENESULFINIC ACID (1S,2R,5S)-MENTHYL (R)-P-TOLUENESULFINATE,(1S,2R,5S)-(+)-MENTHYL (R)-P-TOLUENESULFINATE,(+)-(1S)-Menthyl (R)-p-toluenesulfinate DL-Menthol 2,5-DIMETHYLCYCLOHEXANOL 3,7-DIMETHYL-1-OCTANOL METHYL P-TOLUENESULFINATE (1R,2S,5R)-(-)-MENTHYL (S)-P-TOLUENESULFINATE 2-Methylcyclohexanol (+)-MENTHOL DL-Menthol 2-ETHYLCYCLOHEXANOL

(S)-(-)-Menthyl p-toluenesulfinate, (-)-(1R)-Menthyl (S)-p-toluenesulfinate

4-Methylbenzenesulfinic acid (1R)-2α-isopropyl-5β-methylcyclohexane-1β-yl ester

4-Methylbenzenesulfinic acid (1R,3R,4S)-p-menthane-3-yl ester

p-Toluenesulfinic acid (1R,1β)-2α-isopropyl-5β-methylcyclohexyl ester

p-Toluenesulfinic acid (1R,2S,5R)-2-isopropyl-5-methylcyclohexyl ester

p-Toluenesulfinic acid (1R,3R,4S)-menthyl ester

p-Toluenesulfinic acid (1R,3R,4S)-p-menthane-3-yl ester

(1R,2S,5R)-(-)-Menthyl (S)-p-toluenesulfinate,98%

[S(S)]-4-Methylbenzenesulfinic acid (1R,2S,5R)-5-methyl-2-(1-methylethyl)cyclohexyl ester

Menthyl (S)-4-methylbenzenesulfinate

(S)-((1R,2S,5R)-2-isopropyl-5-Methylcyclohexyl) 4-Methylbenzenesulfinate

(-)-Menthyl (S)-4-methylbenzenesulfinate

(1S)-2-Isopropyl-5-methylcyclohexyl 4-methylbenzenesulfinate

(1R,2S,5R)-(-)-MENTHYL (S)-P-TOLUENESULFITE

(-)-(1R)-MENTHYL (S)-TOLUENE-4-SULFINATE

(1R,2S,5R)-(-)-MENTHYL (S)-P-TOLUENESULFINATE

(1R,2S,5R)-MENTHYL (S)-P-TOLUENESULFINATE

(S)-(-)-MENTHYL P-TOLUENESULFINATE

(S)-(-)-P-TOLUENESULFINIC ACID L-MENTHYL ESTER

(?-(1R)-Menthyl (S)-p-toluenesulfinate

menthyl p-toluenesulfinate

4-Methylbenzenesulfinic acid (1R,3R,4S)-p-menthane-3-

(1R,2S,5R)-(-)-Menthyl(S)-p-Toluenesulfinate&gt

(1R,2S,5R)-(-)-MenthyL

(S)-p-toL

Benzenesulfinic acid, 4-methyl-, (1R,2S,5R)-5-methyl-2-(1-methylethyl)cyclohexyl ester, [S(S)]-

(-)-(1R)-Menthyl (S)-toluene-4-sulfinate

1517-82-4

Organic Building Blocks

Sulfonates/Sulfinates

Chiral Building Blocks

Terpenes

Monocyclic Monoterpenes

Asymmetric Synthesis

Chiral Building Blocks

Organic Building Blocks

Sulfonates/Sulfinates

chiral

Asymmetric Synthesis

Biochemistry

Monocyclic Monoterpenes

Synthetic Organic Chemistry

Terpenes