1-Butyl-3-methylimidazolium chloride
- Product Name
- 1-Butyl-3-methylimidazolium chloride
- CAS No.
- 79917-90-1
- Chemical Name
- 1-Butyl-3-methylimidazolium chloride
- Synonyms
- BMIMCL;1-N-BUTYL-3-METHYLIMIDAZOLIUM CHLORIDE;1-Butyl-3-MethyliMidazoliuM chloride 25GR;1-Butyl-3-MethyliMidazoliuM Chloride [BMiM]Cl;SKL1349;SKL1501;JACS-79917-90-1;Basionics? ST 70;BASIONIC(TM) ST 70;BASIONIC(R) ST 70, BMIMCL
- CBNumber
- CB5114025
- Molecular Formula
- C8H15ClN2
- Formula Weight
- 174.67
- MOL File
- 79917-90-1.mol
1-Butyl-3-methylimidazolium chloride Property
- Melting point:
- ~70 °C
- Density
- d25 1.08 (dried)
- Flash point:
- 192 °C
- storage temp.
- Inert atmosphere,Room Temperature
- solubility
- DMSO (Slightly), Methanol (Sparingly)
- form
- Mass
- color
- Cream to yellow
- Water Solubility
- Soluble in acetone, acetonitrile, hot ethyl acetate, isopropyl alcohol, methylene chloride and methanol. Insoluble in water, hexane and toluene,
- Sensitive
- Hygroscopic
- BRN
- 6449277
- Stability:
- hygroscopic
- InChI
- InChI=1S/C8H15N2.ClH/c1-3-4-5-10-7-6-9(2)8-10;/h6-8H,3-5H2,1-2H3;1H/q+1;/p-1
- InChIKey
- FHDQNOXQSTVAIC-UHFFFAOYSA-M
- SMILES
- N1(CCCC)C=C[N+](C)=C1.[Cl-]
- CAS DataBase Reference
- 79917-90-1(CAS DataBase Reference)
- EPA Substance Registry System
- 1H-Imidazolium, 3-butyl-1-methyl-, chloride (1:1) (79917-90-1)
Safety
- Hazard Codes
- T,N
- Risk Statements
- 25-36/37/38-51/53-36/38
- Safety Statements
- 26-45-61-22
- RIDADR
- UN 2811 6.1/PG 3
- WGK Germany
- 3
- F
- 3-10-21
- HazardClass
- 6.1
- PackingGroup
- III
- HS Code
- 29332900
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H301Toxic if swalloed
H315Causes skin irritation
H319Causes serious eye irritation
H411Toxic to aquatic life with long lasting effects
- Precautionary statements
-
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P270Do not eat, drink or smoke when using this product.
P273Avoid release to the environment.
P301+P310IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- 04129
- Product name
- 1-Butyl-3-methylimidazolium chloride
- Purity
- ≥99.0% (HPLC)
- Packaging
- 5G-F
- Price
- $74.2
- Updated
- 2024/03/01
- Product number
- 04129
- Product name
- 1-Butyl-3-methylimidazolium chloride
- Purity
- ≥99.0% (HPLC)
- Packaging
- 25G-F
- Price
- $353
- Updated
- 2024/03/01
- Product number
- 900856
- Product name
- 1-Butyl-3-methylimidazolium chloride
- Purity
- ≥99%
- Packaging
- 25G
- Price
- $552
- Updated
- 2023/06/20
- Product number
- 04129
- Product name
- 1-Butyl-3-methylimidazolium chloride
- Purity
- ≥99.0% (HPLC)
- Packaging
- 5G
- Price
- $71.3
- Updated
- 2023/01/07
- Product number
- 04129
- Product name
- 1-Butyl-3-methylimidazolium chloride
- Purity
- ≥99.0% (HPLC)
- Packaging
- 25g
- Price
- $339
- Updated
- 2023/01/07
1-Butyl-3-methylimidazolium chloride Chemical Properties,Usage,Production
Description
1-butyl-3-methylimidazolium chloride is a highly efficient direct solvent for the dissolution and regeneration of cellulose. During the precipitation of the regenerated cellulose, large volumes of dilute IL aqueous solutions are produced. This compound, an imidazolium-based ionic liquid, is considered the representative emerging persistent aquatic pollutant, and its environmental toxicity has attracted growing concern[1].
Chemical Properties
cream-colored to yellow mass
Uses
1-Butyl-3-methylimidazolium chloride can be used as a precursor for the preparation of other ionic liquids by anion metathesis.
Uses
1-Butyl-3-methylimidazolium chloride in combination with aluminium chloride forms an organoaluminate molten salt, which can act as an acidic catalyst for the alkylation of isobutane with 2-butene.
General Description
1-Butyl-3-methylimidazolium chloride is an imidazolium based ionic liquid.
Synthesis
1-Butyl-3-methylimidazolium chloride (BMImCl) was prepared according to a procedure available in the literature [26]. A solution of 1-chlorobutane (108 mmol) and 1-methylimidazole (108 mmol) in acetonitrile (60 mL) was refluxed for 48 h under inert atmosphere (Ar). Once cooled to room temperature, two layers were observed. The upper layer was removed, and the lower one was extracted with ethyl acetate three times to remove unreacted starting materials. The remaining solvent from the ionic liquid was removed via a rotary evaporator, and the product was dried under a high vacuum at 50 °C for 24 h. BMImCl: 1H NMR (300 MHz, CD3CN) δ (ppm): 0.91 (t, J = 7.3 Hz, 3H), 1.26–1.36 (m, 2H), 1.76–1.86 (m, 2H), 3.90 (s, 3H), 4.22 (t, J = 7.2 Hz, 2H), 7.51 (m, 1H), 7.54 (m, 1H), 9.77 (s, 1H).
References
[1] Qi Lu and Dongbo Wang*. “1-Butyl-3-methylimidazolium Chloride Affects Anaerobic Digestion through Altering Organics Transformation, Cell Viability, and Microbial Community.” 环境科学与技术 57 8 (2023): 3145–3155.
[2] Brunetti, B. et al. “Evaporation/Decomposition Behavior of 1-Butyl-3-Methylimidazolium Chloride (BMImCL) Investigated through Effusion and Thermal Analysis Techniques.” 2023. 0.
1-Butyl-3-methylimidazolium chloride Preparation Products And Raw materials
Raw materials
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View Lastest Price from 1-Butyl-3-methylimidazolium chloride manufacturers
- Product
- 1-Butyl-3-methylimidazolium chloride 79917-90-1
- Price
- US $45.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- 20 tons
- Release date
- 2024-12-23
- Product
- 1-Butyl-3-methylimidazolium chloride 79917-90-1
- Price
- US $6.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- 2000KG/Month
- Release date
- 2024-08-08
- Product
- 1-Butyl-3-methylimidazolium chloride 79917-90-1
- Price
- US $0.00/KG
- Min. Order
- 1KG
- Purity
- 98.0%
- Supply Ability
- 500kg/month
- Release date
- 2023-01-10