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NITROCYCLOHEXANE

Product Name
NITROCYCLOHEXANE
CAS No.
1122-60-7
Chemical Name
NITROCYCLOHEXANE
Synonyms
NSC66277;NSC 66277;NSC-66277;ai3-14828[qr];NITROCYCLOHEXANE;nitro-cyclohexan;1-Nitrocyclohexane;Cyclohexane, nitro-;Nitrocyclohexane>HEXAHYDRONITROBENZENE
CBNumber
CB5116443
Molecular Formula
C6H11NO2
Formula Weight
129.16
MOL File
1122-60-7.mol
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NITROCYCLOHEXANE Property

Melting point:
−34 °C(lit.)
Boiling point:
205.5-206 °C768 mm Hg(lit.)
Density 
1.061 g/mL at 25 °C(lit.)
vapor density 
4.46 (vs air)
vapor pressure 
768 mm Hg ( 205 °C)
refractive index 
n20/D 1.462(lit.)
Flash point:
166 °F
solubility 
soluble in Alcohol
form 
clear liquid
pka
8.44±0.20(Predicted)
color 
Light orange to Yellow to Green
EPA Substance Registry System
Nitrocyclohexane (1122-60-7)
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Safety

Hazard Codes 
T
Risk Statements 
23/24/25-36/37/38
Safety Statements 
26-36/37/39-45
RIDADR 
UN 3382 6.1/PG 1
WGK Germany 
3
RTECS 
GV6600000
HazardClass 
6.1(b)
PackingGroup 
III
HS Code 
29049090
Hazardous Substances Data
1122-60-7(Hazardous Substances Data)
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P310IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
N16606
Product name
Nitrocyclohexane
Purity
97%
Packaging
5g
Price
$368
Updated
2023/01/07
TCI Chemical
Product number
N0187
Product name
Nitrocyclohexane
Purity
>95.0%(GC)
Packaging
5g
Price
$116
Updated
2024/03/01
TCI Chemical
Product number
N0187
Product name
Nitrocyclohexane
Purity
>95.0%(GC)
Packaging
25g
Price
$412
Updated
2024/03/01
American Custom Chemicals Corporation
Product number
CHM0156851
Product name
NITROCYCLOHEXANE
Purity
95.00%
Packaging
5G
Price
$885.55
Updated
2021/12/16
AHH
Product number
MT-19813
Product name
Nitrocyclohexane
Purity
97%
Packaging
250g
Price
$998
Updated
2021/12/16
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NITROCYCLOHEXANE Chemical Properties,Usage,Production

Chemical Properties

Colorless to dark yellow liquid

Chemical Properties

Nitrocyclohexane is a highly flammable, colorless liquid.

Definition

ChEBI: A C-nitro compound that is cyclohexane in which a single hydrogen is replaced by a nitro group.

Synthesis Reference(s)

Journal of the American Chemical Society, 75, p. 4047, 1953 DOI: 10.1021/ja01112a049
Tetrahedron, 46, p. 7443, 1990 DOI: 10.1016/S0040-4020(01)89059-1
Tetrahedron Letters, 21, p. 1117, 1980 DOI: 10.1016/S0040-4039(01)83928-9

General Description

Colorless liquid.

Air & Water Reactions

Highly Flammable

Reactivity Profile

Nitroalkanes, such as NITROCYCLOHEXANE, range from slight to strong oxidizing agents. If mixed with reducing agents, including hydrides, sulfides and nitrides, they may begin a vigorous reaction that culminates in a detonation. Nitroalkanes are milder oxidizing agents, but still react violently with reducing agents at higher temperature and pressures. Nitroalkanes react with inorganic bases to form explosive salts. The presence of metal oxides increases the thermal sensitivity of nitroalkanes. Nitroalkanes with more than one nitro group are generally explosive. Nitroalkanes are insoluble in water. Flammable/combustible material. May be ignited by heat, sparks or flames.

Potential Exposure

Used in organic synthesis.

Shipping

UN3382 Toxic by inhalation liquid, n.o.s. with an LC50 lower than or equal to 1000 ml/m3 and saturated vapor concentration ≥10 LC50, Hazard Class: 6.1; Labels: 6.1 Technical Name Required, Inhalation Hazard Zone B.

Incompatibilities

A nitro compound; a fire and explosive hazard. May form explosive mixture with air. Nitrocyclohexane, a nitroalkane, is a strong oxidizing agents. If mixed with reducing agents, including hydrides, sulfides and nitrides, they may begin a vigorous reaction that culminates in a detonation. Nitroalkanes are milder oxidizing agents, but still react violently with reducing agents at higher temperature and pressures. Nitroalkanes react with inorganic bases to form explosive salts. The presence of metal oxides increases the thermal sensitivity of nitroalkanes. Nitroalkanes with more than one nitro group are generally explosive. Incompatible with alkalis, and metal oxides. This chemical is highly reactive and may be heat-and shock-sensitive.

Waste Disposal

Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. All federal, state, and local environmental regulations must be observed.

NITROCYCLOHEXANE Preparation Products And Raw materials

Raw materials

3-Chloroperoxybenzoic acid 1,2-Dichloroethane Cyclohexylamine

Preparation Products

3-Amino-2-azepanone Cyclohexylamine
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NITROCYCLOHEXANE Suppliers

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J & K SCIENTIFIC LTD.
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View Lastest Price from NITROCYCLOHEXANE manufacturers

Career Henan Chemical Co
Product
NITROCYCLOHEXANE 1122-60-7
Price
US $1.00/KG
Min. Order
1KG
Purity
99%HPLC
Supply Ability
100KG
Release date
2020-02-01

1122-60-7, NITROCYCLOHEXANERelated Search:

nitro cyclobutane NITROCYCLOHEXANE 1,3-DINITROADAMANTANE 1-NITROADAMANTANE 2-NITROCYCLOHEXANONE CHEMBRDG-BB 5345383 PENTACHLORONITROBENZENE-13C6 2,3,5,6-TETRAHYDROXY-1,4-DINITROCYCLOHEXANE DIHYDRATE 1-Bromo-1-nitrocyclohexane 1-Chloro-1-nitrocyclohexane 1β-(Benzyloxy)-2β-nitrocyclohexane AKOS 91977 AKOS BB-9510 SPECS AN-907/25060008 METHYL 6-NITROBICYCLO[3.1.0]HEXANE-6-CARBOXYLATE 4-NITROTOLUENE-13C6 AKOS 92093 1-AMINO-2-NITROCYCLOHEXANECARBOXYLIC ACID

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