(R)-SEGPHOS

Reactions

Product Name: (R)-SEGPHOS
CAS No.: 244261-66-3
Chemical Name: (R)-SEGPHOS
Synonyms: (R)-SEGPHOS(R);(R)-(+)-SEGPHOS;(R)-SEGPHOS(R) >=94%;(R)-(+)-SEGPHOS(regR);(R)-(+)-SEGPHOS(R)-(+)-SEGPHOS;(R)-(+)-SEGPHOS®4,4'-Bi-1,3-benzodioxole-5,5'-diylbis(diphenylphosphine);(R)-5,5'-Bis(diphenylphosphino)-4,4'-bibenzo[d][1,3]dioxole;(R)-5,5'-Bis(diphenylphosphino)-4,4'-bibenzo[d][1,3]dioxole;(R)-(+)-5,5'-Bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole
CBNumber: CB51180982
Molecular Formula: C38H28O4P2
Formula Weight: 610.59
MOL File: 244261-66-3.mol

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(R)-SEGPHOS Property

Melting point:: 168-172 °C
Boiling point:: 715.4±60.0 °C(Predicted)
storage temp.: Inert atmosphere,Room Temperature
form: Powder
color: off-white
optical activity: [α]20/D +11°, c = 0.5 in chloroform

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Safety

WGK Germany: 3
HS Code: 2932.99.7000

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 692395
Product name: (R)-SEGPHOS?
Purity: ≥94%
Packaging: 100mg
Price: $27.06
Updated: 2024/03/01

TCI Chemical

Product number: S0930
Product name: (R)-(+)-SEGPHOS[R]
Purity: >99.0%(HPLC)
Packaging: 200mg
Price: $56
Updated: 2024/03/01

TCI Chemical

Product number: S0930
Product name: (R)-(+)-SEGPHOS[R]
Purity: >99.0%(HPLC)
Packaging: 1g
Price: $191
Updated: 2024/03/01

Strem Chemicals

Product number: 15-0136
Product name: (R)-(+)-5,5'-Bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole, min. 98% (R)-(+)-SEGPHOS(R)
Packaging: 250mg
Price: $48
Updated: 2024/03/01

Strem Chemicals

Product number: 15-0136
Product name: (R)-(+)-5,5'-Bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole, min. 98% (R)-(+)-SEGPHOS(R)
Packaging: 1g
Price: $142
Updated: 2024/03/01

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(R)-SEGPHOS Chemical Properties,Usage,Production

Reactions

Biaryl bisphosphine ligand with narrow dihedral angle. The SEGPHOS® ligand has been applied to a variety of metal catalyzed reactions. In many cases, yields and enantioselectivities, exceed results obtained earlier using BINAP.
As ruthenium complex, SEGPHOS® generally gives higher levels of chiral induction in asymmetric hydrogenations of α,β,and γ-functionalized ketones.
Used in Rh-catalyzed transformations such as: (a) 1,4-addition of boronic acids to coumarins, (b) addition of titanium reagents to imines,(c) cotrimerization of alkenes and acetylenes,10 (d)double [2+2+2] cycloaddition,11 (e) indanone formation.
Used in Pd-catalyzed transformations such as: (a) cycloaddition of 1,6-enyne,(b) arylative cyclization of allenyl aldehydes with boronic acids,13 (c) synthesis of chromans.
Used in Cu-catalyzed transformations such as: (a) nitroso Diels-Alder,(b) reductive aldol condensation,(c) conjugate reduction of unsaturated sulfones,and phophonates.
Iridium-catalyzed asymmetric hydrogenation of quinolines activated by chloroformates.
Iridium-catalyzed asymmetric transfer hydrogenation used in polyketide construction.
Rhodium-catalyzed asymmetric hydroarylation of 3-pyrrolines.
Palladium-catalyzed regio- and enantioselective dearomatization.

Uses

(R)-(+)-SEGPHOS? is a chelating ligand used to prepare coordination complex catalysts, such as its use in Pd catalysts for the enantioselective addition of diesters to 3,3-difluoropropenes, and in the Ni-based catalyst for the asymmetric propargylic amination of propargylic carbonates with an internal alkyne group.

(R)-SEGPHOS Preparation Products And Raw materials

Raw materials

Preparation Products

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(R)-SEGPHOS Suppliers

China 80 India 2 Japan 2 Switzerland 1 United Kingdom 2 United States 8 Global 95

Henan Kaiyan Biotechnology Co. Ltd.

Tel: 0371-55676069 18137782046
Fax: 0371-55676069
Email: 1821614734@qq.com
Country: China
ProdList: 414
Advantage: 58

Xinxiang Runyu Material Co., Ltd.

Tel: 166-166-37336996 15690792173
Fax: 0373-7759608
Email: chenxi.song@runvmat.com
Country: China
ProdList: 441
Advantage: 55

Zhengzhou Kingorgchem Chemical Technology Co., Ltd.gy Co., Ltd.

Tel: 0371-0371-65511006 18625597674
Email: sales@kingorgchem.com
Country: China
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J & K SCIENTIFIC LTD.

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Fax: 86-10-82849933
Email: jkinfo@jkchemical.com
Country: China
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TCI (Shanghai) Development Co., Ltd.

Tel: 021-67121386
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Email: Sales-CN@TCIchemicals.com
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Energy Chemical

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Accela ChemBio Co.,Ltd.

Tel: 021-50795510 4000665055
Fax: 021-50795055
Email: sales@accelachem.com
Country: China
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Daicel Chiral Technologies (China)CO.,LTD

Tel: 021-50460086-9 15921403865
Fax: +86-21-50462321
Email: han_yajun@dctc.daicel.com
Country: China
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Tianjin heowns Biochemical Technology Co., Ltd.

Tel: 400 638 7771
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View Lastest Price from (R)-SEGPHOS manufacturers

XINXIANG RUNYU MATERIAL CO., LTD.

Product: (R)-(+)-5,5'-Bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole,min.98%(R)-SEGPHOS 244261-66-3
Price: US $0.00-0.00/KG
Min. Order: 1KG
Purity: 0.99
Supply Ability: 500kg
Release date: 2021-11-30

Zhuozhou Wenxi import and Export Co., Ltd

Product: (R)-(+)-5,5"-Bis(diphenylphosphino)-4,4"-bi-1,3-benzodioxole,min.98%(R)-SEGPHOS 244261-66-3
Price: US $15.00-10.00/KG
Min. Order: 1KG
Purity: 99%+ HPLC
Supply Ability: Monthly supply of 1 ton
Release date: 2021-06-27

Career Henan Chemical Co

Product: (R)-(+)-5,5'-Bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole,min.98%(R)-SEGPHOS 244261-66-3
Price: US $1.00-1.00/KG
Min. Order: 1KG
Purity: 98%
Supply Ability: 1lg; 2kg; 5kg; 10kg; 100kg
Release date: 2019-08-31

244261-66-3, (R)-SEGPHOSRelated Search:

(S)-SunPhos (S)-(+)-2,2'-Bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl,min.97% (R)-(+)-TolBINAP (R)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis[bis(3,5-di-tert-butyl-4-methoxypheny R(+)-2 2'-BIS-(DIPHENYLPHOSPHINO)-6 6'-& (S)-(-)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl (S)-(-)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl (R)-(+)-2,2'-Bis(di-i-propylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97% (R)-H8-BINAP (R)-DIFLUORPHOS(TM) (S)-(-)-2,2'-BIS(DI-P-TOLYLPHOSPHINO)-1,1'-BINAPHTHYL (R)-DTBM-SEGPHOS (R)-(+)-5,5'-Bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole,min.98%(R)-DM-SEGPHOS (S)-(-)-5,5'-Bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole,min.98%(S)-DM-SEGPHOS N-[(1R,2R)-1,2-Diphenyl-2-(2-(4-Methylbenzyloxy)ethylaMino)-ethyl]-4-Methylbenzene sulfonaMide(chloro)rutheniuM(II) (R,R)-Ts-DENEB 1333981-84-2 Chloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl} [(2R)-(-)-1-(4-Methoxyphenyl)- 1 (4-Methoxyphenyl-kC)-3- Methyl-1,2-butanediaMine]rutheniuM(II) (R)-RUCY XylBINAP (S)-(-)-5,5'-Bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole,min.98%(S)-SEGPHOS (S)-(+)-5,5'-Bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole,min.98%(S)-DTBM-SEGPHOS

(R)-(+)-5,5'-Bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole,min.98%(R)-SEGPHOS

(R)-(+)-5,5μ-Bis(diphenylphosphino)-4,4μ-bi-1,3-benzodioxole, [4(R)-(4,4μ-bi-1,3-benzodioxole)-5,5μ-diyl]bis[diphenylphosphine]

(R)-SEGPHOS(R)

(R)-(+)-SEGPHOS

Phosphine,1,1'-[(4R)-[4,4'-bi-1,3-benzodioxole]-5,5'-diyl]bis[1,1-diphenyl-

(R)-(+)-5,5'-Bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole,(R)-(+)-SEGPHOS

(R)-(+)-5,5'-Bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole

[(4R)-[4,4'-Bi-1,3-benzodioxole]-5,5'-diyl]bis[diphenylphosphine]

(R)-SEGPHOS(R) >=94%

(R)-(+)-SEGPHOS(regR)

(<i>R</i>)-(+)-SEGPHOS<sup>&reg

(R)-5,5'-Bis(diphenylphosphino)-4,4'-bibenzo[d][1,3]dioxole

(R)-(+)-5,5'-Bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole, min. 98%

(R)-(+)-5,5'-Bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole, min. 98% (R)-(+)-SEGPHOS(R)

1,1'-[(4R)-[4,4'-Bi-1,3-benzodioxole]-5,5'-diyl]bis[1,1-diphenylphosphine]

4,4'-Bi-1,3-benzodioxole-5,5'-diylbis(diphenylphosphine)

(R)-(+)-4,4'-Bis(diphenylphosphino)-3,3'-bi(1,2-methylenedioxybenzene)

(R)-(+)-SEGPHOS(R)-(+)-SEGPHOS

(R)-(+)-5,5'-Bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole,min.98%

(R)-(+)-5,5'-Bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole,min [(R)-Segphos]

(R)-(+)-5,5'-Bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole

(R)-5,5'-Bis(diphenylphosphino)-4,4'-bibenzo[d][1,3]dioxole

244261-66-3

Chiral Phosphine

Segphos Series