ChemicalBook > CAS DataBase List > (S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a
(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a
Reactions- Product Name
- (S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a
- CAS No.
- 185449-81-4
- Chemical Name
- (S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a
- Synonyms
- (S)-MorfPhos;97% (S)-MorfPhos;3,4-a'']dinaphthalen-4-yl)morpholine;3,4-a']dinaphthalen-4-yl)Morpholine (S)-MorfPhos;3,4-a']dinaphthalen-4-yl)morpholine,min.97%(S)-MorfPhos;(S)-4-(Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-yl)morpholine;4-(11bS)-Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-ylmorpholine;(S)-4-(Dinaphtho[2,1-d:1',2'-f][1,3,2]-dioxaphosphepin-4-yl)morpholine;4-(11bS)-Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-ylmorpholine;Morpholine, 4-(11bS)-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-yl-
- CBNumber
- CB51180997
- Molecular Formula
- C24H20NO3P
- Formula Weight
- 401.39
- MOL File
- 185449-81-4.mol
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(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a Property
- Boiling point:
- 613.7±65.0 °C(Predicted)
- storage temp.
- under inert gas (nitrogen or Argon) at 2-8°C
- pka
- -0.88±0.20(Predicted)
- form
- Powder
- color
- white
- Sensitive
- moisture sensitive
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Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H317May cause an allergic skin reaction
H319Causes serious eye irritation
- Precautionary statements
-
P280Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
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N-Bromosuccinimide Price
Strem Chemicals
- Product number
- 15-1235
- Product name
- (S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)morpholine, min. 97% (S)-MorfPhos
- Packaging
- 100mg
- Price
- $41
- Updated
- 2024/03/01
Strem Chemicals
- Product number
- 15-1235
- Product name
- (S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)morpholine, min. 97% (S)-MorfPhos
- Packaging
- 500mg
- Price
- $200
- Updated
- 2024/03/01
American Custom Chemicals Corporation
- Product number
- ING0001357
- Product name
- (S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)MORPHOLINE
- Purity
- 95.00%
- Packaging
- 500MG
- Price
- $814.97
- Updated
- 2021/12/16
AK Scientific
- Product number
- 9700AA
- Product name
- (S)-4-(Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-yl)morpholine
- Packaging
- 250mg
- Price
- $847
- Updated
- 2021/12/16
Matrix Scientific
- Product number
- 095202
- Product name
- (S)-4-(Dinaphtho[2,1-d:1',2'-f][1,3,2]-dioxaphosphepin-4-yl)morpholine
- Purity
- 95+%
- Packaging
- 1g
- Price
- $1311
- Updated
- 2021/12/16
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(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a Chemical Properties,Usage,Production
Reactions
1. Ligand used in the enantioselective rhodium catalyzed low pressure high activity hydrogenation of α–dehydroaminoesters, enamides, and dimethylitaconate.
2. Ligand used in iridinium-catalyzed asymmetric hydrogenation of 2-methylindole.
(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a Preparation Products And Raw materials
Raw materials
Preparation Products
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(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a Suppliers
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185449-81-4, (S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-aRelated Search:
Morpholinazole
(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a
(S)-(-)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl
(S)-(-)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl
(S)-(-)-2,2'-BIS(DI-P-TOLYLPHOSPHINO)-1,1'-BINAPHTHYL
(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a
(R)-MONOPHOS
(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a