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6-Methyl-2-mercaptobenzothiazole

Product Name
6-Methyl-2-mercaptobenzothiazole
CAS No.
2268-79-3
Chemical Name
6-Methyl-2-mercaptobenzothiazole
Synonyms
6-Methyl-2-benzothiazolethiol;2-Mercapto-6-methylbenzothiazole;6-Methylbenzo[d]thiazole-2-thiol;6-Methyl-2-mercaptobenzothiazole;6-Methyl-2(3H)-benzothiazolethione;2(3H)-Benzothiazolethione, 6-methyl-;6-methyl-3H-1,3-benzothiazole-2-thione;2(3H)-Benzothiazolethione,6-methyl-(9CI)
CBNumber
CB51272528
Molecular Formula
C8H7NS2
Formula Weight
181.28
MOL File
2268-79-3.mol
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6-Methyl-2-mercaptobenzothiazole Property

Melting point:
183 °C
Boiling point:
323 °C
Density 
1.39
Flash point:
149 °C
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
pka
9.92±0.20(Predicted)
Appearance
White to off-white Solid
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Safety

HS Code 
2934208090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H317May cause an allergic skin reaction

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

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N-Bromosuccinimide Price

ChemScene
Product number
CS-0061342
Product name
6-Methylbenzo[d]thiazole-2-thiol
Purity
97.93%
Packaging
1g
Price
$122
Updated
2021/12/16
Apolloscientific
Product number
OR958424
Product name
6-Methyl-2-mercaptobenzothiazole
Purity
95%
Packaging
250mg
Price
$140
Updated
2021/12/16
SynQuest Laboratories
Product number
7H70-1-13
Product name
6-Methyl-2,3-dihydro-1,3-benzothiazole-2-thione
Packaging
250mg
Price
$224
Updated
2021/12/16
Apolloscientific
Product number
OR958424
Product name
6-Methyl-2-mercaptobenzothiazole
Purity
95%
Packaging
1g
Price
$335
Updated
2021/12/16
ChemScene
Product number
CS-0061342
Product name
6-Methylbenzo[d]thiazole-2-thiol
Purity
97.93%
Packaging
5g
Price
$370
Updated
2021/12/16
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6-Methyl-2-mercaptobenzothiazole Chemical Properties,Usage,Production

Synthesis

75-15-0

29289-13-2

2268-79-3

2-Iodo-4-methylaniline (2 mmol), carbon disulfide (10 mmol), sodium sulfide (4 mmol), and N,N-dimethylformamide (2 mL) were added to a 50 mL sealed tube at room temperature and protected by argon and sealed by three times of argon displacement. The reaction mixture was stirred electromagnetically at 110 °C for 12 h. The reaction progress was monitored by thin layer chromatography (TLC) on silica gel plates. After completion of the reaction, the mixture was cooled to room temperature, 3 mol/L hydrochloric acid (2 mL) was added and stirred for 30 min. Subsequently, the reaction mixture was extracted with dichloromethane (3 x 20 mL). The organic phases were combined, dried with anhydrous magnesium sulfate and concentrated. The residue was purified by silica gel column chromatography with the eluent being a mixed petroleum ether/ethyl acetate solvent to afford the target product 6-methylbenzo[d]thiazole-2-thiol.

References

[1] Synthetic Communications, 2017, vol. 47, # 20, p. 1916 - 1925
[2] Organic Letters, 2011, vol. 13, # 12, p. 3202 - 3205
[3] Patent: CN104098529, 2016, B. Location in patent: Paragraph 0047-0048

6-Methyl-2-mercaptobenzothiazole Preparation Products And Raw materials

Raw materials

Preparation Products

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6-Methyl-2-mercaptobenzothiazole Suppliers

Beijing Taiya Jie Technology Development Co., Ltd.
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021-33690831-8001 13552411790
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021-33690831
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postmaster@tyjchem.cn
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China
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Nanjing Duolong Bio-tech Co.,Ltd.
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18905173768
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025-83263139
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China
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Shanghai WeiNie Chemical Technology Co., Ltd.
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15902145085
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China
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Shanghai YuanYe Biotechnology Co., Ltd.
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021-61312847; 18021002903
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QQ:3008007432
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3008007409@qq.com
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China
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Grice Rand (Tianjin) Pharmaceutical Co., Ltd.
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022-83705301 13752403750
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China
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BePharm Ltd
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400-685-9117
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021-51816740
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market@bepharm.com
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China
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Shanghai SuperLan Chemcial Technique Centre
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+86-21-51601218
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chaolaichem@foxmail.com
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Amadis Chemical Company Limited
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571-89925085
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0086-571-89925065
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sales@amadischem.com
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Shanghai Qianlai Medical Technology Co., Ltd.
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482109853
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021-37288278
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China
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406
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Shanghai CR Corporation Limited
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13062833949; 4006653949 4006653949
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QQ: 2136646215
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fred.wen@crcorporation.cn
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China
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View Lastest Price from 6-Methyl-2-mercaptobenzothiazole manufacturers

Honest Joy Holdings Limited
Product
6-methyl-3H-1,3-benzothiazole-2-thione 2268-79-3
Price
US $0.00/KG
Min. Order
1KG
Purity
98.7%
Supply Ability
100 tons
Release date
2022-01-14

2268-79-3, 6-Methyl-2-mercaptobenzothiazoleRelated Search:


  • 2(3H)-Benzothiazolethione,6-methyl-(9CI)
  • 6-Methyl-2-mercaptobenzothiazole
  • 6-Methyl-2(3H)-benzothiazolethione
  • 6-Methyl-2-benzothiazolethiol
  • 6-Methylbenzo[d]thiazole-2-thiol
  • 2-Mercapto-6-methylbenzothiazole
  • 6-methyl-3H-1,3-benzothiazole-2-thione
  • 2(3H)-Benzothiazolethione, 6-methyl-
  • 2268-79-3
  • BENZOTHIAZOLE
  • Heterocycles
  • Heterocyclic Compound