(2-FLUORO-BENZYL)-HYDRAZINE

Product Name: (2-FLUORO-BENZYL)-HYDRAZINE
CAS No.: 51859-98-4
Chemical Name: (2-FLUORO-BENZYL)-HYDRAZINE
Synonyms: (2-FLUORO-BENZYL)-HYDRAZINE;[(2-fluorophenyl)methyl]hydrazine;1-fluoro-1-(phenylmethyl)hydrazine;1-Fluoro-2-(hydrazinomethyl)benzene;Hydrazine, [(2-fluorophenyl)methyl]-;(2-Fluorobenzyl)hydrazine (HCl forM)
CBNumber: CB5133923
Molecular Formula: C7H9FN2
Formula Weight: 140.16
MOL File: 51859-98-4.mol

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(2-FLUORO-BENZYL)-HYDRAZINE Property

Boiling point:: 265.8±23.0 °C(Predicted)
Density: 1.144±0.06 g/cm3(Predicted)
storage temp.: Keep in dark place,Inert atmosphere,Store in freezer, under -20°C
pka: 6.74±0.10(Predicted)
form: liquid
color: Clear, colourless
InChI: InChI=1S/C7H9FN2/c8-7-4-2-1-3-6(7)5-10-9/h1-4,10H,5,9H2
InChIKey: OOMBRKGIWITBLL-UHFFFAOYSA-N
SMILES: N(CC1=CC=CC=C1F)N

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Safety

HS Code: 2928009090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word: Danger
Precautionary statements: P280Wear protective gloves/protective clothing/eye protection/face protection.

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N-Bromosuccinimide Price

TRC

Product number: F588635
Product name: 2-Fluorobenzylhydrazine
Packaging: 1g
Price: $195
Updated: 2021/12/16

Apolloscientific

Product number: PC49334
Product name: (2-Fluorobenzyl)hydrazine
Purity: 95%
Packaging: 25g
Price: $275
Updated: 2021/12/16

AK Scientific

Product number: W6669
Product name: (2-Fluorobenzyl)hydrazine
Packaging: 1g
Price: $380
Updated: 2021/12/16

Ark Pharm

Product number: AK-35444
Product name: (2-Fluorobenzyl)hydrazine
Purity: 90%
Packaging: 1g
Price: $29
Updated: 2021/12/16

SynQuest Laboratories

Product number: 3739-3-01
Product name: (2-Fluorobenzyl)hydrazine
Packaging: 1g
Price: $48
Updated: 2021/12/16

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(2-FLUORO-BENZYL)-HYDRAZINE Chemical Properties,Usage,Production

Uses

2-Fluorobenzylhydrazine has been used as a reactant for the synthesis of acylamino substituted benzylbenzohydrazide derivatives.

Synthesis

446-48-0

51859-98-4

The general procedure for the synthesis of 2-fluorobenzyl hydrazine from 2-fluorobenzyl bromide was as follows: 190 g (1.0 mol) of 2-fluorobenzyl bromide was slowly added to a 2 L ethanol solution containing 250 g (5.0 mol) of hydrazine hydrate and 137 g (1.0 mol) of potassium carbonate under stirring conditions. The reaction mixture was stirred continuously at room temperature for 48 hours. After completion of the reaction, the reaction mixture was concentrated by distillation under reduced pressure. The residue was extracted with ether to separate the organic phase. The organic phase was dried over anhydrous sodium sulfate and concentrated again under reduced pressure to remove the solvent. The crude product was purified by silica gel column chromatography to give 109 g (76% yield) of 2-fluorobenzylhydrazine.

References

[1] Journal of Medicinal Chemistry, 1995, vol. 38, # 19, p. 3884 - 3888
[2] Patent: WO2005/97784, 2005, A1. Location in patent: Page/Page column 70-71
[3] Patent: US2012/196861, 2012, A1
[4] Patent: US2012/196862, 2012, A1
[5] Patent: US2014/357637, 2014, A1. Location in patent: Paragraph 1226

(2-FLUORO-BENZYL)-HYDRAZINE Preparation Products And Raw materials

Raw materials

Preparation Products

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(2-FLUORO-BENZYL)-HYDRAZINE Suppliers

China 121 Germany 2 India 2 Ukraine 1 United Kingdom 1 United States 12 Global 139

Alchem Pharmtech,Inc.

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View Lastest Price from (2-FLUORO-BENZYL)-HYDRAZINE manufacturers

Changzhou waston chemical technology Co.,Ltd

Product: (2-FLUORO-BENZYL)-HYDRAZINE 51859-98-4
Price: US $0.00/kg
Min. Order: 1kg
Purity: 93%
Supply Ability: As your request
Release date: 2025-03-19

Honest Joy Holdings Limited

Product: (2-fluorobenzyl)hydrazine 51859-98-4
Price: US $0.00/KG
Min. Order: 1KG
Purity: 98.5%
Supply Ability: 100 tons
Release date: 2022-01-14

Career Henan Chemical Co

Product: (2-FLUORO-BENZYL)-HYDRAZINE 51859-98-4
Price: US $1.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: Customized
Release date: 2018-12-17

51859-98-4, (2-FLUORO-BENZYL)-HYDRAZINERelated Search:

4,5-DICHLORO-2-(2-FLUOROBENZYL)PYRIDAZINE-3(2H)-ONE 2-(2-CHLORO-6-FLUOROBENZYL)-4,5-DICHLOROPYRIDAZINE-3-(2H)-ONE 2,6-Difluorobenzoyl hydrazine STATIL 2-Fluorobenzohydrazide Benzylhydrazine 2,4-DIFLUOROBENZOIC ACID HYDRAZIDE Isaglidole SALOR-INT L460400-1EA SALOR-INT L384755-1EA SALOR-INT L273406-1EA SALOR-INT L277258-1EA SPECS AG-205/12125058 2,6-DIFLUORO-N'-METHYL-N'-[4-METHYL-3-(METHYLSULFONYL)-6-PHENYL-2-PYRIDINYL]BENZENECARBOHYDRAZIDE N'1-(2-CHLORO-6-FLUOROBENZYL)-N'1-PHENYL-2-CHLOROETHANOHYDRAZIDE SALOR-INT L108758-1EA AURORA 12480 N'-[4,6-DIMETHYL-3-(METHYLSULFONYL)-2-PYRIDINYL]-2,6-DIFLUORO-N'-METHYLBENZENECARBOHYDRAZIDE

(2-FLUORO-BENZYL)-HYDRAZINE

1-Fluoro-2-(hydrazinomethyl)benzene

[(2-fluorophenyl)methyl]hydrazine

(2-Fluorobenzyl)hydrazine (HCl forM)

1-fluoro-1-(phenylmethyl)hydrazine

Hydrazine, [(2-fluorophenyl)methyl]-

51859-98-4

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