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DICHLOROTRIPHENYLPHOSPHORANE

Product Name
DICHLOROTRIPHENYLPHOSPHORANE
CAS No.
2526-64-9
Chemical Name
DICHLOROTRIPHENYLPHOSPHORANE
Synonyms
TRIPHENYLPHOSPHINE DICHLORIDE;Triphenyldichlorophosphorane;DICHLOROTRIPHENYLPHOSPHORANE;DICHLORO TRIPHENYL PHOSPHINE;Dichloride Triphenylphosphine;Triphenyldichlorophosphorus(V);Phosphorane,dichlorotriphenyl-;Dichlorotriphenylphosphorane 95%;dichloro(triphenyl)-λ5-phosphane;Dichlorotriphenyl-lambda5-phosphane
CBNumber
CB5136171
Molecular Formula
C18H15Cl2P
Formula Weight
333.19
MOL File
2526-64-9.mol
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DICHLOROTRIPHENYLPHOSPHORANE Property

Melting point:
85 °C (dec.) (lit.)
Flash point:
68 °F
solubility 
Chloroform (Soluble), Dichloromethane (Slightly)
form 
Solid
color 
White to Light Yellow
Water Solubility 
Reacts with water.
Sensitive 
Moisture Sensitive
Stability:
Extremely Moisture Sensitive, Hygroscopic
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Safety

Hazard Codes 
F,T
Risk Statements 
45-11-34
Safety Statements 
53-26-36/37/39-45-16
RIDADR 
UN 2925 4.1/PG 2
WGK Germany 
3
HazardClass 
8
PackingGroup 
II
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H228Flammable solid

H314Causes severe skin burns and eye damage

H350May cause cancer

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
378755
Product name
Dichlorotriphenylphosphorane
Purity
95%
Packaging
25g
Price
$66.2
Updated
2024/03/01
Sigma-Aldrich
Product number
378755
Product name
Dichlorotriphenylphosphorane
Purity
95%
Packaging
100g
Price
$169
Updated
2024/03/01
TRC
Product number
D436840
Product name
Dichlorotriphenylphosphorane
Packaging
5g
Price
$75
Updated
2021/12/16
Biosynth Carbosynth
Product number
FD161279
Product name
Dichlorotriphenylphosphorane
Packaging
25g
Price
$100
Updated
2021/12/16
Biosynth Carbosynth
Product number
FD161279
Product name
Dichlorotriphenylphosphorane
Packaging
50g
Price
$150
Updated
2021/12/16
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DICHLOROTRIPHENYLPHOSPHORANE Chemical Properties,Usage,Production

Uses

Dichlorotriphenylphosphorane may be used in the synthesis of the following:

  • tertiary benzanilide derivatives
  • N-phosphodipeptides
  • dialkyl phosphorochloridites based on the reaction of trialkyl phosphites
  • naphthalene ring-based calix[3]amide, via reaction with 6-amino-2-naphthoic acid
  • C2v-symmetrical cyclic tetramers of aromatic amides

General Description

Dichlorotriphenylphosphorane (Triphenylphosphine dichloride, PPh3Cl2) is a phosphorous halide. Stability and reactivity of dichlorotriphenylphosphorane have been studied by solid state 31P NMR spectroscopy. It participates in the conversion of carboxylic esters to acid halides and mechanism of this cleavage has been investigated. Modified method has been proposed in which dichlorotriphenylphosphorane participates in the synthesis of tertiary amides.

DICHLOROTRIPHENYLPHOSPHORANE Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from DICHLOROTRIPHENYLPHOSPHORANE manufacturers

Shaanxi Dideu Medichem Co. Ltd
Product
Triphenylphosphine dichloride 2526-64-9
Price
US $1.00-0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
20 tons
Release date
2020-01-16
Career Henan Chemical Co
Product
DICHLOROTRIPHENYLPHOSPHORANE 2526-64-9
Price
US $11.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
1000KG
Release date
2018-08-16

2526-64-9, DICHLOROTRIPHENYLPHOSPHORANERelated Search:


  • TRIPHENYLPHOSPHINE DICHLORIDE
  • DICHLORO TRIPHENYL PHOSPHINE
  • DICHLOROTRIPHENYLPHOSPHORANE
  • Triphenyldichlorophosphorane
  • Triphenyldichlorophosphorus(V)
  • Dichlorotriphenylphosphorane,Triphenylphosphine dichloride
  • dichloro(triphenyl)-λ<sup>5</sup>-phosphane
  • Phosphorane,dichlorotriphenyl-
  • Dichlorotriphenylphosphorane 95%
  • ichloro(triphenyl)-λsup5sup-phosphane
  • Dichloride Triphenylphosphine
  • Dichlorotriphenyl-lambda5-phosphane
  • dichloro(triphenyl)-λ5-phosphane
  • 2526-64-9
  • C18H15Cl2P
  • C6H53PCl2
  • Building Blocks
  • Organic Building Blocks
  • Phosphorus Compounds
  • Phosphorus Halides
  • Building Blocks
  • Chemical Synthesis
  • Organic Building Blocks
  • Phosphorus Compounds
  • Phosphorus Halides