(FORMYLMETHYLENE)TRIPHENYLPHOSPHORANE
- Product Name
- (FORMYLMETHYLENE)TRIPHENYLPHOSPHORANE
- CAS No.
- 2136-75-6
- Chemical Name
- (FORMYLMETHYLENE)TRIPHENYLPHOSPHORANE
- Synonyms
- Ph3P;(TRIPHENYLPHOSPHORANYLIDENE)ACETALDEHYDE;2-(Triphenylphosphoranylidene)acetaldehyde;FMY;idene)acetaL;Triphenylphosphorany;Tri Phenyl Phosphorane;TriPhenylPhosphine(TPP);Formylmethyltriphenylphosphine;Formylmethylenetriphenylphosphine
- CBNumber
- CB6361549
- Molecular Formula
- C20H17OP
- Formula Weight
- 304.32
- MOL File
- 2136-75-6.mol
(FORMYLMETHYLENE)TRIPHENYLPHOSPHORANE Property
- Melting point:
- 185-188 °C(lit.)
- Boiling point:
- 472.6±28.0 °C(Predicted)
- Density
- 1.16±0.1 g/cm3(Predicted)
- storage temp.
- Inert atmosphere,Store in freezer, under -20°C
- solubility
- Soluble in Chloroform, Methanol.
- form
- Fine Crystalline Powder
- color
- Pink to brown
- Sensitive
- Air Sensitive
- BRN
- 523797
- Stability:
- Stable. Combustible. Incompatible with strong oxidizing agents.
- InChIKey
- CQCAYWAIRTVXIY-UHFFFAOYSA-N
- CAS DataBase Reference
- 2136-75-6(CAS DataBase Reference)
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- 280933
- Product name
- (Triphenylphosphoranylidene)acetaldehyde
- Purity
- 95%
- Packaging
- 5g
- Price
- $73.7
- Updated
- 2024/03/01
- Product number
- 280933
- Product name
- (Triphenylphosphoranylidene)acetaldehyde
- Purity
- 95%
- Packaging
- 25g
- Price
- $227
- Updated
- 2024/03/01
- Product number
- T2001
- Product name
- (Triphenylphosphoranylidene)acetaldehyde
- Purity
- >98.0%(HPLC)
- Packaging
- 5g
- Price
- $77
- Updated
- 2024/03/01
- Product number
- T2001
- Product name
- (Triphenylphosphoranylidene)acetaldehyde
- Purity
- >98.0%(HPLC)
- Packaging
- 25g
- Price
- $265
- Updated
- 2024/03/01
- Product number
- A11709
- Product name
- (Formylmethylene)triphenylphosphorane, 97%, may cont. up to ca 3% water
- Packaging
- 10g
- Price
- $65.65
- Updated
- 2024/03/01
(FORMYLMETHYLENE)TRIPHENYLPHOSPHORANE Chemical Properties,Usage,Production
Chemical Properties
pink to brown crystalline powder
Uses
(Formylmethylene)triphenylphosphorane is used as Wittig reagent. It is also used as Pharmaceutical Intermediates. It is employed as raw material in organic Synthesis, Agrochemicals.
Uses
Wittig reagent for the conversion of aldehydes and ketones to two-carbon homologated, α,β-unsaturated carbonyl compounds.
Purification Methods
Recrystallise it from Me2CO, or dissolve it in *C6H6, wash with N NaOH, dry (MgSO4), evaporate, and crystallise the residue from Me2CO. It can be prepared from its precursor, formylmethyltriphenylphosphonium chloride (which crystallises from CHCl3/EtOAc), by treatment with Et3N and extraction with *C6H6. [Tripett & Walker J Chem Soc 1266 1961.]
(FORMYLMETHYLENE)TRIPHENYLPHOSPHORANE Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from (FORMYLMETHYLENE)TRIPHENYLPHOSPHORANE manufacturers
- Product
- (Formylmethylene)Triphenylphosphorane 2136-75-6
- Price
- US $30.00-10.00/KG
- Min. Order
- 50KG
- Purity
- 99%
- Supply Ability
- 500000kg
- Release date
- 2024-11-05
- Product
- (FORMYLMETHYLENE) Triphenylphosphorane 2136-75-6
- Price
- US $10.70/k g
- Min. Order
- 10k g
- Purity
- 99%
- Supply Ability
- 10000kg
- Release date
- 2024-08-20
- Product
- (FORMYLMETHYLENE)TRIPHENYLPHOSPHORANE 2136-75-6
- Price
- US $0.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- 50000KG/month
- Release date
- 2024-09-24