Uses
ChemicalBook > CAS DataBase List > DICHLORODICARBONYLBIS(TRIPHENYLPHOSPHINE)RUTHENIUM (II)

DICHLORODICARBONYLBIS(TRIPHENYLPHOSPHINE)RUTHENIUM (II)

Uses
Product Name
DICHLORODICARBONYLBIS(TRIPHENYLPHOSPHINE)RUTHENIUM (II)
CAS No.
14564-35-3
Chemical Name
DICHLORODICARBONYLBIS(TRIPHENYLPHOSPHINE)RUTHENIUM (II)
Synonyms
DICARBONYLDICHLOROBIS(TRIPHENYLPHOSPHIN&;Dichlorodicarbonylbis(triphenylphosphine);Dichlorodicarbonylbis(triphenylphosphine)ruth;dicarbonyldichlorobis(triphenylphosphine)-rutheni;dicarbonyldichlorobis(triphenylphosphine)ruthenium;Dichlorodicarbonylbis-(triphenylphosphino)-ruthenium;RUTHENIUM(II)-BIS(TRIPHENYLPHOSPHINE)DICHLOROCARBONYL;Dichlorodicarbonylbis(triphenylphosphine)ruthenium(Ⅱ);Dichlorocarbonylbis(triphenylphosphine)ruthenium (II);DICHLORODICARBONYLBIS(TRIPHENYLPHOSPHINE)RUTHENIUM (II)
CBNumber
CB3715486
Molecular Formula
C38H30Cl2O2P2Ru
Formula Weight
752.57
MOL File
14564-35-3.mol
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DICHLORODICARBONYLBIS(TRIPHENYLPHOSPHINE)RUTHENIUM (II) Property

Melting point:
230-235°C
storage temp. 
Inert atmosphere,Room Temperature
form 
Powder
color 
white
InChI
InChI=1S/2C18H15P.2CO.2ClH.Ru/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;2*1-2;;;/h2*1-15H;;;2*1H;/q;;;;;;+2/p-2
InChIKey
PXURRFCLQDNZOY-UHFFFAOYSA-L
SMILES
P(C1=CC=CC=C1)(C1=CC=CC=C1)C1=CC=CC=C1.P(C1=CC=CC=C1)(C1C=CC=CC=1)C1=CC=CC=C1.[Ru](Cl)Cl.[O+]#[C-].[O+]#[C-]
CAS DataBase Reference
14564-35-3
EPA Substance Registry System
Ruthenium, dicarbonyldichlorobis(triphenylphosphine)- (14564-35-3)
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Safety

Hazard Codes 
Xn
Risk Statements 
20/21/22-36/37/38
Safety Statements 
22-24/25
WGK Germany 
3
TSCA 
TSCA listed
HS Code 
28439090
Storage Class
11 - Combustible Solids
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Hazard and Precautionary Statements (GHS)

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
15258
Product name
Bis(triphenylphosphine)ruthenium(II) dicarbonyl chloride
Purity
≥98.0% (CH)
Packaging
1g
Price
$459
Updated
2025/07/31
Strem Chemicals
Product number
44-0400
Product name
Dichlorodicarbonylbis(triphenylphosphine)ruthenium(II), min. 98%
Packaging
250mg
Price
$88
Updated
2024/03/01
Strem Chemicals
Product number
44-0400
Product name
Dichlorodicarbonylbis(triphenylphosphine)ruthenium(II), min. 98%
Packaging
1g
Price
$262
Updated
2024/03/01
Biosynth Carbosynth
Product number
FD152849
Product name
Dichlorodicarbonylbis(triphenylphosphine)ruthenium(II)
Packaging
2g
Price
$269
Updated
2021/12/16
AK Scientific
Product number
E051
Product name
Dichlorodicarbonylbis(triphenylphosphine)ruthenium(II)
Packaging
5g
Price
$361
Updated
2021/12/16
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DICHLORODICARBONYLBIS(TRIPHENYLPHOSPHINE)RUTHENIUM (II) Chemical Properties,Usage,Production

Uses

Dichlorodicarbonylbis(triphenylphosphine)ruthenium exhibits good catalytic performance in the addition reaction of aromatic ketone carbonyl groups with olefin molecules, and can be widely used as a noble metal catalyst in organic synthesis reactions.

Chemical Properties

white crystals

reaction suitability

core: ruthenium
reagent type: catalyst

Synthesis

A certain amount of triphenylphosphine was weighed and added to a 100mL three-necked flask having a quantitative anhydrous ethanol solution, stirred, and heated to boiling, then a certain amount of ruthenium trichloride trihydrate, formaldehyde solution, and potassium hydroxide were added to the three-necked flask in rapid succession. The reaction was heated to reflux (precipitates were produced during the reaction), the reaction was stopped after a period of time, naturally cooled to room temperature and filtered. The filter cake was washed with 95% ethanol, deionized water, 95% ethanol and petroleum ether in sequence, and the precipitate was dried to constant weight to obtain the crude product of dichlorodicarbonylbis(triphenylphosphine)ruthenium, weighed, and the product yield was calculated.

DICHLORODICARBONYLBIS(TRIPHENYLPHOSPHINE)RUTHENIUM (II) Preparation Products And Raw materials

Raw materials

Preparation Products

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DICHLORODICARBONYLBIS(TRIPHENYLPHOSPHINE)RUTHENIUM (II) Suppliers

Changsha Shunyan New Materials Technology Co., Ltd
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13005015646
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1258788278@qq.com
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China
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J & K SCIENTIFIC LTD.
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18210857532; 18210857532
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86-10-82849933
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jkinfo@jkchemical.com
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China
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INTATRADE GmbH
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+49 3493/605464
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+49 3493/605470
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sales@intatrade.de
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Germany
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Energy Chemical
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021-58436166
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sales8178@energy-chemical.com
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China
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021-54306202 13764082696
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010-56205725
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010-65763397
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021-57603038 13601791340
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Shanghai Aladdin Bio-Chem Technology Co.,LTD
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400-6206333 13167063860
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021-50323701
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anhua.mao@aladdin-e.com
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The future of Shanghai Industrial Co., Ltd.
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021-55660885
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View Lastest Price from DICHLORODICARBONYLBIS(TRIPHENYLPHOSPHINE)RUTHENIUM (II) manufacturers

ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD
Product
Dichlorodicarbonyl-bis-(triphenylphosphine)ruthenium(II) 14564-35-3
Price
US $2.00-5.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
100kg
Release date
2025-06-19
Career Henan Chemical Co
Product
DICHLORODICARBONYLBIS(TRIPHENYLPHOSPHINE)RUTHENIUM (II) 14564-35-3
Price
US $3.00/KG
Min. Order
1KG
Purity
98%min
Supply Ability
200KG
Release date
2020-01-07

14564-35-3, DICHLORODICARBONYLBIS(TRIPHENYLPHOSPHINE)RUTHENIUM (II)Related Search:


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